Palladium-catalyzed selective C–C bond cleavage and stereoselective alkenylation between cyclopropanol and 1,3-diyne: one-step synthesis of diverse conjugated enynes

Palladium-Catalyzed C–C Bond Activation of Cyclopropenone: Modular Access to Trisubstituted α,β-Unsaturated Esters and Amides

(2021) Tanmayee Nanda et al.   JOURNAL OF ORGANIC CHEMISTRY

Additive-Controlled Divergent Synthesis of Tetrasubstituted 1,3-Enynes and Alkynylated 3H-Pyrrolo[1,2-a]indol-3-ones via Rhodium Catalysis

(2021) Fei Zhao et al.   ORGANIC LETTERS

Enantioselective Conjugate Addition of Catalytically Generated Zinc Homoenolate

(2021) Yoshiya Sekiguchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Controlled Regiodivergent Nickel-Catalyzed Hydrocyanation of Silyl-Substituted 1,3-Diynes

(2021) Feilong Sun et al.   ORGANIC LETTERS

Arene diversification through distal C(sp2)−H functionalization

(2021) Uttam Dutta et al.   SCIENCE

Tailored Palladium Catalysts for Selective Synthesis of Conjugated Enynes via Monocarbonylation of 1,3-Diynes

(2020) Jiawang Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Palladium-Catalyzed Cascade C–C Activation of Cyclopropenone and Carbonylative Amination: Easy Access to Highly Functionalized Maleimide Derivatives

(2020) Tanmayee Nanda et al.   ORGANIC LETTERS

Ru(II)-Catalyzed C–H Functionalization of N-Hydroxyoximes with 1,3-Diynes Unveils a Regioselective Disparity

(2020) Shreemoyee Kumar et al.   ORGANIC LETTERS

Rhodium-Catalyzed Room Temperature C–C Activation of Cyclopropanol for One-Step Access to Diverse 1,6-Diketones

(2020) Bedadyuti Vedvyas Pati et al.   ORGANIC LETTERS

Palladium-Catalyzed meta-C–H Allylation of Arenes: A Unique Combination of a Pyrimidine-Based Template and Hexafluoroisopropanol

(2020) Sukdev Bag et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Denitrogenative Cross-Coupling of Benzotriazinones and Cyclopropanols: An Easy Access to Functionalized β-Aryl Ketones

(2020) Jincan Li et al.   ORGANIC LETTERS

Cobalt‐Catalyzed Diastereo‐ and Enantioselective Hydroalkylation of Cyclopropenes with Cobalt‐Homoenolates

(2020) Wei Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Carbon–Carbon Bond Cleavage of Cyclopropanols

(2020) Tyler R. McDonald et al.   CHEMICAL REVIEWS

Traceless Bidentate Directing Group Assisted Cobalt-Catalyzed sp2-C–H Activation and [4 + 2]-Annulation Reaction with 1,3-Diynes

(2020) Arnab Dey et al.   ORGANIC LETTERS

Cobalt-Catalyzed Regio- and Diastereoselective Formal [3 + 2] Cycloaddition between Cyclopropanols and Allenes

(2019) Junfeng Yang et al.   ACS Catalysis

Cobalt-Catalyzed N–O and C–C Bond Cleavage in 1,2-Oxazetidines: Solvent-Controlled C–H Aminomethylation and Hydroxymethylation of Heteroarenes

(2019) Song Li et al.   ORGANIC LETTERS

Deacylative transformations of ketones via aromatization-promoted C–C bond activation

(2019) Yan Xu et al.   NATURE

Enantioselective Aza-Heck Cyclizations of N-(Tosyloxy)carbamates: Synthesis of Pyrrolidines and Piperidines

(2019) Xiaofeng Ma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium‐Catalyzed Copper‐Assisted Intermolecular Domino C−H Annulation of 1,3‐Diynes with Picolinamides: Access to Pentacyclic π‐Extended Systems

(2019) Ángel Manu Martínez et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cobalt-Catalyzed Enantioselective and Chemodivergent Addition of Cyclopropanols to Oxabicyclic Alkenes

(2019) Junfeng Yang et al.   ACS Catalysis

Cobaltaelectro-Catalyzed Oxidative C–H/N–H Activation with 1,3-Diynes by Electro-Removable Hydrazides

(2019) Ruhuai Mei et al.   ORGANIC LETTERS

Ni-Catalyzed β-Alkylation of Cyclopropanol-Derived Homoenolates

(2019) L. Reginald Mills et al.   ORGANIC LETTERS

Cobalt-Catalyzed Regiodivergent Stereoselective Hydroboration of 1,3-Diynes To Access Boryl-Functionalized Enynes

(2019) Hui Leng Sang et al.   ACS Catalysis

Pd-catalyzed reactions of cyclopropanols, cyclobutanols and cyclobutenols

(2019) Jean Le Bras et al.   TETRAHEDRON

Highly Selective Synthesis of 1,3-Enynes, Pyrroles, and Furans by Manganese(I)-Catalyzed C–H Activation

(2019) Sara Cembellín et al.   ACS Catalysis

Intermolecular Metal-Catalyzed Reductive Coupling of Dienes, Allenes, and Enynes with Carbonyl Compounds and Imines

(2018) Michael Holmes et al.   CHEMICAL REVIEWS

Zirconocene-Mediated Selective C–C Bond Cleavage of Strained Carbocycles: Scope and Mechanism

(2018) Jeffrey Bruffaerts et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Synthesis of Trisubstituted Allenyl–B(pin) Compounds by Phosphine–Cu-Catalyzed 1,3-Enyne Hydroboration. Insights Regarding Stereochemical Integrity of Cu–Allenyl Intermediates

(2018) Youming Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Concise Synthesis of (−)-Cycloclavine and (−)-5-epi-Cycloclavine via Asymmetric C–C Activation

(2018) Lin Deng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Divergent ring-opening coupling between cyclopropanols and alkynes under cobalt catalysis

(2018) Junfeng Yang et al.   Chemical Science

Catalytic Cyclopropanol Ring Opening for Divergent Syntheses of γ-Butyrolactones and δ-Ketoesters Containing All-Carbon Quaternary Centers

(2018) Zhishi Ye et al.   ACS Catalysis

One-pot Synthesis of Alkynylated Coumarins via Rhodium-Catalyzed Annulation of Aryl Thiocarbamates with 1,3-Diynes or Terminal Alkynes

(2018) Yuan Gao et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed Hydroalkylation of Alkynes with Cyclopropanols: Access to γ,δ-Unsaturated Ketones

(2018) Hao Liu et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic activations of unstrained C–C bond involving organometallic intermediates

(2018) Feijie Song et al.   CHEMICAL SOCIETY REVIEWS

A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

(2018) Carlo Sambiagio et al.   CHEMICAL SOCIETY REVIEWS

Cobalt‐Catalyzed Temperature‐Dependent Annulation of 3‐Aryl‐1,2,4‐oxadiazolones with 1,3‐Diynes: An Approach to π‐Conjugated Molecules

(2018) Wenge Zhang et al.   ADVANCED SYNTHESIS & CATALYSIS

3d Transition Metals for C–H Activation

(2018) Parthasarathy Gandeepan et al.   CHEMICAL REVIEWS

Copper-Catalyzed Radical 1,4-Difunctionalization of 1,3-Enynes with Alkyl Diacyl Peroxides and N-Fluorobenzenesulfonimide

(2018) Xiaotao Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular trans-Carbocarbonation of Internal Alkynes by a Cascade of Formal anti-Carbopalladation/Cyclopropanol Opening

(2018) Andreas Reding et al.   ORGANIC LETTERS

Selective Synthesis of Alkynylated Isoquinolines and Biisoquinolines via RhIII Catalyzed C–H Activation/1,3-Diyne Strategy

(2017) Ruokun Feng et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of γ-keto sulfones by copper-catalyzed oxidative sulfonylation of tertiary cyclopropanols

(2017) Yulia A. Konik et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Cobalt Catalyzed, Regioselective C(sp2)–H Activation of Amides with 1,3-Diynes

(2017) Subban Kathiravan et al.   ORGANIC LETTERS

“Cut and Sew” Transformations via Transition-Metal-Catalyzed Carbon–Carbon Bond Activation

(2017) Peng-hao Chen et al.   ACS Catalysis

Transition-Metal-Catalyzed C–H Bond Addition to Carbonyls, Imines, and Related Polarized π Bonds

(2016) Joshua R. Hummel et al.   CHEMICAL REVIEWS

Potential of Metal-Catalyzed C–C Single Bond Cleavage for Organic Synthesis

(2016) Masahiro Murakami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Formal [4 + 1] Cycloaddition of Biphenylenes with Alkenes Initiated by C–C Bond Cleavage for the Synthesis of 9,9-Disubstituted Fluorenes

(2016) Hideaki Takano et al.   ORGANIC LETTERS

Mechanism of Ru(II)-Catalyzed Rearrangements of Allenyl- and Alkynylcyclopropanols to Cyclopentenones

(2016) Eppa Gyanchander et al.   ORGANIC LETTERS

All-Carbon [3+3] Oxidative Annulations of 1,3-Enynes by Rhodium(III)-Catalyzed CH Functionalization and 1,4-Migration

(2015) David J. Burns et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic C–C Bond Activations via Oxidative Addition to Transition Metals

(2015) Laetitia Souillart et al.   CHEMICAL REVIEWS

Oxidative Addition of Haloheteroarenes to Palladium(0): Concerted versus SNAr-Type Mechanism

(2015) Bert U. W. Maes et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-catalysed ring-opening trifluoromethylation of cyclopropanols

(2015) Xia-Ping He et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

An Umpolung Strategy for the Synthesis of β-Aminoketones via Copper-Catalyzed Electrophilic Amination of Cyclopropanols

(2015) Zhishi Ye et al.   ORGANIC LETTERS

Copper-Catalyzed Cyclopropanol Ring Opening Csp3–Csp3 Cross-Couplings with (Fluoro)Alkyl Halides

(2015) Zhishi Ye et al.   ORGANIC LETTERS

Efficient Synthesis of β-CF3/SCF3-Substituted Carbonyls via Copper-Catalyzed Electrophilic Ring-Opening Cross-Coupling of Cyclopropanols

(2015) Yong Li et al.   ORGANIC LETTERS

Cobalt-Catalyzed C–H Activation

(2015) Marc Moselage et al.   ACS Catalysis

The CH Activation/1,3-Diyne Strategy: Highly Selective Direct Synthesis of Diverse Bisheterocycles by RhIIICatalysis

(2014) Da-Gang Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in Transition-Metal-Catalyzed Functionalization of Unstrained Carbon–Carbon Bonds

(2014) Feng Chen et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Cross-Coupling of Benzyl Chlorides with Cyclopropanol-Derived Ketone Homoenolates

(2014) Nisha Nithiy et al.   ORGANIC LETTERS

Catalytic Functionalization of C(sp2)H and C(sp3)H Bonds by Using Bidentate Directing Groups

(2013) Guy Rouquet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed cross-coupling of cyclopropanol-derived ketone homoenolates with aryl bromides

(2013) David Rosa et al.   CHEMICAL COMMUNICATIONS

C–H nitrogenation and oxygenation by ruthenium catalysis

(2013) Vedhagiri S. Thirunavukkarasu et al.   CHEMICAL COMMUNICATIONS

Chemicals from Alkynes with Palladium Catalysts

(2013) Rafael Chinchilla et al.   CHEMICAL REVIEWS

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

Arylation of Aldehyde Homoenolates with Aryl Bromides

(2013) Kevin Cheng et al.   ORGANIC LETTERS

C-Acylation of Cyclopropanols: Preparation of Functionalized 1,4-Diketones

(2013) Bibhuti Bhusan Parida et al.   ORGANIC LETTERS

Synthesis of Aromatic Compounds by Catalytic CC Bond Activation of Biphenylene or Angular [3]Phenylene

(2012) Aleš Korotvička et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transition-Metal-Mediated Cleavage and Activation of C-C Single Bonds

(2012) Klaus Ruhland   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Activated Phenacenes from Phenylenes by Nickel-Catalyzed Alkyne Cycloadditions

(2011) Zhenhua Gu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Solvent Effect on Palladium-Catalyzed Cross-Coupling Reactions and Implications on the Active Catalytic Species

(2011) Fabien Proutiere et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-catalysed cleavage of carbon–carbon bonds

(2010) Masahiro Murakami et al.   CHEMICAL COMMUNICATIONS

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

(2010) Stefan Grimme et al.   JOURNAL OF CHEMICAL PHYSICS

DFT Study of Electronic Properties of 3d Metal Complexes of σ-Geminal Diethynylethenes (gem-DEEs)

(2010) Zhi Cao et al.   ORGANOMETALLICS

Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions

(2009) Aleksandr V. Marenich et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Tetrasubstituted Furans by a PdII-Catalyzed Three-Component Michael Addition/Cyclization/Cross-Coupling Reaction

(2008) Yuanjing Xiao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Optical Properties of all-trans-Oligodiacetylenes

(2008) Gregor S. Pilzak et al.   CHEMISTRY-A EUROPEAN JOURNAL

Tandem Rh(I)-Catalyzed [(5+2)+1] Cycloaddition/Aldol Reaction for the Construction of Linear Triquinane Skeleton:  Total Syntheses of (±)-Hirsutene and (±)-1-Desoxyhypnophilin

(2008) Lei Jiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY