Palladacycle-Catalyzed Olefinic C–P Cross-Coupling of Alkenylsulfonium Salts with Diarylphosphines to Access Alkenylphosphines

Catalytic Asymmetric Axially Chiral Allenyl C–P Bond Formation

(2022) Huanan Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Transformations of Sulfonium Salts via C‐S Bond Activation

(2021) Hideki Yorimitsu   CHEMICAL RECORD

Diverse C–P Cross-Couplings of Arylsulfonium Salts with Diarylphosphines via Selective C–S Bond Cleavage

(2021) Yun Ye et al.   ORGANIC LETTERS

Asymmetric Synthesis of P-Stereogenic Secondary Phosphine-Boranes by an Unsymmetric Bisphosphine Pincer-Nickel Complex

(2021) Chuanyong Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enabling the Use of Alkyl Thianthrenium Salts in Cross‐Coupling Reactions by Copper Catalysis

(2021) Cheng Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper(I)-Catalyzed Asymmetric Alkylation of Unsymmetrical Secondary Phosphines

(2021) Shuai Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Vinyl Thianthrenium Tetrafluoroborate: A Practical and Versatile Vinylating Reagent Made from Ethylene

(2021) Fabio Juliá et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aziridine synthesis by coupling amines and alkenes via an electrogenerated dication

(2021) Dylan E. Holst et al.   NATURE

Palladium-Catalyzed Fluoroalkylation via C(sp3)–S Bond Cleavage of Vinylsulfonium Salts

(2021) Yuan He et al.   ORGANIC LETTERS

Generation of non-stabilized alkyl radicals from thianthrenium salts for C–B and C–C bond formation

(2021) Cheng Chen et al.   Nature Communications

Metal-free allylic C–H nitrogenation, oxygenation, and carbonation of alkenes by thianthrenation

(2021) Ming-Shang Liu et al.   Chemical Science

Radical C–C bond formation using sulfonium salts and light

(2020) Aron Peter et al.   ADVANCED SYNTHESIS & CATALYSIS

Rapd Synthesis of Chiral 1,2-Bisphosphine Derivatives through Copper(I)-Catalyzed Asymmetric Conjugate Hydrophosphination

(2020) Wen-Jun Yue et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free photoredox-catalysed formal C–H/C–H coupling of arenes enabled by interrupted Pummerer activation

(2020) Miles H. Aukland et al.   Nature Catalysis

Pd‐Catalyzed Site‐Selective Borylation of Simple Arenes via Thianthrenation

(2020) Xiao‐Yue Chen et al.   CHINESE JOURNAL OF CHEMISTRY

Synthetic Applications of Sulfonium Salts

(2020) Manuel Alcarazo et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Metal–Catalyzed P–C Bond Formation via P–H Oxidative Addition: Fundamentals and Recent Advances

(2020) David S Glueck   JOURNAL OF ORGANIC CHEMISTRY

Site-Selective C–H Functionalization–Sulfination Sequence to Access Aryl Sulfonamides

(2020) Eva Maria Alvarez et al.   ORGANIC LETTERS

P‐Chiral Alkenylphosphine Oxides Enabled by Highly Chemo‐, Regio‐ and Enantioselective Hydrophosphinylation of Alkynes

(2020) Junliang Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cine-Substitutions at Five-Membered Hetarenes Enabled by Sulfonium Salts

(2020) Florian Berger et al.   ORGANIC LETTERS

Site-Selective Silylation of Arenes Mediated by Thianthrene S-Oxide

(2020) Yichen Wu et al.   ORGANIC LETTERS

Vinyl Sulfonium Salts as the Radical Acceptor for Metal-Free Decarboxylative Alkenylation

(2020) Yu-Lan Zhang et al.   ORGANIC LETTERS

Asymmetric Hydrophosphination of Heterobicyclic Alkenes: Facile Access to Phosphine Ligands for Asymmetric Catalysis

(2019) Zhiwu Lu et al.   ACS Catalysis

Site-selective and versatile aromatic C−H functionalization by thianthrenation

(2019) Florian Berger et al.   NATURE

Structurally Constrained Boron-, Nitrogen-, Silicon-, and Phosphorus-Centered Polycyclic π-Conjugated Systems

(2019) Masato Hirai et al.   CHEMICAL REVIEWS

Transition metal-free cross-coupling of benzothiophenes and styrenes in a stereoselective synthesis of substituted (E,Z)-1,3-dienes

(2019) Mindaugas Šiaučiulis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bond-Forming and -Breaking Reactions at Sulfur(IV): Sulfoxides, Sulfonium Salts, Sulfur Ylides, and Sulfinate Salts

(2019) Daniel Kaiser et al.   CHEMICAL REVIEWS

Regioselective Single and Double Hydrophosphination and Hydrophosphinylation of Unactivated Alkynes

(2019) Miriam M. I. Basiouny et al.   ACS Catalysis

C–N Cross-Couplings for Site-Selective Late-Stage Diversification via Aryl Sulfonium Salts

(2019) Pascal S. Engl et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-Metal-Free Aryl–Heteroatom Bond Formation via C–S Bond Cleavage

(2019) Jian-Nan Zhao et al.   ORGANIC LETTERS

Aryl Sulfonium Salts for Site-Selective Late-Stage Trifluoromethylation

(2019) Fei Ye et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Site-Selective C−H Oxygenation via Aryl Sulfonium Salts

(2019) Ruocheng Sang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and Stereoselective Thianthrenation of Olefins to Access Versatile Alkenyl Electrophiles

(2019) Tobias Ritter et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis, Structure, and Reactivity of 5-(Aryl)dibenzothiophenium Triflates

(2019) Kevin Kafuta et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoredox catalysis with aryl sulfonium salts enables site-selective late-stage fluorination

(2019) Jiakun Li et al.   Nature Chemistry

Para-selective borylation of monosubstituted benzenes using a transient mediator

(2019) Jie Wu et al.   Science China-Chemistry

Site-Selective Late-Stage Aromatic [18 F]Fluorination via Aryl Sulfonium Salts

(2019) Peng Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

P-Chiral Phosphines Enabled by Palladium/Xiao-Phos-Catalyzed Asymmetric P–C Cross-Coupling of Secondary Phosphine Oxides and Aryl Bromides

(2019) Qiang Dai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Interrupted Pummerer/Nickel-Catalysed Cross-Coupling Sequence

(2018) Miles H. Aukland et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Application of arylsulfonium salts as arylation reagents

(2018) Ze-Yu Tian et al.   TETRAHEDRON LETTERS

5-(Alkynyl)dibenzothiophenium Triflates: Sulfur-Based Reagents for Electrophilic Alkynylation

(2018) Bernd Waldecker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphine Organocatalysis

(2018) Hongchao Guo et al.   CHEMICAL REVIEWS

Phosphine-Catalyzed Asymmetric Organic Reactions

(2018) Huanzhen Ni et al.   CHEMICAL REVIEWS

Catalyst- and Solvent-Free Addition of the P–H Species to Alkenes and Alkynes: A Green Methodology for C–P Bond Formation

(2017) Boris Trofimov et al.   SYNTHESIS-STUTTGART

Palladium-Catalyzed Borylation of Aryl Sulfoniums with Diborons

(2017) Hiroko Minami et al.   ACS Catalysis

Catalyst- and solvent-free hydrophosphination and multicomponent hydrothiophosphination of alkenes and alkynes

(2016) Yanina Moglie et al.   GREEN CHEMISTRY

Cobalt catalysed, copper assisted C(sp2)–P cross coupling

(2016) Tubai Ghosh et al.   NEW JOURNAL OF CHEMISTRY

A Dynamic Kinetic C–P Cross–Coupling for the Asymmetric Synthesis of Axially Chiral P,N Ligands

(2016) Pedro Ramírez-López et al.   ACS Catalysis

Synthesis of 6- and 7-Membered N-Heterocycles Using α-Phenylvinylsulfonium Salts

(2015) Johnathan V. Matlock et al.   ORGANIC LETTERS

Recent Progress in Palladium-Catalyzed Asymmetric Hydrophos­phination

(2015) Sumod Pullarkat   SYNTHESIS-STUTTGART

Preparation of phosphines through C–P bond formation

(2014) Iris Wauters et al.   Beilstein Journal of Organic Chemistry

Enantioselective phospha-Michael addition of diarylphosphines to β,γ-unsaturated α-ketoesters and amides

(2014) Renta Jonathan Chew et al.   CHEMICAL COMMUNICATIONS

Contemporary avenues in catalytic PH bond addition reaction: A case study of hydrophosphination

(2014) Vijay Koshti et al.   COORDINATION CHEMISTRY REVIEWS

Asymmetric Synthesis of P-Stereogenic Diarylphosphinites by Palladium-Catalyzed Enantioselective Addition of Diarylphosphines to Benzoquinones

(2014) Yinhua Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Addition of Diphenylphosphine to 3-Methyl-4-nitro-5-alkenylisoxazoles

(2013) Renta Jonathan Chew et al.   ADVANCED SYNTHESIS & CATALYSIS

Nickel(II)-Magnesium-Catalyzed Cross-Coupling of 1,1-Dibromo-1-alkenes with Diphenylphosphine Oxide: One-Pot Synthesis of (E)-1-Alkenylphosphine Oxides or Bisphosphine Oxides

(2013) Liu Liu et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Synthesis of QUINAP via Dynamic Kinetic Resolution

(2013) Vikram Bhat et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Activation of Vinyl C-S Bonds Over Aryl C-S Bonds in the Pd-Catalyzed Coupling of (E)-(β-Trifluoromethyl)vinyldiphenylsulfonium Salts: Preparation of Trifluoromethylated Alkenes and Dienes

(2012) Hao Lin et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Palladacycle-Catalyzed Asymmetric Hydrophosphination of Enones for Synthesis of C*- and P*-Chiral Tertiary Phosphines

(2012) Yinhua Huang et al.   INORGANIC CHEMISTRY

Asymmetric Synthesis of Enaminophosphines via Palladacycle-Catalyzed Addition of Ph2PH to α,β-Unsaturated Imines

(2012) Yinhua Huang et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladacycle-Catalyzed Asymmetric Intermolecular Construction of Chiral Tertiary P-Heterocycles by Stepwise Addition of H–P–H Bonds to Bis(enones)

(2012) Yinhua Huang et al.   ORGANOMETALLICS

β-(Trifluoromethyl)vinyl Sulfonium Salts: Preparation and Reactions with Active Methylene and Methenyl Compounds

(2011) Hao Lin et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct Synthesis of Chiral Tertiary DiphosphinesviaPd(II)-Catalyzed Asymmetric Hydrophosphination of Dienones

(2011) Yinhua Huang et al.   ORGANIC LETTERS

Palladium(ii)-catalyzed asymmetric hydrophosphination of enones: efficient access to chiral tertiary phosphines

(2010) Yinhua Huang et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Asymmetric Addition of Diarylphosphines to Enones toward the Synthesis of Chiral Phosphines

(2010) Jian-Jun Feng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preparation and Reactions of (β-Trifluoromethyl)vinyl Sulfonium Salt

(2010) Ryoko Maeda et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed C-P Cross-Coupling Reactions

(2010) Martin Oestreich et al.   SYNTHESIS-STUTTGART

Catalytic Asymmetric Synthesis of Chiral Phosphanes

(2008) David S. Glueck   CHEMISTRY-A EUROPEAN JOURNAL