In Situ Generation of Silyl Anion Species through Si−B Bond Activation for the Concerted Nucleophilic Aromatic Substitution of Fluoroarenes

In Situ Generation of Silylzinc by Si−B Bond Activation Enabling Silylzincation and Silaboration of Terminal Alkynes

(2018) Yuki Nagashima et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Concerted nucleophilic aromatic substitutions

(2018) Eugene E. Kwan et al.   Nature Chemistry

Ni(COD)2-Catalyzed ipso-Silylation of 2-Methoxynaphthalene: A Density Functional Theory Study

(2018) Pooja Jain et al.   ORGANOMETALLICS

Base-Mediated Defluorosilylation of C(sp2 )−F and C(sp3 )−F Bonds

(2018) Xiang-Wie Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silyldefluorination of Fluoroarenes by Concerted Nucleophilic Aromatic Substitution

(2018) Shubhadip Mallick et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Defluorosilylation of fluoroarenes and fluoroalkanes

(2018) Benqiang Cui et al.   Nature Communications

C(sp3)–Si Cross-Coupling

(2018) Susanne Bähr et al.   ACS Catalysis

Stereodivergent Silylzincation of α-Heteroatom-Substituted Alkynes

(2016) Carolin Fopp et al.   ORGANIC LETTERS

Ring-Opening ofN-tert-Butanesulfinylethynylaziridines with Lithium Tris(dimethylphenylsilyl)zincate: Stereoselective Access to 4-Amino-1-allenylsilanes

(2015) Valentin N. Bochatay et al.   ADVANCED SYNTHESIS & CATALYSIS

Reaction Mechanism of the Anomalous Formal Nucleophilic Borylation of Organic Halides with Silylborane: Combined Theoretical and Experimental Studies

(2015) Ryohei Uematsu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Functionalization of Fluorinated Molecules by Transition-Metal-Mediated C–F Bond Activation To Access Fluorinated Building Blocks

(2014) Theresia Ahrens et al.   CHEMICAL REVIEWS

Recent advances in homogeneous nickel catalysis

(2014) Sarah Z. Tasker et al.   NATURE

Chelation-Assisted Regioselective Catalytic Functionalization of C–H, C–O, C–N and C–F Bonds

(2014) Fumitoshi Kakiuchi et al.   SYNLETT

Design, Generation, and Synthetic Application of Borylzincate: Borylation of Aryl Halides and Borylzincation of Benzynes/Terminal Alkyne

(2013) Yuki Nagashima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Systematic exploration of the mechanism of chemical reactions: the global reaction route mapping (GRRM) strategy using the ADDF and AFIR methods

(2013) Satoshi Maeda et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis

(2012) Martin Oestreich et al.   CHEMICAL REVIEWS

Recent advances in transition-metal-free carbon–carbon and carbon–heteroatom bond-forming reactions using arynes

(2012) Anup Bhunia et al.   CHEMICAL SOCIETY REVIEWS

Synthesis and Structure of Zwitterionic Silylborates and Silylzincates with Pendant Polydonor Arms

(2012) Hui Li et al.   ORGANOMETALLICS

C-F Bond Activation of Highly Fluorinated Molecules at Rhodium: From Model Reactions to Catalysis

(2011) Thomas Braun et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Nickel-Catalyzed Cross-Couplings Involving Carbon−Oxygen Bonds

(2010) Brad M. Rosen et al.   CHEMICAL REVIEWS

Regioselective Silylzincation of Phenylallene Derivatives

(2010) Mitsuhiro Yonehara et al.   Chemistry-An Asian Journal

Arylation of unactivated arenes

(2010) Aiwen Lei et al.   DALTON TRANSACTIONS

Silylboranes as New Tools in Organic Synthesis

(2009) Toshimichi Ohmura et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

C−F Bond Activation in Organic Synthesis

(2009) Hideki Amii et al.   CHEMICAL REVIEWS

Silylmetalation of Alkenes

(2007) Shinji Nakamura et al.   CHEMISTRY-A EUROPEAN JOURNAL