Rhodium hydride enabled enantioselective intermolecular C–H silylation to access acyclic stereogenic Si–H

Consecutive β,β′‐Selective C(sp 3 )−H Silylation of Tertiary Amines with Dihydrosilanes Catalyzed by B(C 6 F 5 ) 3

(2021) Huaquan Fang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium‐Catalyzed Intermolecular Silylation of C sp −H by Silacyclobutanes

(2021) Tao He et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Combined Computational and Experimental Study of Rh-Catalyzed C–H Silylation with Silacyclobutanes: Insights Leading to a More Efficient Catalyst System

(2021) Linxing Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of Silicon-Stereogenic Monohydrosilanes by Dehydrogenative C–H Silylation

(2021) Wei Yuan et al.   ORGANIC LETTERS

Catalytic Asymmetric Synthesis of Silicon‐Stereogenic Dihydrodibenzosilines: Silicon Central‐to‐Axial Chirality Relay

(2021) Yonghong Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Revealing Silylation of C(sp 2 )/C(sp 3 )–H Bonds in Arylphosphines by Ruthenium Catalysis

(2020) Jian Wen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of Silicon‐Stereogenic Silanes by Copper‐Catalyzed Desymmetrizing Protoboration of Vinylsilanes

(2020) Ge Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Streamlined Construction of Silicon-Stereogenic Silanes by Tandem Enantioselective C–H Silylation/Alkene Hydrosilylation

(2020) Delong Mu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Silylation of Aliphatic C−H Bonds for the Synthesis of Silicon‐Stereogenic Dihydrobenzosiloles

(2020) Bo Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium‐Catalyzed Synthesis of Chiral Monohydrosilanes by Intramolecular C−H Functionalization of Dihydrosilanes

(2020) Wenpeng Ma et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed Silylation of C–H Bonds in Unactivated Arenes: A Sterically Encumbered Phenanthroline Ligand Accelerates Catalysis

(2019) Caleb Karmel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Generation of Heteroatom Stereocenters by Enantioselective C–H Functionalization

(2019) Johannes Diesel et al.   ACS Catalysis

Controllable Si−C Bond Activation Enables Stereocontrol in the Palladium-Catalyzed [4+2] Annulation of Cyclopropenes with Benzosilacyclobutanes

(2019) Xing-Ben Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

B(C₆F₅)₃/Amine-Catalyzed C(sp)-H Silylation of Terminal Alkynes with Hydrosilanes: Combined Experimental and Theoretical Studies

(2018) Zhaomin Hou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Yttrium-Catalyzed Regioselective α-C–H Silylation of Methyl Sulfides with Hydrosilanes

(2018) Yong Luo et al.   ACS Catalysis

A Mild and Direct Site-Selective sp2 C–H Silylation of (Poly)Azines

(2018) Yiting Gu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Access to Bridged Sila-N-heterocycles from Piperidines via Cascade sp3 and sp2 C–Si Bond Formation

(2018) Jianbo Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed C–H Silylation of Arenes with Vinylsilanes: Rapid and Reversible β-Si Elimination

(2017) Matthew R. Elsby et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Site-Selective Intramolecular Silylation of Primary C–H Bonds for Synthesis of Sila-Heterocycles

(2017) Huaquan Fang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alkali Metal-Hydroxide-Catalyzed C(sp)–H Bond silylation

(2017) Anton A. Toutov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

B(C6F5)3-Catalyzed (Convergent) Disproportionation Reaction of Indoles

(2017) Yuxi Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Progress in Catalytic Enantioselective Desymmetrization of Prochiral Organosilanes for the Synthesis of Silicon-Stereogenic Compounds

(2017) Ryo Shintani   SYNLETT

A well-defined NHC–Ir(iii) catalyst for the silylation of aromatic C–H bonds: substrate survey and mechanistic insights

(2017) Laura Rubio-Pérez et al.   Chemical Science

Iridium-Catalyzed Regioselective C(sp3)–H Silylation of 4-Alkylpyridines at the Benzylic Position with Hydrosilanes Leading to 4-(1-Silylalkyl)pyridines

(2017) Yoshiya Fukumoto et al.   ACS Catalysis

Rhodium-Catalyzed Intramolecular C−H Silylation by Silacyclobutanes

(2016) Qing-Wei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Divergent and Stereoselective Synthesis of β-Silyl-α-Amino Acids through Palladium-Catalyzed Intermolecular Silylation of Unactivated Primary and Secondary C−H Bonds

(2016) Yue-Jin Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Construction of Chiral Tetraorganosilicons by Tandem Desymmetrization of Silacyclobutanes/Intermolecular Dehydrogenative Silylation

(2016) Qing-Wei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed direct intermolecular silylation of remote unactivated C(sp3)–H bonds

(2016) Jin-Long Pan et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed Synthesis of Chiral Spiro-9-silabifluorenes by Dehydrogenative Silylation: Mechanistic Insights into the Construction of Tetraorganosilicon Stereocenters

(2016) Masahito Murai et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Progress in Asymmetric Synthesis and Application of Difunctionalized Silicon-Stereogenic Silanes

(2016) Jonathan O. Bauer et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Boron-Catalyzed Aromatic C–H Bond Silylation with Hydrosilanes

(2016) Yuanhong Ma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermolecular C–H Silylation of Arenes and Heteroarenes with HSiEt3 under Operationally Diverse Conditions: Neat/Stoichiometric and Acceptor/Acceptorless

(2016) Kang-sang Lee et al.   ACS Catalysis

Undirected, Homogeneous C–H Bond Functionalization: Challenges and Opportunities

(2016) John F. Hartwig et al.   ACS Central Science

Rhodium-Catalyzed Enantioselective Intramolecular CH Silylation for the Syntheses of Planar-Chiral Metallocene Siloles

(2015) Qing-Wei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Silylation of Unactivated C–H Bonds

(2015) Chen Cheng et al.   CHEMICAL REVIEWS

Silylations of Arenes with Hydrosilanes: From Transition-Metal-Catalyzed CX Bond Cleavage to Environmentally Benign Transition-Metal-Free CH Bond Activation

(2015) Zheng Xu et al.   ChemSusChem

Acceleration Effects of Phosphine Ligands on the Rhodium-Catalyzed Dehydrogenative Silylation and Germylation of Unactivated C(sp3)–H Bonds

(2015) Masahito Murai et al.   JOURNAL OF ORGANIC CHEMISTRY

Nickel(0)-Catalyzed Enantio- and Diastereoselective Synthesis of Benzoxasiloles: Ligand-Controlled Switching from Inter- to Intramolecular Aryl-Transfer Process

(2015) Ravindra Kumar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Silylation of Aryl C–H Bonds

(2015) Chen Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silylation of C–H bonds in aromatic heterocycles by an Earth-abundant metal catalyst

(2015) Anton A. Toutov et al.   NATURE

Iridium Pincer Catalysts for Silane Dehydrocoupling: Ligand Effects on Selectivity and Activity

(2015) Neil T. Mucha et al.   ORGANOMETALLICS

Direct silylation reactions of inert C-H bonds via transition metal catalysis

(2015) Yunhui Yang et al.   Science China-Chemistry

Rhodium-Catalyzed Intermolecular C-H Silylation of Arenes with High Steric Regiocontrol

(2014) C. Cheng et al.   SCIENCE

E–H (E = R3Si or H) bond activation by B(C6F5)3 and heteroarenes; competitive dehydrosilylation, hydrosilylation and hydrogenation

(2013) Liam D. Curless et al.   CHEMICAL COMMUNICATIONS

Hemilabile N-Xylyl-N′-methylperimidine Carbene Iridium Complexes as Catalysts for C–H Activation and Dehydrogenative Silylation: Dual Role of N-Xylyl Moiety for ortho-C–H Bond Activation and Reductive Bond Cleavage

(2013) Gyeongshin Choi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Desymmetrization Catalyzed by Transition-Metal Complexes: Enantioselective Formation of Silicon-Stereogenic Silanes

(2012) Li-Wen Xu   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Asymmetric Synthesis of Spirosilabifluorene Derivatives

(2012) Yoichiro Kuninobu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redistribution of Trialkyl Silanes Catalyzed by Iridium Silyl Complexes

(2012) Sehoon Park et al.   ACS Catalysis

Borylation and Silylation of C–H Bonds: A Platform for Diverse C–H Bond Functionalizations

(2011) John F. Hartwig   ACCOUNTS OF CHEMICAL RESEARCH

Scandium-Catalyzed Silylation of Aromatic CH Bonds

(2011) Juzo Oyamada et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperative Catalytic Activation of Si−H Bonds by a Polar Ru−S Bond: Regioselective Low-Temperature C−H Silylation of Indoles under Neutral Conditions by a Friedel−Crafts Mechanism

(2011) Hendrik F. T. Klare et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The recent synthesis and application of silicon-stereogenic silanes: A renewed and significant challenge in asymmetric synthesis

(2010) Li-Wen Xu et al.   CHEMICAL SOCIETY REVIEWS

Easily Attachable and Detachableortho-Directing Agent for Arylboronic Acids in Ruthenium-Catalyzed Aromatic C−H Silylation

(2009) Hideki Ihara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Iridium-Catalyzed CH Functionalization/Silylation of Heteroarenes

(2008) Biao Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION