A New Ligand Design Based on London Dispersion Empowers Chiral Bismuth–Rhodium Paddlewheel Catalysts
Published 2021 View Full Article
- Home
- Publications
- Publication Search
- Publication Details
Title
A New Ligand Design Based on London Dispersion Empowers Chiral Bismuth–Rhodium Paddlewheel Catalysts
Authors
Keywords
-
Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 143, Issue 15, Pages 5666-5673
Publisher
American Chemical Society (ACS)
Online
2021-04-15
DOI
10.1021/jacs.1c01972
References
Ask authors/readers for more resources
Related references
Note: Only part of the references are listed.- Catalytic Asymmetric Fluorination of Copper Carbene Complexes: Preparative Advances and a Mechanistic Rationale
- (2020) Michael Buchsteiner et al. CHEMISTRY-A EUROPEAN JOURNAL
- Unveiling the Delicate Balance of Steric and Dispersion Interactions in Organocatalysis Using High-Level Computational Methods
- (2020) Diana Yepes et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Nickel-catalysed anti-Markovnikov hydroarylation of unactivated alkenes with unactivated arenes facilitated by non-covalent interactions
- (2020) Noam I. Saper et al. Nature Chemistry
- A Heteroleptic Dirhodium Catalyst for Asymmetric Cyclopropanation with α‐Stannyl α‐Diazoacetate.Stereoretentive Stille Coupling with Formation of Chiral Quarternary Carbon Centers
- (2020) Alois Fürstner et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Transition Metal Catalyzed Insertion Reactions with Donor/Donor Carbenes
- (2020) Jared Thomas Shaw et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Recent Perspectives on Rearrangement Reactions of Ylides via Carbene Transfer Reactions
- (2020) Sripati Jana et al. CHEMISTRY-A EUROPEAN JOURNAL
- Application of Trimethylgermanyl-Substituted Bisphosphine Ligands with Enhanced Dispersion Interactions to Copper-Catalyzed Hydroboration of Disubstituted Alkenes
- (2020) Yumeng Xi et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Chiral paddle-wheel diruthenium complexes for asymmetric catalysis
- (2020) Taku Miyazawa et al. Nature Catalysis
- London Dispersion Rather than Steric Hindrance Determines the Enantioselectivity of the Corey‐Bakshi‐Shibata Reduction
- (2020) Christian Eschmann et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Intramolecular London Dispersion Interactions Do Not Cancel in Solution
- (2020) Jan M. Schümann et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Chiral Heterobimetallic Bismuth-Rhodium Paddlewheel Catalysts: A Conceptually New Approach to Asymmetric Cyclopropanation
- (2019) Lee R. Collins et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Finding chemical concepts in the Hilbert space: Coupled cluster analyses of noncovalent interactions
- (2019) Giovanni Bistoni Wiley Interdisciplinary Reviews-Computational Molecular Science
- In Situ Kinetic Studies of Rh(II)-Catalyzed Asymmetric Cyclopropanation with Low Catalyst Loadings
- (2019) Bo Wei et al. ACS Catalysis
- Structure and Reactivity of Half-Sandwich Rh(+3) and Ir(+3) Carbene Complexes. Catalytic Metathesis of Azobenzene Derivatives
- (2018) Daniel J. Tindall et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Chiral proton-transfer shuttle catalysts for carbene insertion reactions
- (2018) Yuan-Yuan Ren et al. ORGANIC & BIOMOLECULAR CHEMISTRY
- Enhanced Electrophilicity of Heterobimetallic Bi-Rh Paddlewheel Carbene Complexes: A Combined Experimental, Spectroscopic and Computational Study
- (2018) Lee R. Collins et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Mechanistically Guided Design of Ligands that Significantly Improve the Efficiency of CuH-Catalyzed Hydroamination Reactions
- (2018) Andy A Thomas et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Comparison of Reactivity and Enantioselectivity between Chiral Bimetallic Catalysts: Bismuth-Rhodium and Dirhodium Catalyzed Carbene Chemistry
- (2018) Zhi Ren et al. ACS Catalysis
- Metal–Metal Bonds: From Fundamentals to Applications
- (2017) John F. Berry et al. INORGANIC CHEMISTRY
- Ligand–Substrate Dispersion Facilitates the Copper-Catalyzed Hydroamination of Unactivated Olefins
- (2017) Gang Lu et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Software update: the ORCA program system, version 4.0
- (2017) Frank Neese Wiley Interdisciplinary Reviews-Computational Molecular Science
- On the Structure of Chiral Dirhodium(II) Carboxylate Catalysts: Stereoselectivity Relevance and Insights
- (2017) Frady Adly Catalysts
- London dispersion forces in sterically crowded inorganic and organometallic molecules
- (2017) David J. Liptrot et al. Nature Reviews Chemistry
- Stabilization of a Chiral Dirhodium Carbene by Encapsulation and a Discussion of the Stereochemical Implications
- (2016) Christophe Werlé et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Dispersion-Corrected Mean-Field Electronic Structure Methods
- (2016) Stefan Grimme et al. CHEMICAL REVIEWS
- Metal-Metal Single Bonds with the Magnetic Anisotropy of Quadruple Bonds: A Systematic Series of Heterobimetallic Bismuth(II)-Rhodium(II) Formamidinate Complexes
- (2016) Travis L. Sunderland et al. CHEMISTRY-A EUROPEAN JOURNAL
- Design and Synthesis of Novel Chiral Dirhodium(II) Carboxylate Complexes for Asymmetric Cyclopropanation Reactions
- (2016) Frady G. Adly et al. CHEMISTRY-A EUROPEAN JOURNAL
- Expanding the family of heterobimetallic Bi–Rh paddlewheel carboxylate complexes via equatorial carboxylate exchange
- (2016) Travis L. Sunderland et al. DALTON TRANSACTIONS
- Decomposition of Intermolecular Interaction Energies within the Local Pair Natural Orbital Coupled Cluster Framework
- (2016) Wolfgang B. Schneider et al. Journal of Chemical Theory and Computation
- The first bismuth(II)–rhodium(II) oxypyridinate paddlewheel complexes: synthesis and structural characterization
- (2016) Travis L. Sunderland et al. JOURNAL OF COORDINATION CHEMISTRY
- Structures of Reactive Donor/Acceptor and Donor/Donor Rhodium Carbenes in the Solid State and Their Implications for Catalysis
- (2016) Christophe Werlé et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Rhodium(I)-Catalyzed Highly Enantioselective Insertion of Carbenoid into Si–H: Efficient Access to Functional Chiral Silanes
- (2016) Diao Chen et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Site-selective and stereoselective functionalization of unactivated C–H bonds
- (2016) Kuangbiao Liao et al. NATURE
- Metal–Metal Bonds in Catalysis
- (2016) Ian G. Powers et al. ACS Catalysis
- Rh-Catalyzed Intermolecular Reactions of α-Alkyl-α-Diazo Carbonyl Compounds with Selectivity over β-Hydride Migration
- (2015) Andrew DeAngelis et al. ACCOUNTS OF CHEMICAL RESEARCH
- The First Crystal Structure of a Reactive Dirhodium Carbene Complex and a Versatile Method for the Preparation of Gold Carbenes by Rhodium-to-Gold Transmetalation
- (2015) Christophe Werlé et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- London Dispersion in Molecular Chemistry-Reconsidering Steric Effects
- (2015) J. Philipp Wagner et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Modern Organic Synthesis with α-Diazocarbonyl Compounds
- (2015) Alan Ford et al. CHEMICAL REVIEWS
- Catalytic functionalization of low reactive C(sp3)–H and C(sp2)–H bonds of alkanes and arenes by carbene transfer from diazo compounds
- (2015) Ana Caballero et al. DALTON TRANSACTIONS
- Mechanism and stereoselectivity of the Rh(ii)-catalyzed cyclopropanation of diazooxindole: a density functional theory study
- (2015) Yun-Sheng Xue et al. RSC Advances
- 2,2,2-Trichloroethyl Aryldiazoacetates as Robust Reagents for the Enantioselective C–H Functionalization of Methyl Ethers
- (2014) David M. Guptill et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Dispersion Makes the Difference: Bisligated Transition States Found for the Oxidative Addition of Pd(PtBu3)2 to Ar-OSO2R and Dispersion-Controlled Chemoselectivity in Reactions with Pd[P(iPr)(tBu2)]2
- (2014) Eirik Lyngvi et al. ORGANOMETALLICS
- Catalytic X–H insertion reactions based on carbenoids
- (2013) Dennis Gillingham et al. CHEMICAL SOCIETY REVIEWS
- Guide to enantioselective dirhodium(II)-catalyzed cyclopropanation with aryldiazoacetates
- (2013) Kathryn M. Chepiga et al. TETRAHEDRON
- The Combined C–H Functionalization/Cope Rearrangement: Discovery and Applications in Organic Synthesis
- (2012) Huw M. L. Davies et al. ACCOUNTS OF CHEMICAL RESEARCH
- Transition-Metal-Catalyzed Enantioselective Heteroatom–Hydrogen Bond Insertion Reactions
- (2012) Shou-Fei Zhu et al. ACCOUNTS OF CHEMICAL RESEARCH
- Highly enantioselective intermolecular carbene insertion to C–H and Si–H bonds catalyzed by a chiral iridium(iii) complex of a D4-symmetric Halterman porphyrin ligand
- (2012) Jing-Cui Wang et al. CHEMICAL COMMUNICATIONS
- Highly Enantioselective Cyclopropenation Reaction of 1-Alkynes with α-Alkyl-α-Diazoesters Catalyzed by Dirhodium(II) Carboxylates
- (2011) Takayuki Goto et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- From Solid State to Solution: Advancing Chemistry of Bi–Bi and Bi–Rh Paddlewheel Carboxylates
- (2011) Alexander S. Filatov et al. INORGANIC CHEMISTRY
- Optimizing dirhodium(ii) tetrakiscarboxylates as chiral NMR auxiliaries
- (2011) Jens T. Mattiza et al. ORGANIC & BIOMOLECULAR CHEMISTRY
- Enantio- and diastereoselective cyclopropanation with tert-butyl α-diazopropionate catalyzed by dirhodium(II) tetrakis[N-tetrabromophthaloyl-(S)-tert-leucinate]
- (2011) Takayuki Goto et al. TETRAHEDRON LETTERS
- The chiral crown conformation in paddlewheel complexes
- (2010) Andrew DeAngelis et al. CHEMICAL COMMUNICATIONS
- Synthesis and Applications oftert-Butanesulfinamide
- (2010) MaryAnn T. Robak et al. CHEMICAL REVIEWS
- First X-ray Structure of aN-Naphthaloyl-Tethered Chiral Dirhodium(II) Complex: Structural Basis for Tether Substitution Improving Asymmetric Control in Olefin Cyclopropanation
- (2010) Ashraf Ghanem et al. CHEMISTRY-A EUROPEAN JOURNAL
- Metallopeptides for Asymmetric Dirhodium Catalysis
- (2010) Ramya Sambasivan et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Iridium(III)-Catalyzed Enantioselective Si−H Bond Insertion and Formation of an Enantioenriched Silicon Center
- (2010) Yoichi Yasutomi et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Catalytic Carbene Insertion into C−H Bonds
- (2009) Michael P. Doyle et al. CHEMICAL REVIEWS
- Catalytic [2,3]-sigmatropic rearrangement of sulfur ylide derived from metal carbene
- (2009) Yan Zhang et al. COORDINATION CHEMISTRY REVIEWS
- Combined Experimental and Computational Studies of Heterobimetallic Bi−Rh Paddlewheel Carboxylates as Catalysts for Metal Carbenoid Transformations
- (2009) Jo̷rn Hansen et al. JOURNAL OF ORGANIC CHEMISTRY
- Chiral Crown Conformation of Rh2(S-PTTL)4: Enantioselective Cyclopropanation with α-Alkyl-α-diazoesters
- (2009) Andrew DeAngelis et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Experimental Evidence for the All-Up Reactive Conformation of Chiral Rhodium(II) Carboxylate Catalysts: Enantioselective Synthesis ofcis-Cyclopropane α-Amino Acids
- (2009) Vincent N. G. Lindsay et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Why Is Copper(I) Complex More Competent Than Dirhodium(II) Complex in Catalytic Asymmetric O−H Insertion Reactions? A Computational Study of the Metal Carbenoid O−H Insertion into Water
- (2009) Yong Liang et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Enantioselective Reactions of Donor/Acceptor Carbenoids Derived from α-Aryl-α-Diazoketones
- (2009) Justin R. Denton et al. ORGANIC LETTERS
- Copper-Catalyzed Highly Enantioselective Carbenoid Insertion into SiH Bonds
- (2008) Yong-Zhen Zhang et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion
- (2008) Huw M. L. Davies et al. NATURE
- Recent studies on the reactions of α-diazocarbonyl compounds
- (2008) Zhenhua Zhang et al. TETRAHEDRON
Find Funding. Review Successful Grants.
Explore over 25,000 new funding opportunities and over 6,000,000 successful grants.
ExploreDiscover Peeref hubs
Discuss science. Find collaborators. Network.
Join a conversation