Journal
NEW JOURNAL OF CHEMISTRY
Volume 40, Issue 11, Pages 9556-9564Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6nj02247b
Keywords
-
Categories
Funding
- DST, Govt. of India, New Delhi
- J. C. Bose fellowship [SR/S2/JCB-11/2008]
- Indian National Science Academy, New Delhi
- CSIR, New Delhi
Ask authors/readers for more resources
An efficient protocol for the cross coupling of styrenyl/aryl halides and H-phosphinate has been developed using a unique Co/Cu catalytic system in the absence of any additional ligand for the first time. A library of diversely functionalised styrenyl/aryl phosphonates has been synthesized using this procedure. The advantages offered using this procedure are operational simplicity, the use of inexpensive and relatively benign metals as a catalyst, wide tolerance to functionality including electron withdrawing and releasing substituents, excellent stereoselectivity and high yields. The mechanism has also been established. The unique feature of this Co/Cu system is that, it primarily involves Co in the catalytic cycle and Cu in the transmetalation process.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available