Recent Progress in Asymmetric Synthesis and Application of Difunctionalized Silicon-Stereogenic Silanes

Rhodium-catalyzed asymmetric synthesis of silicon-stereogenic silicon-bridged arylpyridinones

(2016) Ryo Shintani et al.   Chemical Science

Catalytic Silylations of Alcohols: Turning Simple Protecting-Group Strategies into Powerful Enantioselective Synthetic Methods

(2015) Li-Wen Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Constellation of Deuterium-Labeled Silanes as a Simple Mechanistic Probe not Requiring Absolute Configuration Determination

(2015) Thomas Fallon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-catalyzed intramolecular alkynylsilylation of alkynes

(2015) Ryo Shintani et al.   CHEMICAL COMMUNICATIONS

Construction of a Chiral Silicon Center by Rhodium-Catalyzed Enantioselective Intramolecular Hydrosilylation

(2015) Yuki Naganawa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chiral Memory in Silylium Ions

(2015) P. Ducos et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydrogen bonding principles in inclusion compounds of triphenylsilanol and pyrrolidine: Synthesis and structural features of [(Ph3SiOH)4·HN(CH2)4] and [Ph3SiOH·HN(CH2)4·CH3CO2H]

(2015) Jonathan O. Bauer et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Nickel(0)-Catalyzed Enantio- and Diastereoselective Synthesis of Benzoxasiloles: Ligand-Controlled Switching from Inter- to Intramolecular Aryl-Transfer Process

(2015) Ravindra Kumar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereocontrol in Nucleophilic Substitution Reactions at Silicon: The Role of Permutation in Generating Silicon-Centered Chirality

(2015) Jonathan O. Bauer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Advances in the Transition-Metal-Catalyzed Enantioselective Synthesis of Silicon-Stereogenic Organosilanes

(2015) Ryo Shintani   Asian Journal of Organic Chemistry

Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles by Enantioselective [2+2+2] Cycloaddition

(2014) Ryo Shintani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From an α-Functionalized Silicon-Stereogenic N,O-Silane to a Monomeric and TetracoordinatetBuLi Adduct with Lithium-Centered Chirality

(2014) Jonathan O. Bauer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Flexible Stereoselective Functionalizations of Ketones through Umpolung with Hypervalent Iodine Reagents

(2014) Pushpak Mizar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Synthesis of Silicon-Stereogenic Aminomethoxysilanes: Easy Access to Highly Enantiomerically Enriched Siloxanes

(2013) Jonathan O. Bauer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactivity Consequences of Substituent-Dependent Preaggregation Motifs ofn- andtert-Butyllithium towards 1,3,5-Triazacyclohexanes

(2013) Matthias Hülsmann et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Catalytic Synthesis of Functional Silicon-Stereogenic Silanes throughCandida antarcticaLipase B Catalyzed Remote Desymmetrization of Silicon-Centered Diols

(2013) Xing Lu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Desymmetrization Catalyzed by Transition-Metal Complexes: Enantioselective Formation of Silicon-Stereogenic Silanes

(2012) Li-Wen Xu   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Asymmetric Synthesis of Spirosilabifluorene Derivatives

(2012) Yoichiro Kuninobu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Synthesis of Alkenylhydrosilanes

(2012) Kazunobu Igawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-step conversion of methoxysilanes to aminosilanes: a convenient synthetic strategy to N,O-functionalised organosilanes

(2012) Jonathan O. Bauer et al.   CHEMICAL COMMUNICATIONS

Synthesis of optically active tertiary silanes via Pd-catalyzed enantioselective arylation of secondary silanes

(2012) Yu Kurihara et al.   CHEMICAL COMMUNICATIONS

Illuminating the Mechanism of the Borane-Catalyzed Hydrosilylation of Imines with Both an Axially Chiral Borane and Silane

(2012) Marius Mewald et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reinvestigation of the Pd-catalyzed bis(silylation) of alkynes with 1,1,2,2-tetramethyl-1,2-bis(phenylthiomethyl)disilane: Unexpected formation of the eight-membered siloxane–chelate complex cis-[PdCl2{(PhSCH2SiMe2)2O}]

(2012) Harmel W. Peindy N'dongo et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Palladium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles via Enantioselective C–H Bond Functionalization

(2012) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzooxasilines via Enantioselective Transmetalation

(2012) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Carbon–Silicon Bond Activation for Synthesis of Benzosilole Derivatives

(2012) Masahiro Onoe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Desymmetrization of Silacyclobutanes with Alkynes: Enantioselective Synthesis of Silicon-Stereogenic 1-Sila-2-cyclohexenes and Mechanistic Considerations

(2012) Ryo Shintani et al.   ORGANIC LETTERS

Removable Directing Groups in Organic Synthesis and Catalysis

(2011) Géraldine Rousseau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereomutation in Trigonal-Bipyramidal Systems: A Unified Picture

(2011) Christina Moberg   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Insights into the Reaction of Enantiomerically Pure Lithiosilanes and Electrophiles: Understanding the Differences between Aryl and Alkyl Halides

(2011) Christian Däschlein et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Palladium-Catalyzed Enantioselective Desymmetrization of Silacyclobutanes: Construction of Silacycles Possessing a Tetraorganosilicon Stereocenter

(2011) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nonhydrolytic Synthesis of Branched Alkoxysiloxane Oligomers Si[OSiH(OR)2]4 (R=Me, Et)

(2010) Ryutaro Wakabayashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The recent synthesis and application of silicon-stereogenic silanes: A renewed and significant challenge in asymmetric synthesis

(2010) Li-Wen Xu et al.   CHEMICAL SOCIETY REVIEWS

Silyl-Modified Analogues of 2-Tritylpyrrolidine: Synthesis and Applications in Asymmetric Organocatalysis

(2010) Jonathan O. Bauer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective (Formal) Aza-Diels−Alder Reactions with Non-Danishefsky-Type Dienes

(2010) Uttam K. Tambar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereomutation of Pentavalent Compounds: Validating the Berry Pseudorotation, Redressing Ugi’s Turnstile Rotation, and Revealing the Two- and Three-Arm Turnstiles

(2010) Erik P. A. Couzijn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium(III)-Catalyzed Enantioselective Si−H Bond Insertion and Formation of an Enantioenriched Silicon Center

(2010) Yoichi Yasutomi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lithiation of Diamine Ligands to Chiral Building Blocks: Syntheses, Selectivities, and Lithiated Intermediates

(2010) Viktoria H. Gessner et al.   ORGANOMETALLICS

From the Selective Cleavage of the Si-O-Si Bond in Disiloxanes to Zwitterionic, Water-Stable Zinc Silanolates

(2009) Christian Däschlein et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of Chiral Silacarboxylic Acids and Their Ester Derivatives

(2009) Kazunobu Igawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Ring-Closing Metathesis with a Twist

(2009) Hendrik F. T. Klare et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereocontrolled synthesis of tertiary silanes via optically pure 1,3,2-oxazasilolidine derivatives

(2009) Natsuhisa Oka et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Tandem Asymmetric Aza-Darzens/Ring-Opening Reactions: Dual Functionality from the Silane Lewis Acid

(2009) S. Corey Valdez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conclusive Evidence for an SN2-Si Mechanism in the B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Compounds: Implications for the Related Hydrogenation

(2008) Sebastian Rendler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frontside versus Backside SN2 Substitution at Group 14 Atoms: Origin of Reaction Barriers and Reasons for Their Absence

(2008) A. Patrícia Bento et al.   Chemistry-An Asian Journal

Enantioselective Synthesis of Silanol

(2008) Kazunobu Igawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structure/Reactivity Studies on an α-Lithiated Benzylsilane: Chemical Interpretation of Experimental Charge Density

(2008) Holger Ott et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Silicon Lewis Acid for Highly Enantioselective Mannich Reactions of Aliphatic Ketone-Derived Hydrazones

(2008) Gregory T. Notte et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lithiation of TMEDA and its Higher Homologous TEEDA: Understanding Observed α- and β-Deprotonation

(2008) Viktoria H. Gessner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly efficient molybdenum-based catalysts for enantioselective alkene metathesis

(2008) Steven J. Malcolmson et al.   NATURE

Kinetic Resolution and Desymmetrization by Stereoselective Silylation of Alcohols

(2007) Sebastian Rendler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stable Silanetriols That Containtert-Alkoxy Groups: Versatile Precursors of Siloxane-Based Nanomaterials

(2007) Jumpei Suzuki et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hypervalent Silicon versus Carbon: Ball-in-a-Box Model

(2007) Simon C. A. H. Pierrefixe et al.   CHEMISTRY-A EUROPEAN JOURNAL