Rhodium(II)-Catalyzed Regioselective Remote C–H Alkylation of Protic Indoles

Alkyne Linchpin Strategy for Drug:Pharmacophore Conjugation: Experimental and Computational Realization of a Meta-Selective Inverse Sonogashira Coupling

(2020) Sandip Porey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Achieving Site-Selectivity for C–H Activation Processes Based on Distance and Geometry: A Carpenter’s Approach

(2020) Guangrong Meng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C7‐Indole Amidations and Alkenylations by Ruthenium(II) Catalysis

(2020) Isaac Choi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-Catalyzed Remote C5–H Selenylation of Indoles

(2020) Wei-Hong Song et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Diarylcarbene Insertion into Si–H Bonds Induced by Electronic Properties of the Carbenes

(2020) Liang-Liang Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C-H Functionalization Reactions of Unprotected N-Heterocycles by Gold-Catalyzed Carbene Transfer

(2020) Sripati Jana et al.   ACS Catalysis

Iron-Catalyzed Highly para-Selective Difluoromethylation of Arenes

(2020) Wei-Tai Fan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Peptide Late-Stage Diversifications by Rhodium-Catalyzed Tryptophan C7 Amidation

(2020) Wei Wang et al.   Chem

Hydrogen Bond-Accelerated meta-Selective C–H Borylation of Aromatic Compounds and Expression of Functional Group and Substrate Specificities

(2019) Xu Lu et al.   ACS Catalysis

Palladium/Norbornene Cooperative Catalysis

(2019) Jianchun Wang et al.   CHEMICAL REVIEWS

Rh(II)-Catalyzed Monocyclopropanation of Pyrroles and Its Application to the Synthesis Pharmaceutically Relevant Compounds

(2019) Jiantao Fu et al.   ORGANIC LETTERS

Metal-free directed C–H bond activation and borylation

(2019) Jiahang Lv et al.   NATURE

Remote C6-Enantioselective C–H Functionalization of 2,3-Disubstituted Indoles through the Dual H-Bonds and π–π Interaction Strategy Enabled by CPAs

(2019) Jia Zhou et al.   ORGANIC LETTERS

Regioselective direct arylation of indoles on the benzenoid moiety

(2018) Youqing Yang et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed Regioselective N 2 -Alkylation of Benzotriazoles with Diazo Compounds/Enynones via a Nonclassical Pathway

(2018) Kai Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

PIII -Chelation-Assisted Indole C7-Arylation, Olefination, Methylation, and Acylation with Carboxylic Acids/Anhydrides by Rhodium Catalysis

(2018) Xiaodong Qiu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Game of Directors: Accessing Remote Meta- and Para-C--H Bonds With Covalently Attached Directing Groups

(2018) Aniruddha Dey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Site-Selective Coupling of Indoles with Diazo Esters: C4-Alkylation versus C2-Annulation

(2017) Xiaohong Chen et al.   ORGANIC LETTERS

Iridium-Catalyzed Direct Regioselective C4-Amidation of Indoles under Mild Conditions

(2017) Shuyou Chen et al.   ORGANIC LETTERS

Remote C6-Selective Ruthenium-Catalyzed C–H Alkylation of Indole Derivatives via σ-Activation

(2017) Jamie A. Leitch et al.   ACS Catalysis

Beyond C2 and C3: Transition-Metal-Catalyzed C–H Functionalization of Indole

(2017) Jamie A. Leitch et al.   ACS Catalysis

Transition-Metal-Catalyzed C–H Bond Addition to Carbonyls, Imines, and Related Polarized π Bonds

(2016) Joshua R. Hummel et al.   CHEMICAL REVIEWS

Boron-Catalyzed Aromatic C–H Bond Silylation with Hydrosilanes

(2016) Yuanhong Ma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed C–H Arylation of Indoles at the C7 Position

(2016) Youqing Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu-Catalyzed Direct C6-Arylation of Indoles

(2016) Youqing Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Meta-Selective CAr–H Nitration of Arenes through a Ru3(CO)12-Catalyzed Ortho-Metalation Strategy

(2016) Zhoulong Fan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Direct Access to 7-Aminoindoles via Iridium-Catalyzed Mild C–H Amidation of N-Pivaloylindoles with Organic Azides

(2016) Youyoung Kim et al.   ORGANIC LETTERS

Electronic Nature of Ketone Directing Group as a Key To Control C-2 vs C-4 Alkenylation of Indoles

(2016) Veeranjaneyulu Lanke et al.   ORGANIC LETTERS

Integrated catalysis opens new arylation pathways via regiodivergent enzymatic C–H activation

(2016) Jonathan Latham et al.   Nature Communications

Direct and Practical Synthesis of Primary Anilines through Iron-Catalyzed C–H Bond Amination

(2016) Luca Legnani et al.   ACS Catalysis

Rh-Catalyzed Intermolecular Reactions of α-Alkyl-α-Diazo Carbonyl Compounds with Selectivity over β-Hydride Migration

(2015) Andrew DeAngelis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Transition Metal-Catalyzed CH Activation of Indoles

(2015) Alexander H. Sandtorv   ADVANCED SYNTHESIS & CATALYSIS

Rhodium-Catalyzed Regioselective C7-Functionalization of N -Pivaloylindoles

(2015) Lanting Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Palladium-Catalyzed CH Functionalization of Indoles Using an Axially Chiral 2,2′-Bipyridine Ligand

(2015) Xiang Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Catalyzedmeta-Selective CH Bromination

(2015) Christopher J. Teskey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of Verruculogen and Fumitremorgin A Enabled by Ligand-Controlled C–H Borylation

(2015) Yu Feng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A meta-selective C–H borylation directed by a secondary interaction between ligand and substrate

(2015) Yoichiro Kuninobu et al.   Nature Chemistry

Catalytic Methylation of CH Bonds Using CO2and H2

(2014) Yuehui Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Functionalization of Aromatic CH Bonds by Electrophilic Trapping of Metal-Carbene-Induced Zwitterionic Intermediates

(2014) Shikun Jia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed CH Cyanation of Arenes and Heteroarenes

(2014) Jie Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthetic Approaches to 3-(2-Nitroalkyl) Indoles and Their Use to Access Tryptamines and Related Bioactive Compounds

(2014) Stefano Lancianesi et al.   CHEMICAL REVIEWS

Reactions of metallocarbenes derived from N-sulfonyl-1,2,3-triazoles

(2014) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

Catalytic C6 Functionalization of 2,3-Disubstituted Indoles by Scandium Triflate

(2014) Hua Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd(II)-Catalyzed meta-C–H Olefination, Arylation, and Acetoxylation of Indolines Using a U-Shaped Template

(2014) Guoqiang Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)- and Ir(III)-Catalyzed C–H Alkynylation of Arenes under Chelation Assistance

(2014) Fang Xie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective Synthesis of 4-Substituted Indoles via C–H Activation: A Ruthenium Catalyzed Novel Directing Group Strategy

(2013) Veeranjaneyulu Lanke et al.   ORGANIC LETTERS

Direct Spectroscopic Characterization of a Transitory Dirhodium Donor-Acceptor Carbene Complex

(2013) K. P. Kornecki et al.   SCIENCE

Copper-Catalyzed CH Oxidation/Cross-Coupling of α-Amino Carbonyl Compounds

(2012) Ji-Cheng Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Mediated and Copper-Catalyzed Cross-Coupling of Indoles and 1,3-Azoles: Double CH Activation

(2012) Mayuko Nishino et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild and Efficient C2-Alkenylation of Indoles with Alkynes Catalyzed by a Cobalt Complex

(2012) Zhenhua Ding et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

(2012) Nadine Kuhl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

(2012) Percia Beatrice Arockiam et al.   CHEMICAL REVIEWS

From C(sp2)–H to C(sp3)–H: systematic studies on transition metal-catalyzed oxidative C–C formation

(2012) Bi-Jie Li et al.   CHEMICAL SOCIETY REVIEWS

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Rh-Catalyzed Intermolecular Reactions of Cyclic α-Diazocarbonyl Compounds with Selectivity over Tertiary C–H Bond Migration

(2012) Andrew DeAngelis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Adding Aliphatic C-H Bond Oxidations to Synthesis

(2012) M. C. White   SCIENCE

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

C–H functionalization logic in total synthesis

(2011) Will R. Gutekunst et al.   CHEMICAL SOCIETY REVIEWS

Recent developments in natural product synthesis using metal-catalysed C–H bond functionalisation

(2011) Lindsay McMurray et al.   CHEMICAL SOCIETY REVIEWS

Guiding principles for site selective and stereoselective intermolecular C–H functionalization by donor/acceptor rhodium carbenes

(2011) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

Rhodium(II)-Catalyzed Enantioselective C−H Functionalization of Indoles

(2011) Andrew DeAngelis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mild and Selective Ru-Catalyzed Formylation and Fe-Catalyzed Acylation of Free (N–H) Indoles Using Anilines as the Carbonyl Source

(2011) Wenliang Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Meta Sulfonation of 2-Phenylpyridines

(2011) Ourida Saidi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Iridium-Catalyzed, Silyl-Directed Borylation of Nitrogen-Containing Heterocycles

(2010) Daniel W. Robbins et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Palladium-Catalyzed Carboaminoxylations of Indoles with Arylboronic Acids and TEMPO

(2009) Sylvia Kirchberg et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed [3 + 2] Annulation of Indoles

(2009) Yajing Lian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Meta-Selective Copper-Catalyzed C-H Bond Arylation

(2009) R. J. Phipps et al.   SCIENCE

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

(2008) Huw M. L. Davies et al.   NATURE