Reactions of Stable Amidinate Chlorosilylene and [1+4]-Oxidative Addition of N-Heterocyclic Silylene with N-Benzylideneaniline

Synthetic Routes to N-Heterocyclic Carbene Precursors

(2011) Laure Benhamou et al.   CHEMICAL REVIEWS

Synthesis of Stable Silicon Heterocycles by Reaction of Organic Substrates with a Chlorosilylene [PhC(NtBu)2SiCl]

(2011) Shabana Khan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Syntheses of Group 7 Metal Carbonyl Complexes with a Stable N-Heterocyclic Chlorosilylene

(2011) Ramachandran Azhakar et al.   INORGANIC CHEMISTRY

Formation of Silicon Centered Spirocyclic Compounds: Reaction of N-Heterocyclic Stable Silylene with Benzoylpyridine, Diisopropyl Azodicarboxylate, and 1,2-Diphenylhydrazine

(2011) Ramachandran Azhakar et al.   INORGANIC CHEMISTRY

Gold(III) N-Heterocyclic Carbene Complexes Mediated Synthesis of β-Enaminones From 1,3-Dicarbonyl Compounds and Aliphatic Amines

(2011) Manoja K. Samantaray et al.   INORGANIC CHEMISTRY

Regiospecific C–H Bond Activation: Reactivity Study of N-Heterocyclic Silylene toward Ambidentate Phosphorus Ylide

(2011) Ramachandran Azhakar et al.   ORGANOMETALLICS

Reactions of StableN-Heterocyclic Silylenes with Ketones and 3,5-Di-tert-butyl-o-benzoquinone

(2011) Ramachandran Azhakar et al.   ORGANOMETALLICS

Synthesis of a Lewis Base Stabilized Dimer of N-Substituted Hydrosila Hydrazone and a Silaaziridine

(2011) Sankaranarayana Pillai Sarish et al.   ORGANOMETALLICS

Facile Synthesis of a Rare Chlorosilylene-BH3 Adduct

(2010) Ramachandran Azhakar et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Unsymmetric Ru(II) Complexes withN-Heterocyclic Carbene and/or Terpyridine Ligands: Synthesis, Characterization, Ground- and Excited-State Electronic Structures and Their Application for DSSC Sensitizers

(2010) Hee-Jun Park et al.   INORGANIC CHEMISTRY

Cationic, Neutral, and Anionic PNP PdIIand PtIIComplexes: Dearomatization by Deprotonation and Double-Deprotonation of Pincer Systems

(2010) Moran Feller et al.   INORGANIC CHEMISTRY

Use of Molecular Electrostatic Potential at the Carbene Carbon as a Simple and Efficient Electronic Parameter of N-heterocyclic Carbenes†

(2010) Jomon Mathew et al.   INORGANIC CHEMISTRY

Reactions of Aromatic Heterocycles with Uranium Alkyl Complexes

(2010) Selma Duhović et al.   INORGANIC CHEMISTRY

Group 6 Carbon Monoxide-Releasing Metal Complexes with Biologically-Compatible Leaving Groups

(2010) Wei-Qiang Zhang et al.   INORGANIC CHEMISTRY

Synthesis of a Zinc(II) Imidazolium Dicarboxylate Ligand Metal−Organic Framework (MOF): a Potential Precursor to MOF-Tethered N-Heterocyclic Carbene Compounds

(2010) Rachel S. Crees et al.   INORGANIC CHEMISTRY

Biscarbene Palladium(II) Complexes. Reactivity of Saturated Versus UnsaturatedN-Heterocyclic Carbenes

(2010) Ching-Feng Fu et al.   INORGANIC CHEMISTRY

First-Row Transition Metal Complexes of the Strongly Donating Pentadentate Ligand PY4Im

(2010) Jeremy M. Smith et al.   INORGANIC CHEMISTRY

Facile Syntheses of Silylene Nickel Carbonyl Complexes from Lewis Base Stabilized Chlorosilylenes†

(2010) Gašper Tavčar et al.   INORGANIC CHEMISTRY

The Use of Imidazolium-2-dithiocarboxylates in the Formation of Gold(I) Complexes and Gold Nanoparticles†† Dedicated to Prof. Dr. Hubert Schmidbaur on the occasion of his 75th birthday.

(2010) Saira Naeem et al.   INORGANIC CHEMISTRY

Highly Convenient Regioselective Intermolecular Hydroamination of Alkynes Yielding Ketimines Catalyzed by Gold(I) Complexes of 1,2,4-triazole Based N-heterocyclic Carbenes

(2010) Chandrakanta Dash et al.   INORGANIC CHEMISTRY

Iridium Metal Complexes Containing N-Heterocyclic Carbene Ligands for Blue-Light-Emitting Electrochemical Cells

(2010) Cheng-Han Yang et al.   INORGANIC CHEMISTRY

Neutral Pentacoordinate Silicon Fluorides Derived from Amidinate, Guanidinate, and Triazapentadienate Ligands and Base-Induced Disproportionation of Si2Cl6to Stable Silylenes

(2010) Rajendra S. Ghadwal et al.   INORGANIC CHEMISTRY

Regioselective C−H Activation and Sequential C−C and C−O Bond Formation Reactions of Aryl Ketones Promoted by an Yttrium Carbene

(2010) David P. Mills et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Steering S−H and N−H Bond Activation by a Stable N-Heterocyclic Silylene: Different Addition of H2S, NH3, and Organoamines on a Silicon(II) Ligand versus Its Si(II)→Ni(CO)3Complex

(2010) Antje Meltzer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Insertion of Carboryne into Aromatic Rings: Formation of Cyclooctatetraenocarboranes

(2010) Sunewang R. Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High Yield Access to Silylene RSiCl (R = PhC(NtBu)2) and Its Reactivity toward Alkyne: Synthesis of Stable Disilacyclobutene

(2010) Sakya S. Sen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbene-Catalyzed Conjugate Additions of Alcohols

(2010) Eric M. Phillips et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Catalytic Role of N-Heterocyclic Carbene in a Metal-Free Conversion of Carbon Dioxide into Methanol: A Computational Mechanism Study

(2010) Fang Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Viable Anionic N-Heterocyclic Dicarbene

(2010) Yuzhong Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Aromatic C−F and C−H Bond Activation with Silylenes of Different Coordinate Silicon

(2010) Anukul Jana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A {Fe(NO)3}10Trinitrosyliron Complex Stabilized by an N-Heterocyclic Carbene and the Cationic and Neutral {Fe(NO)2}9/10Products of Its NO Release

(2010) Chung-Hung Hsieh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactions of an Isolable Dialkylsilylene with Ketones†

(2010) Shintaro Ishida et al.   ORGANOMETALLICS

Unusual [3+1] Cycloaddition of a Stable Silylene with a 2,3-Diazabuta-1,3-diene versus [4+1] Cycloaddition toward a Buta-1,3-diene

(2010) Yun Xiong et al.   ORGANOMETALLICS

Synthesis of a Stable Four-Membered Si2O2Ring and a Dimer with Two Four-Membered Si2O2Rings Bridged by Two Oxygen Atoms, with Five-Coordinate Silicon Atoms in Both Ring Systems

(2010) Sakya S. Sen et al.   ORGANOMETALLICS

Unique homonuclear multiple bonding in main group compounds

(2009) Yuzhong Wang et al.   CHEMICAL COMMUNICATIONS

Versatile Reactivity of a Zwitterionic Isolable Silylene toward Ketones: Silicon-Mediated, Regio- and Stereoselective CH Activation

(2009) Yun Xiong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ambiphilicity of Dichlorosilylene in a Single Molecule

(2009) Rajendra S. Ghadwal et al.   CHEMISTRY-A EUROPEAN JOURNAL

N-Aryl substituted heterocyclic silylenes

(2009) Lingbing Kong et al.   DALTON TRANSACTIONS

Multifaceted Coordination of Naphthyridine−Functionalized N-Heterocyclic Carbene: A Novel “IrIII(C∧N)(C∧C)” Compound and Its Evaluation as Transfer Hydrogenation Catalyst

(2009) Arup Sinha et al.   INORGANIC CHEMISTRY

H2Activation by a (PNP)Ir(C6H5) Complex via the Dearomatization/Aromatization Process of the PNP Ligand: A Computational Study

(2009) Guixiang Zeng et al.   INORGANIC CHEMISTRY

Luminescent Copper(I) Halide Butterfly Dimers Coordinated to [Au(CH3imCH2py)2]BF4and [Au(CH3imCH2quin)2]BF4

(2009) Vincent J. Catalano et al.   INORGANIC CHEMISTRY

Catalytic Dehydrogenation of Ammonia Borane at Ni Monocarbene and Dicarbene Catalysts

(2009) Paul M. Zimmerman et al.   INORGANIC CHEMISTRY

Bimetallic N-Heterocyclic Carbene−Iridium Complexes: Investigating Metal−Metal and Metal−Ligand Communication via Electrochemistry and Phosphorescence Spectroscopy

(2009) Andrew G. Tennyson et al.   INORGANIC CHEMISTRY

Side-on Coordination of a P−P Bond in Heterobinuclear Tetraphosphorus Complexes with a [Si(μ,η2:2-P4)Ni] Core and Nickel(I) Centers

(2009) Yun Xiong et al.   INORGANIC CHEMISTRY

A Series of Mononuclear Quasi-Two-Coordinate Copper(I) Complexes Employing a Sterically Demanding Thiolate Ligand

(2009) Stanislav Groysman et al.   INORGANIC CHEMISTRY

Concomitant Formation of N-Heterocyclic Carbene−Copper Complexes within a Supramolecular Network in the Self-Assembly of Imidazolium Dicarboxylate with Metal Ions

(2009) Jiseul Chun et al.   INORGANIC CHEMISTRY

A Base-Stabilized Silylene with a Tricoordinate Silicon Atom as a Ligand for a Metal Complex

(2009) Wei Yang et al.   INORGANIC CHEMISTRY

Lewis-Base-Stabilized Dichlorosilylene: A Two-Electron σ-Donor Ligand

(2009) Jianfeng Li et al.   INORGANIC CHEMISTRY

Group-Transfer Reactions of Nickel−Carbene and −Nitrene Complexes with Organoazides and Nitrous Oxide that Form New C═N, C═O, and N═N Bonds

(2009) Nicole D. Harrold et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation of Free Phenylide-like Carbanions with N-Heterocyclic Carbene Frameworks

(2009) Kelly E. Krahulic et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diketiminate Silicon(II) and Related NHSi Ligands Generated in the Coordination Sphere of Nickel(0)

(2009) Antje Meltzer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative Addition of Ammonia at a Silicon(II) Center and an Unprecedented Hydrogenation Reaction of Compounds with Low-Valent Group 14 Elements Using Ammonia Borane

(2009) Anukul Jana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Complexation of Nitrous Oxide by Frustrated Lewis Pairs

(2009) Edwin Otten et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Neutral Ga6Octahedron: Synthesis, Structure, and Aromaticity

(2009) Brandon Quillian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reduction of Nitrous Oxide to Dinitrogen by a Mixed Valent Tricopper-Disulfido Cluster

(2009) Itsik Bar-Nahum et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereogenic-at-Metal Zn- and Al-Based N-Heterocyclic Carbene (NHC) Complexes as Bifunctional Catalysts in Cu-Free Enantioselective Allylic Alkylations

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Asymmetric Dearomatization of Naphthalene Derivatives

(2009) Jorge García-Fortanet et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Isolable NHC-Supported Silanone

(2009) Yun Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

α′-Hydroxyenones as Mechanistic Probes and Scope-Expanding Surrogates for α,β-Unsaturated Aldehydes in N-Heterocyclic Carbene-Catalyzed Reactions

(2009) Pei-Chen Chiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dearomatization Reactions of N-Heterocycles Mediated by Group 3 Complexes

(2009) Kevin L. Miller et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Double [3 + 2] Photocycloaddition Reaction

(2009) Clive S. Penkett et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactivity of a Zwitterionic Stable Silylene toward Halosilanes and Haloalkanes

(2009) Yun Xiong et al.   ORGANOMETALLICS

Insertion Reaction of a Silylene into a N−H Bond of Hydrazine and a [1+4] Cycloaddition with Diphenyl Hydrazone§

(2009) Anukul Jana et al.   ORGANOMETALLICS

C4-bound imidazolylidenes: from curiosities to high-impact carbene ligands

(2008) Martin Albrecht   CHEMICAL COMMUNICATIONS

Synthesis, structure, magnetism and nuclease activity of tetranuclear copper(ii) phosphonates containing ancillary 2,2′-bipyridine or 1,10-phenanthroline ligands

(2008) Vadapalli Chandrasekhar et al.   DALTON TRANSACTIONS

The Chemistry of Aluminum(I), Silicon(II), and Germanium(II)

(2008) Selvarajan Nagendran et al.   ORGANOMETALLICS

A Stable Silicon(0) Compound with a Si=Si Double Bond

(2008) Y. Wang et al.   SCIENCE