Transition-Metal-Mediated Cleavage and Activation of C-C Single Bonds

Allyl-, Allenyl-, and Propargyl-Transfer Reactions through Cleavage of CC Bonds Catalyzed by an N-Heterocyclic Carbene/Copper Complex: Synthesis of Multisubstituted Pyrroles

(2011) Masahiro Sai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Nature of β-Agostic Bonding in Late-Transition-Metal Alkyl Complexes

(2011) Wolfgang Scherer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Acylation with Quinolinyl Ketones: Carbon−Carbon Single Bond Activation as the Turnover-Limiting Step of Catalysis

(2011) Colin M. Rathbun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pyridinyl Directed Alkenylation with Olefins via Rh(III)-Catalyzed C–C Bond Cleavage of Secondary Arylmethanols

(2011) Hu Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–C Activation in the Solid State in an Organometallic σ-Complex

(2011) Adrian B. Chaplin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of an Unstrained C(sp2)–C(sp2) Single Bond Using Chelate-Bisphosphinite Rhodium(I) Complexes

(2011) Andreas Obenhuber et al.   ORGANOMETALLICS

Palladium-Catalyzed Hydrometalation and Bismetalation of Biphenylene

(2011) Takanori Matsuda et al.   ORGANOMETALLICS

Controlling the Selectivity for C–H and C–CN Bond Activation at Rhodium: A DFT Examination of Ligand Effects

(2011) Meagan E. Evans et al.   ORGANOMETALLICS

Palladium-Catalyzed Arylative Ring-Opening Reactions of Norbornenols: Entry to Highly Substituted Cyclohexenes, Quinolines, and Tetrahydroquinolines

(2010) Michael Waibel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

General and highly active catalyst for mono and double Hiyama coupling reactions of unreactive aryl chlorides in water

(2010) Dong-Hwan Lee et al.   CHEMICAL COMMUNICATIONS

Metal-catalysed cleavage of carbon–carbon bonds

(2010) Masahiro Murakami et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Allylation of Aryl Halides with Homoallyl Alcohols Bearing a Trisubstituted Double Bond: Application to Chirality Transfer from Hydroxylated Carbon to Benzylic One

(2010) Ryota Wakabayashi et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Decarboxylative Cross-Coupling Reaction Between Heteroaromatic Carboxylic Acids and Aryl Halides

(2010) François Bilodeau et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed C−C Bond Cleavage: Construction of Acyclic Methyl Substituted Quaternary Stereogenic Centers

(2010) Tobias Seiser et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metalloradical-Catalyzed Aliphatic Carbon−Carbon Activation of Cyclooctane

(2010) Yun Wai Chan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Arylative Ring-Opening of 3-Methylenecycloalkane-1,1-dicarboxylates

(2010) Yuto Sumida et al.   ORGANIC LETTERS

Rhodium-Catalyzed Direct Alkenylation and Arylation of Arene C−H Bonds via Decarbonylation of Cinnamoyl Chlorides, Cinnamic Anhydrides, and Poly(aroyl) Chlorides

(2010) Wenjing Ye et al.   ORGANOMETALLICS

C−C Bond Activation of a Cyclopropyl Phosphine: Isolation and Reactivity of a Tetrameric Rhodacyclobutane

(2010) Adrian B. Chaplin et al.   ORGANOMETALLICS

Comparison of the Thermal and Reductive Decarbonylation of a Rhodium Trifluoroacetyl Diphosphine Complex

(2010) Basu D. Panthi et al.   ORGANOMETALLICS

Cleavage of Carbonyl Carbon and α-Carbon Bond of Acetophenones by Iridium(III) Porphyrin Complexes

(2010) Bao Zhu Li et al.   ORGANOMETALLICS

Activation of a Nonstrained C(sp2)−C(sp2) Single Bond in a Vaska Complex Analogue Using Chelating Assistance

(2010) Andreas Obenhuber et al.   ORGANOMETALLICS

Metal-Mediated Retro-Allylation of Homoallyl Alcohols for Highly Selective Organic Synthesis

(2009) Hideki Yorimitsu et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Microwave-Assisted Cu-Catalyzed Protodecarboxylation of Aromatic Carboxylic Acids

(2009) Lukas J. Goossen et al.   JOURNAL OF ORGANIC CHEMISTRY

Charge Density Analysis of the (C−C)→Ti Agostic Interactions in a Titanacyclobutane Complex

(2009) Stephan Scheins et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Theoretical Analysis of Factors Controlling Pd-Catalyzed Decarboxylative Coupling of Carboxylic Acids with Olefins

(2009) Song-Lin Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Catalyzed Protodecarboxylation of Heteroaromatic Carboxylic Acids†

(2009) Pengfei Lu et al.   ORGANIC LETTERS

Leaving Group Potential of a Substituted Cyclopentadienyl Anion Toward Oxidative Addition

(2009) Ethan L. Fisher et al.   ORGANIC LETTERS

Reactivity Differences of Pt0Phosphine Complexes in C−C Bond Activation of Asymmetric Acetylenes

(2009) Ahmet Gunay et al.   ORGANOMETALLICS

Base-Promoted, Selective Aliphatic Carbon−Carbon Bond Cleavage of Ethers by Rhodium(III) Porphyrin Complexes

(2009) Tsz Ho Lai et al.   ORGANOMETALLICS

Metal−Organic Cooperative Catalysis in C−H and C−C Bond Activation and Its Concurrent Recovery

(2008) Young Jun Park et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Catalyzed Direct (Hetero)arylation of Ethyl Oxazole-4-carboxylate: An Efficient Access to (Hetero)aryloxazoles

(2008) Cécile Verrier et al.   JOURNAL OF ORGANIC CHEMISTRY

The comonomer inducing selective β-methyl elimination chain transfer: A new approach for end-functionalizations of syndiotactic polypropylene-based copolymers

(2008) Wen-Fu Lin et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Synthesis of Arylallenes by Palladium-Catalyzed Retro-Propargylation of Homopropargyl Alcohols

(2008) Sayuri Hayashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Intramolecular Arylcyanation of Unactivated Olefins via C−CN Bond Activation

(2008) Mary P. Watson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Mechanism for the Rhodium-Catalyzed Decarbonylation of Aldehydes: A Combined Experimental and Theoretical Study

(2008) Peter Fristrup et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon−Carbon Bond Activation of 2,2,6,6-Tetramethyl-piperidine-1-oxyl by a RhIIMetalloradical:  A Combined Experimental and Theoretical Study

(2008) Kin Shing Chan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Arylcyanation of Alkenes Catalyzed by Nickel/AlMe2Cl

(2008) Yoshiaki Nakao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Carbon−Carbon σ Bond Activation: An Intramolecular Carbo-Acylation Reaction with Acylquinolines

(2008) Ashley M. Dreis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Allylation of Allyl Carbonates with Homoallyl Alcohols via Retro-Allylation Providing 1,5-Hexadienes

(2008) Yuto Sumida et al.   ORGANIC LETTERS

Rhodium-Catalyzed Kinetic Resolution of Tertiary Homoallyl Alcohols via Stereoselective Carbon−Carbon Bond Cleavage

(2008) Ryo Shintani et al.   ORGANIC LETTERS

Access to Ruthenium(0) Carbonyl Complexes via Dehydrogenation of a Tricyclopentylphosphine Ligand and Decarbonylation of Alcohols

(2008) Paul D. Bolton et al.   ORGANOMETALLICS

Cleavage of Unstrained C(sp2)C(sp2) Single Bonds with Ni0Complexes Using Chelating Assistance

(2008) Klaus Ruhland et al.   ORGANOMETALLICS

Experimental and Theoretical Examination of C−CN Bond Activation of Benzonitrile Using Zerovalent Nickel

(2008) Tülay A. Ateşin et al.   ORGANOMETALLICS

Insertions of Ketones and Nitriles into Organorhodium(I) Complexes and β-Hydrocarbyl Eliminations from Rhodium(I) Alkoxo and Iminyl Complexes

(2008) Pinjing Zhao et al.   ORGANOMETALLICS