Chiral Heterobimetallic Bismuth-Rhodium Paddlewheel Catalysts: A Conceptually New Approach to Asymmetric Cyclopropanation

Two Amphoteric Silver Carbene Clusters

(2018) Alexander G. Tskhovrebov et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structure and Reactivity of Half-Sandwich Rh(+3) and Ir(+3) Carbene Complexes. Catalytic Metathesis of Azobenzene Derivatives

(2018) Daniel J. Tindall et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Half-Sandwich Ruthenium Carbene Complexes Link trans-Hydrogenation and gem-Hydrogenation of Internal Alkynes

(2018) Alexandre Guthertz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enhanced Electrophilicity of Heterobimetallic Bi-Rh Paddlewheel Carbene Complexes: A Combined Experimental, Spectroscopic and Computational Study

(2018) Lee R. Collins et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Comparison of Reactivity and Enantioselectivity between Chiral Bimetallic Catalysts: Bismuth-Rhodium and Dirhodium Catalyzed Carbene Chemistry

(2018) Zhi Ren et al.   ACS Catalysis

trans-Hydrogenation, gem-Hydrogenation, and trans-Hydrometalation of Alkynes: An Interim Report on an Unorthodox Reactivity Paradigm

(2018) Alois Fürstner   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the Structure of Chiral Dirhodium(II) Carboxylate Catalysts: Stereoselectivity Relevance and Insights

(2017) Frady Adly   Catalysts

Stabilization of a Chiral Dirhodium Carbene by Encapsulation and a Discussion of the Stereochemical Implications

(2016) Christophe Werlé et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Halogen Bond

(2016) Gabriella Cavallo et al.   CHEMICAL REVIEWS

Design and Synthesis of Novel Chiral Dirhodium(II) Carboxylate Complexes for Asymmetric Cyclopropanation Reactions

(2016) Frady G. Adly et al.   CHEMISTRY-A EUROPEAN JOURNAL

Expanding the family of heterobimetallic Bi–Rh paddlewheel carboxylate complexes via equatorial carboxylate exchange

(2016) Travis L. Sunderland et al.   DALTON TRANSACTIONS

The first bismuth(II)–rhodium(II) oxypyridinate paddlewheel complexes: synthesis and structural characterization

(2016) Travis L. Sunderland et al.   JOURNAL OF COORDINATION CHEMISTRY

Structures of Reactive Donor/Acceptor and Donor/Donor Rhodium Carbenes in the Solid State and Their Implications for Catalysis

(2016) Christophe Werlé et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-Catalyzed Intermolecular Reactions of α-Alkyl-α-Diazo Carbonyl Compounds with Selectivity over β-Hydride Migration

(2015) Andrew DeAngelis et al.   ACCOUNTS OF CHEMICAL RESEARCH

The First Crystal Structure of a Reactive Dirhodium Carbene Complex and a Versatile Method for the Preparation of Gold Carbenes by Rhodium-to-Gold Transmetalation

(2015) Christophe Werlé et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Modern Organic Synthesis with α-Diazocarbonyl Compounds

(2015) Alan Ford et al.   CHEMICAL REVIEWS

Mechanism and stereoselectivity of the Rh(ii)-catalyzed cyclopropanation of diazooxindole: a density functional theory study

(2015) Yun-Sheng Xue et al.   RSC Advances

Structure of a Reactive Gold Carbenoid

(2014) Günter Seidel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Guide to enantioselective dirhodium(II)-catalyzed cyclopropanation with aryldiazoacetates

(2013) Kathryn M. Chepiga et al.   TETRAHEDRON

Transition-Metal-Catalyzed Enantioselective Heteroatom–Hydrogen Bond Insertion Reactions

(2012) Shou-Fei Zhu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Design and Synthesis of Chiral Heteroleptic Rhodium(II) Carboxylate Catalysts: Experimental Investigation of Halogen Bond Rigidification Effects in Asymmetric Cyclopropanation

(2012) Vincent N. G. Lindsay et al.   ACS Catalysis

Highly Enantioselective Cyclopropenation Reaction of 1-Alkynes with α-Alkyl-α-Diazoesters Catalyzed by Dirhodium(II) Carboxylates

(2011) Takayuki Goto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From Solid State to Solution: Advancing Chemistry of Bi–Bi and Bi–Rh Paddlewheel Carboxylates

(2011) Alexander S. Filatov et al.   INORGANIC CHEMISTRY

Optimizing dirhodium(ii) tetrakiscarboxylates as chiral NMR auxiliaries

(2011) Jens T. Mattiza et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantio- and diastereoselective cyclopropanation with tert-butyl α-diazopropionate catalyzed by dirhodium(II) tetrakis[N-tetrabromophthaloyl-(S)-tert-leucinate]

(2011) Takayuki Goto et al.   TETRAHEDRON LETTERS

The chiral crown conformation in paddlewheel complexes

(2010) Andrew DeAngelis et al.   CHEMICAL COMMUNICATIONS

First X-ray Structure of aN-Naphthaloyl-Tethered Chiral Dirhodium(II) Complex: Structural Basis for Tether Substitution Improving Asymmetric Control in Olefin Cyclopropanation

(2010) Ashraf Ghanem et al.   CHEMISTRY-A EUROPEAN JOURNAL

Combined Experimental and Computational Studies of Heterobimetallic Bi−Rh Paddlewheel Carboxylates as Catalysts for Metal Carbenoid Transformations

(2009) Jo̷rn Hansen et al.   JOURNAL OF ORGANIC CHEMISTRY

Chiral Crown Conformation of Rh2(S-PTTL)4: Enantioselective Cyclopropanation with α-Alkyl-α-diazoesters

(2009) Andrew DeAngelis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental Evidence for the All-Up Reactive Conformation of Chiral Rhodium(II) Carboxylate Catalysts: Enantioselective Synthesis ofcis-Cyclopropane α-Amino Acids

(2009) Vincent N. G. Lindsay et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

(2008) Huw M. L. Davies et al.   NATURE

Metal-Site-Controlled Arene Coordination in a Heterobimetallic Bi−Rh Complex with Pyrene

(2008) Evgeny V. Dikarev et al.   ORGANOMETALLICS

Recent studies on the reactions of α-diazocarbonyl compounds

(2008) Zhenhua Zhang et al.   TETRAHEDRON