Journal
SYNTHESIS-STUTTGART
Volume 48, Issue 4, Pages 493-503Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0035-1560556
Keywords
Michael addition; asymmetric synthesis; hydrophosphination; palladacycle; pincer complex
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Asymmetric construction of P-C bonds is considered to be one of the most powerful methods for the preparation of chiral organophosphorus compounds. This review highlights recent progress in palladium-catalyzed asymmetric hydrophosphination reactions involving activated C=C bonds and diarylphosphines. The main catalytic systems employed for this protocol together with current substrate scope and mechanistic insights are described. 1 Introduction 2 Five-Membered CN/CP Palladacycle Catalyzed Protocols 3 PCP Pincer-Type Catalyst Based Protocols 4 NCN and PCN Pincers as Catalysts 5 Conclusion and Outlook
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