Controllable Si−C Bond Activation Enables Stereocontrol in the Palladium-Catalyzed [4+2] Annulation of Cyclopropenes with Benzosilacyclobutanes

Rhodium-Catalyzed Reaction of Silacyclobutanes with Unactivated Alkynes to Afford Silacyclohexenes

(2019) Hua Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Rhodium-Catalyzed Desymmetric Hydrosilylation of Cyclopropenes

(2019) Zhi-Yuan Zhao et al.   ACS Catalysis

Intermolecular σ-Bond Cross-Exchange Reaction between Cyclopropenones and (Benzo)silacyclobutanes: Straightforward Access towards Sila(benzo)cycloheptenones

(2018) Wen-Tao Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Arylation of Cyclopropenes Based on Asymmetric Direct Functionalization of Three-Membered Carbocycles

(2018) Longyang Dian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Catalytic Preparation of Polysubstituted Cyclopropanol and Cyclopropylamine Derivatives

(2018) Marwan Simaan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

2-Arylsilacyclobutane as a Latent Carbanion Reacting with CO2

(2018) Naoki Ishida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Immobilized-Dirhodium Hollow-Fiber Flow Reactor for Scalable and Sustainable C−H Functionalization in Continuous Flow

(2018) Chun-Jae Yoo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of silacyclobutanes and their catalytic transformations enabled by transition-metal complexes

(2018) Qiu-Chao Mu et al.   COORDINATION CHEMISTRY REVIEWS

Cyclopropanations via Heme Carbenes: Basic Mechanism and Effects of Carbene Substituent, Protein Axial Ligand, and Porphyrin Substitution

(2018) Yang Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Seven-Membered Silacycle Construction: 1,7-Enyne Hydroxycyclization To Give a Benzosilepine Skeleton

(2018) Kohei Takamoto et al.   ORGANIC LETTERS

Diastereo- and enantioselective copper catalyzed hydroallylation of disubstituted cyclopropenes

(2018) Heiko Sommer et al.   Chemical Science

Asymmetric C(sp)–H Addition of Terminal Alkynes to Cyclopropenes by a Chiral Gadolinium Catalyst

(2018) Huai-Long Teng et al.   ACS Catalysis

Construction of Six-Membered Silacyclic Skeletons via Platinum-Catalyzed Tandem Hydrosilylation/Cyclization with Dihydrosilanes

(2018) Peng-Wei Long et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Preparation of Polysubstituted Cyclopropanes Based on Direct Functionalization of Achiral Three-Membered Carbocycles

(2018) Longyang Dian et al.   CHEMICAL REVIEWS

Comparison of Reactivity and Enantioselectivity between Chiral Bimetallic Catalysts: Bismuth-Rhodium and Dirhodium Catalyzed Carbene Chemistry

(2018) Zhi Ren et al.   ACS Catalysis

Highly efficient desymmetrization of cyclopropenes to azabicyclo[3.1.0]hexanes with five continuous stereogenic centers by copper-catalyzed [3 + 2] cycloadditions

(2018) Yang Yuan et al.   Organic Chemistry Frontiers

Synthesis of Myrocin G, the Putative Active Form of the Myrocin Antitumor Antibiotics

(2018) Christos Economou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereodivergent Asymmetric Carboamination/Annulation of Cyclopropenes with Aminoalkenes by Chiral Lanthanum Catalysts

(2017) Huai-Long Teng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Intermolecular Exchange between C–C and C–Si σ-Bonds

(2017) Shintaro Okumura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Nitrone Synthesis via Ligand-Enabled Copper-Catalyzed Cope-Type Hydroamination of Cyclopropene with Oxime

(2017) Zhanyu Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tandem Hydroalumination/Cu-Catalyzed Asymmetric Vinyl Metalation as a New Access to Enantioenriched Vinylcyclopropane Derivatives

(2017) Daniel S. Müller et al.   ORGANIC LETTERS

Synthesis of Chiral Aminocyclopropanes by Rare-Earth-Metal-Catalyzed Cyclopropene Hydroamination

(2016) Huai-Long Teng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Intramolecular C−H Silylation by Silacyclobutanes

(2016) Qing-Wei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Construction of Chiral Tetraorganosilicons by Tandem Desymmetrization of Silacyclobutanes/Intermolecular Dehydrogenative Silylation

(2016) Qing-Wei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Desymmetrization of Silacyclobutanes with Alkynes to Silicon-Stereogenic Silanes: A Density Functional Theory Study

(2016) Jin Zhang et al.   Chemistry-An Asian Journal

Recent Progress in Asymmetric Synthesis and Application of Difunctionalized Silicon-Stereogenic Silanes

(2016) Jonathan O. Bauer et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis and Olfactory Properties of Silicon-Containing Analogs of Rosamusk, Romandolide, and Applelide: Insights into the Structural Parameters of Linear Alicyclic Musks

(2016) Junhui Liu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Recent Progresses towards the Strengthening of Cyclopropene Chemistry

(2016) Rubén Vicente   SYNTHESIS-STUTTGART

An Inexpensive and Recyclable Silver-Foil Catalyst for the Cyclopropanation of Alkenes with Diazoacetates under Mechanochemical Conditions

(2015) Longrui Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Copper-Catalyzed Carbozincation of Cyclopropenes en Route to the Formation of Diastereo- and Enantiomerically Enriched Polysubstituted Cyclopropanes

(2015) Daniel S. Müller et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structurally diversified diterpenoids from Euphorbia dracunculoides

(2015) Li Wang et al.   TETRAHEDRON

Recent Advances in the Transition-Metal-Catalyzed Enantioselective Synthesis of Silicon-Stereogenic Organosilanes

(2015) Ryo Shintani   Asian Journal of Organic Chemistry

Six-Membered Silacycle Odorants: Synthesis and Olfactory Characterization of Si Analogues of Artemone, β-Dynascone, and Herbac

(2014) Junhui Liu et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Copper-Catalyzed Diastereo- and Enantioselective Desymmetrization of Cyclopropenes: Synthesis of Cyclopropylboronates

(2014) Alejandro Parra et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cleavage of C–C and C–Si σ-Bonds and Their Intramolecular Exchange

(2014) Naoki Ishida et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular donor–acceptor cyclopropane ring-opening cyclizations

(2013) Marchello A. Cavitt et al.   CHEMICAL SOCIETY REVIEWS

Silicon Ring Strain Creates High-Conductance Pathways in Single-Molecule Circuits

(2013) Timothy A. Su et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Desymmetrization Catalyzed by Transition-Metal Complexes: Enantioselective Formation of Silicon-Stereogenic Silanes

(2012) Li-Wen Xu   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formation of silacycles via metal-mediated or catalyzed Si-C bond cleavage

(2012) LiLi Wang et al.   CHINESE SCIENCE BULLETIN

Organosilicon Molecules with Medicinal Applications

(2012) Annaliese K. Franz et al.   JOURNAL OF MEDICINAL CHEMISTRY

Palladium-Catalyzed Desymmetrization of Silacyclobutanes with Alkynes: Enantioselective Synthesis of Silicon-Stereogenic 1-Sila-2-cyclohexenes and Mechanistic Considerations

(2012) Ryo Shintani et al.   ORGANIC LETTERS

Designing N-Heterocyclic Carbenes: Simultaneous Enhancement of Reactivity and Enantioselectivity in the Asymmetric Hydroacylation of Cyclopropenes

(2011) Fan Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent developments of cyclopropene chemistry

(2011) Zhi-Bin Zhu et al.   CHEMICAL SOCIETY REVIEWS

Conformational aspects in the studies of organic compounds by electronic circular dichroism

(2011) Gennaro Pescitelli et al.   CHEMICAL SOCIETY REVIEWS

Synopsis of Some Recent Tactical Application of Bioisosteres in Drug Design

(2011) Nicholas A. Meanwell   JOURNAL OF MEDICINAL CHEMISTRY

Palladium-Catalyzed Enantioselective Desymmetrization of Silacyclobutanes: Construction of Silacycles Possessing a Tetraorganosilicon Stereocenter

(2011) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The recent synthesis and application of silicon-stereogenic silanes: A renewed and significant challenge in asymmetric synthesis

(2010) Li-Wen Xu et al.   CHEMICAL SOCIETY REVIEWS

Asymmetric Si–O coupling of alcohols

(2010) Andreas Weickgenannt et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Ring expansion reactions of ethyl cyclopropylideneacetate and benzosilacyclobutenes: formal σ bond cross metathesis

(2010) Shinichi Saito et al.   TETRAHEDRON LETTERS

Palladium-Catalyzed Formal Cycloaddition of Silacyclobutanes with Enones: Synthesis of Eight-Membered Cyclic Silyl Enolates

(2008) Koji Hirano et al.   ORGANIC LETTERS