Rhodium-Catalyzed Synthesis of Chiral Spiro-9-silabifluorenes by Dehydrogenative Silylation: Mechanistic Insights into the Construction of Tetraorganosilicon Stereocenters

Catalytic Enantioselective Construction of Quaternary Stereocenters: Assembly of Key Building Blocks for the Synthesis of Biologically Active Molecules

(2015) Yiyang Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Rhodium-Catalyzed Enantioselective Intramolecular CH Silylation for the Syntheses of Planar-Chiral Metallocene Siloles

(2015) Qing-Wei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhenium-catalysed dehydrogenative borylation of primary and secondary C(sp3)–H bonds adjacent to a nitrogen atom

(2015) Masahito Murai et al.   CHEMICAL COMMUNICATIONS

Rhodium-catalyzed intramolecular alkynylsilylation of alkynes

(2015) Ryo Shintani et al.   CHEMICAL COMMUNICATIONS

Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C–H silylation

(2015) Takanori Shibata et al.   CHEMICAL COMMUNICATIONS

Catalytic Silylation of Unactivated C–H Bonds

(2015) Chen Cheng et al.   CHEMICAL REVIEWS

Iridium-Catalyzed Intermolecular Dehydrogenative Silylation of Polycyclic Aromatic Compounds without Directing Groups

(2015) Masahito Murai et al.   CHEMISTRY-A EUROPEAN JOURNAL

Acceleration Effects of Phosphine Ligands on the Rhodium-Catalyzed Dehydrogenative Silylation and Germylation of Unactivated C(sp3)–H Bonds

(2015) Masahito Murai et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Enantioselective Silylation of Arene C–H Bonds: Desymmetrization of Diarylmethanols

(2015) Taegyo Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Dehydrogenative Silylation of Azulenes Based on Regioselective C–H Bond Activation

(2015) Masahito Murai et al.   ORGANIC LETTERS

Rhodium-Catalyzed Synthesis of Benzosilolometallocenes via the Dehydrogenative Silylation of C(sp2)–H Bonds

(2015) Masahito Murai et al.   ORGANIC LETTERS

Recent advances in C–Si bond activation via a direct transition metal insertion

(2015) Linjie Li et al.   TETRAHEDRON LETTERS

Recent Advances in the Transition-Metal-Catalyzed Enantioselective Synthesis of Silicon-Stereogenic Organosilanes

(2015) Ryo Shintani   Asian Journal of Organic Chemistry

Palladium-Catalyzed CH Fluorosilylation of 2-Phenylpyridines: Synthesis of Silafluorene Equivalents

(2014) Qing Xiao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanism of the Rhodium-Catalyzed Silylation of Arene C–H Bonds

(2014) Chen Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Planar Chiral Tetrasubstituted [2.2]Paracyclophane: Optical Resolution and Functionalization

(2014) Yasuhiro Morisaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis and Enhanced Circularly Polarized Luminescence of S-Shaped Double Azahelicenes

(2014) Kyosuke Nakamura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Dehydrogenative Germylation of C–H Bonds: New Entry to Unsymmetrically Functionalized 9-Germafluorenes

(2014) Masahito Murai et al.   ORGANIC LETTERS

B(C6F5)3-Catalyzed Synthesis of Benzofused-Siloles

(2014) Liam D. Curless et al.   ORGANOMETALLICS

Palladium-Catalyzedortho-Selective CH Borylation of 2-Phenylpyridine and Its Derivatives at Room Temperature

(2013) Yoichiro Kuninobu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

POP-Pincer Silyl Complexes of Group 9: Rhodium versus Iridium

(2013) Miguel A. Esteruelas et al.   INORGANIC CHEMISTRY

Spirosilane Derivatives as Fluoride Sensors

(2013) Hugo Lenormand et al.   ORGANIC LETTERS

Rhodium-Catalyzed Intramolecular Silylation of Unactivated C(sp3)–H Bonds

(2013) Yoichiro Kuninobu et al.   ORGANIC LETTERS

Facile Synthetic Route to Highly Luminescent Sila[7]helicene

(2013) Hiromi Oyama et al.   ORGANIC LETTERS

Synthesis and Photophysical Properties of Asymmetric Substituted Silafluorenes

(2013) Erika Pusztai et al.   ORGANOMETALLICS

Desymmetrization Catalyzed by Transition-Metal Complexes: Enantioselective Formation of Silicon-Stereogenic Silanes

(2012) Li-Wen Xu   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Asymmetric Synthesis of Spirosilabifluorene Derivatives

(2012) Yoichiro Kuninobu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular Oxidative Annulation of 2-Aminoanthracenes to Diazaacenes and Aza[7]helicenes

(2012) Kiyohiko Goto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organosilicon Molecules with Medicinal Applications

(2012) Annaliese K. Franz et al.   JOURNAL OF MEDICINAL CHEMISTRY

Palladium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles via Enantioselective C–H Bond Functionalization

(2012) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzooxasilines via Enantioselective Transmetalation

(2012) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Carbon–Silicon Bond Activation for Synthesis of Benzosilole Derivatives

(2012) Masahiro Onoe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Enantioselective Synthesis, Crystal Structures, and Photophysical Properties of Helically Chiral 1,1′-Bitriphenylenes

(2012) Yayoi Sawada et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Desymmetrization of Silacyclobutanes with Alkynes: Enantioselective Synthesis of Silicon-Stereogenic 1-Sila-2-cyclohexenes and Mechanistic Considerations

(2012) Ryo Shintani et al.   ORGANIC LETTERS

General and Practical One-Pot Synthesis of Dihydrobenzosiloles from Styrenes

(2012) Alexey Kuznetsov et al.   ORGANIC LETTERS

Hierarchical Assembly of a Phthalhydrazide-Functionalized Helicene

(2011) Takahiro Kaseyama et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Synthesis of Dibenzophosphole Oxides via Intramolecular Dehydrogenative Cyclization

(2011) Yoichiro Kuninobu et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Enantioselective Desymmetrization of Silacyclobutanes: Construction of Silacycles Possessing a Tetraorganosilicon Stereocenter

(2011) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemical-Stimuli-Controllable Circularly Polarized Luminescence from Anion-Responsive π-Conjugated Molecules

(2011) Hiromitsu Maeda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Kumada Cross-Coupling Reactions of Tertiary Alkylmagnesium Halides and Aryl Bromides/Triflates

(2011) Amruta Joshi-Pangu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(I)-Catalyzed 1,4-Silicon Shift of Unactivated Silanes from Aryl to Alkyl: Enantioselective Synthesis of Indanol Derivatives

(2010) Tobias Seiser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The recent synthesis and application of silicon-stereogenic silanes: A renewed and significant challenge in asymmetric synthesis

(2010) Li-Wen Xu et al.   CHEMICAL SOCIETY REVIEWS

Application of the sila-Friedel–Crafts reaction to the synthesis of π-extended silole derivatives and their properties

(2010) Shunsuke Furukawa et al.   DALTON TRANSACTIONS

Rhodium-Catalyzed Synthesis of Silafluorene Derivatives via Cleavage of Silicon−Hydrogen and Carbon−Hydrogen Bonds

(2010) Tomonari Ureshino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Si–O coupling of alcohols

(2010) Andreas Weickgenannt et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Substituent effects on the electronic structure of siloles

(2009) Xiaowei Zhan et al.   CHEMICAL COMMUNICATIONS

Synthesis and applications of silicon-containing α-amino acids

(2009) Matthew Mortensen et al.   CHEMICAL SOCIETY REVIEWS

Ladder π-Conjugated Materials Containing Main-Group Elements

(2009) Aiko Fukazawa et al.   Chemistry-An Asian Journal

Development of a Sila-Friedel−Crafts Reaction and Its Application to the Synthesis of Dibenzosilole Derivatives

(2009) Shunsuke Furukawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Configurationally Rigid Pentaorganosilicates

(2009) Erik P. A. Couzijn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Silanol

(2008) Kazunobu Igawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY