An Olefinic 1, 2‐ α ‐Boryl Migration Enables 1, 2‐Bis (boronic esters) via Radical‐Polar Crossover Reaction

Passerini-type reaction of boronic acids enables α-hydroxyketones synthesis

(2021) Kai Yang et al.   Nature Communications

Photoinduced NaI‐Promoted Radical Borylation of Alkyl Halides and Pseudohalides

(2021) Chenglan Wang et al.   CHINESE JOURNAL OF CHEMISTRY

Tetracoordinate Boron Intermediates Enable Unconventional Transformations

(2021) Kai Yang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Radical Aryl Migration from Boron to Carbon

(2021) Dinghai Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light-Driven Strain-Increase Ring Contraction Allows the Synthesis of Cyclobutyl Boronic Esters

(2020) Raffael Davenport et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

1,3-Difunctionalizations of [1.1.1]Propellane via 1,2-Metallate Rearrangements of Boronate Complexes

(2020) Songjie Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

1,n-Bisborylalkanes via Radical Boron Migration

(2020) Dinghai Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu-Catalyzed Regio- and Stereodivergent Chemoselective sp/sp 1,3- and 1,4-Diborylations of CF3-Containing 1,3-Enynes

(2020) Zhijie Kuang et al.   Chem

An Olefinic 1,2-Boryl-Migration Enabled by Radical Addition: Construction of gem -Bis(boryl)alkanes

(2019) Binlin Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereospecific 1,4-Metallate Shift Enables Stereoconvergent Synthesis of Ketoximes

(2019) Qiuling Song et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

1,2-Boron Shifts of β-Boryl Radicals Generated from Bis-boronic Esters Using Photoredox Catalysis

(2019) Daniel Kaiser et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of α-Chiral Ketones and Chiral Alkanes Using Radical Polar Crossover Reactions of Vinyl Boron Ate Complexes

(2018) Carolin Gerleve et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Radical-Triggered Three-Component Coupling Reaction of Alkenylboronates, α-Halocarbonyl Compounds, and Organolithium Reagents: The Inverse Ylid Mechanism

(2018) Nicholas D. C. Tappin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Radical-Polar Crossover Reactions of Dienylboronate Complexes: Synthesis of Functionalized Allylboronic Esters

(2018) Marvin Kischkewitz et al.   ORGANIC LETTERS

Functionalized geminal-diborylalkanes from various electron-deficient alkynes and B2pin2

(2018) Guoliang Gao et al.   Organic Chemistry Frontiers

Base-controlled highly selective synthesis of alkyl 1,2-bis(boronates) or 1,1,2-tris(boronates) from terminal alkynes

(2017) Guoliang Gao et al.   GREEN CHEMISTRY

Merging Photoredox with 1,2-Metallate Rearrangements: The Photochemical Alkylation of Vinyl Boronate Complexes

(2017) Mattia Silvi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Enantioselective Conjunctive Coupling with C(sp3) Electrophiles: A Radical-Ionic Mechanistic Dichotomy

(2017) Gabriel J. Lovinger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Radical-polar crossover reactions of vinylboron ate complexes

(2017) Marvin Kischkewitz et al.   SCIENCE

Selective uni- and bidirectional homologation of diborylmethane

(2017) Daniel J. Blair et al.   Chemical Science

Nickel-catalyzed synthesis of 1,1-diborylalkanes from terminal alkenes

(2017) Lei Li et al.   Nature Communications

Synthesis and Reactivity of 1,1-Diborylalkanes towards C-C Bond Formation and Related Mechanisms

(2017) Núria Miralles et al.   ADVANCED SYNTHESIS & CATALYSIS

Carbohydrate-Catalyzed Enantioselective Alkene Diboration: Enhanced Reactivity of 1,2-Bonded Diboron Complexes

(2016) Lichao Fang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Applications of Boronic Acid-Containing Polymers: From Materials to Medicine

(2015) William L. A. Brooks et al.   CHEMICAL REVIEWS

Asymmetric synthesis of optically active 3-amino-1,2-diols from N-acyl-protected allylamines via catalytic diboration with Rh[bis(oxazolinyl)phenyl] catalysts

(2015) Kenji Toribatake et al.   TETRAHEDRON

Stereospecific Couplings of Secondary and Tertiary Boronic Esters

(2014) Daniele Leonori et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydroxyl-Directed Stereoselective Diboration of Alkenes

(2014) Thomas P. Blaisdell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Diboration of Terminal Alkenes with a Rhodium Catalyst and Subsequent Oxidation: Enantioselective Synthesis of Optically Active 1,2-Diols

(2013) Kenji Toribatake et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Introduction of Fluorine and Fluorine-Containing Functional Groups

(2013) Theresa Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selection of boron reagents for Suzuki–Miyaura coupling

(2013) Alastair J. J. Lennox et al.   CHEMICAL SOCIETY REVIEWS

Scope and Mechanism of the Pt-Catalyzed Enantioselective Diboration of Monosubstituted Alkenes

(2013) John R. Coombs et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Exploiting the Reversible Covalent Bonding of Boronic Acids: Recognition, Sensing, and Assembly

(2012) Steven D Bull et al.   ACCOUNTS OF CHEMICAL RESEARCH

A “Renaissance” in Radical Trifluoromethylation

(2012) Armido Studer   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Free Diboration Reaction by Activation of Diboron Compounds with Simple Lewis Bases

(2011) Amadeu Bonet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cross-Coupling Reactions Of Organoboranes: An Easy Way To Construct CC Bonds (Nobel Lecture)

(2011) Akira Suzuki   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pt-Catalyzed Enantioselective Diboration of Terminal Alkenes with B2(pin)2

(2009) Laura T. Kliman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS