Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 84, Pages 12619-12622Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc05181e
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Funding
- Alexander von Humboldt foundation (Sofja Kovalevskaja Program)
- New Szechenyi Plan [TAMOP-4.2.2/B-10/1-2010-0009]
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Taking advantage of two N-heterocyclic carbenes (NHCs), novel silyliumylidene ions 1a and 1b are prepared by a facile one-pot reaction of the corresponding dichlorosilanes with three equivalents of NHCs. For the first time, a C-H insertion reaction of phenylacetylene by a novel silyliumylidene ion is reported. The treatment of m-terphenyl substituted silyliumylidene ion 1a with three equivalents of phenylacetylene results in the formation of m-terphenyl substituted 1-alkenyl-1,1-dialkynylsilane 2.
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