Catalytic functionalization of low reactive C(sp3)–H and C(sp2)–H bonds of alkanes and arenes by carbene transfer from diazo compounds

Copper and Silver Carbene Complexes without Heteroatom-Stabilization: Structure, Spectroscopy, and Relativistic Effects

(2015) Matthias W. Hussong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Expanding the Carbene CH Insertion Toolbox

(2015) Daniel Morton et al.   ChemCatChem

Functionalization of CnH2n+2Alkanes: Supercritical Carbon Dioxide Enhances the Reactivity towards Primary Carbon-Hydrogen Bonds

(2015) Riccardo Gava et al.   ChemCatChem

Copper-Carbene Intermediates in the Copper-Catalyzed Functionalization of OH Bonds

(2015) Ana Pereira et al.   CHEMISTRY-A EUROPEAN JOURNAL

CF3-Carbenoid C-H Functionalization of (Hetero)arenes under Chelation-Controlled RhIIICatalysis

(2015) Irina E. Iagafarova et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Catalyst design in the alkane C–H bond functionalization of alkanes by carbene insertion with TpxM complexes (Tpx = hydrotrispyrazolylborate ligand; M = Cu, Ag)

(2015) Ana Caballero et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

A computational view on the reactions of hydrocarbons with coinage metal complexes

(2015) Maria Besora et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Catalytic Asymmetric Arylation of α-Aryl-α-diazoacetates with Aniline Derivatives

(2015) Bin Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Discovering Copper for Methane C–H Bond Functionalization

(2015) Riccardo Gava et al.   ACS Catalysis

Ruthenium-Porphyrin-Catalyzed Diastereoselective Intramolecular Alkyl Carbene Insertion into CH Bonds of Alkyl Diazomethanes Generated In Situ fromN-Tosylhydrazones

(2014) Annapureddy Rajasekar Reddy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Functionalization of Aromatic CH Bonds by Electrophilic Trapping of Metal-Carbene-Induced Zwitterionic Intermediates

(2014) Shikun Jia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structure of a Reactive Gold Carbenoid

(2014) Günter Seidel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isolation of a Non-Heteroatom-Stabilized Gold-Carbene Complex

(2014) Matthias W. Hussong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemoselective Carbophilic Addition of α-Diazoesters through Ligand-Controlled Gold Catalysis

(2014) Yumeng Xi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Functionalization of Methane and Light Alkanes in Supercritical Carbon Dioxide

(2014) M. Ángeles Fuentes et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Intramolecular C–H Insertion Reactions of Donor–Donor Metal Carbenoids

(2014) Cristian Soldi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Site-Selective Direct C–H Bond Functionalization of Phenols with α-Aryl-α-diazoacetates and Diazooxindoles via Gold Catalysis

(2014) Zhunzhun Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-CatalyzedorthoAlkenylation ofN-Phenoxyacetamides withN-Tosylhydrazones or Diazoesters through CH Activation

(2013) Fangdong Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Methane as raw material in synthetic chemistry: the final frontier

(2013) Ana Caballero et al.   CHEMICAL SOCIETY REVIEWS

Catalytic cross-coupling of diazo compounds with coinage metal-based catalysts: an experimental and theoretical study

(2013) Ivan Rivilla et al.   DALTON TRANSACTIONS

Rh(III)-Catalyzed Synthesis of Multisubstituted Isoquinoline and Pyridine N-Oxides from Oximes and Diazo Compounds

(2013) Zhuangzhi Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Coupling of Benzamides and Donor/Acceptor Diazo Compounds To Form γ-Lactams via Rh(III)-Catalyzed C–H Activation

(2013) Todd K. Hyster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Spectroscopic Characterization of a Transitory Dirhodium Donor-Acceptor Carbene Complex

(2013) K. P. Kornecki et al.   SCIENCE

The Rh2(OAc)4-catalyzed reactions of 3-trifluoromethyl-4-diazopyrazolinones with aromatic compounds

(2013) Huafang Fan et al.   TETRAHEDRON

Functionalization of Non-activated CH Bonds of Alkanes: An Effective and Recyclable Catalytic System Based on Fluorinated Silver Catalysts and Solvents

(2012) M. Ángeles Fuentes et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reactivity of Stabilized Vinyl Diazo Derivatives toward Unsaturated Hydrocarbons: Regioselective Gold-Catalyzed Carbon-Carbon Bond Formation

(2012) José Barluenga et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Hydrocarbon Functionalization with Gold Complexes Containing N-Heterocyclic Carbene Ligands with Pendant Donor Groups

(2012) Manuela Delgado-Rebollo et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Rh-Catalyzed Intermolecular Carbenoid Functionalization of Aromatic C–H Bonds by α-Diazomalonates

(2012) Wai-Wing Chan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver(I)-Catalyzed Insertion of Carbene into Alkane C–H Bonds and the Origin of the Special Challenge of Methane Activation Using DFT as a Mechanistic Probe

(2012) Jaime A. Flores et al.   ACS Catalysis

Gold-catalyzed naphthalene functionalization

(2011) Pedro J Pérez et al.   Beilstein Journal of Organic Chemistry

Mechanism of Side Reactions in Alkane CH Bond Functionalization by Diazo Compounds Catalyzed by Ag and Cu Homoscorpionate Complexes-A DFT Study

(2011) Ataualpa A. C. Braga et al.   ChemCatChem

Resolving Heterogeneity Problems and Impurity Artifacts in Operationally Homogeneous Transition Metal Catalysts

(2011) Robert H. Crabtree   CHEMICAL REVIEWS

Dehydrogenation and Related Reactions Catalyzed by Iridium Pincer Complexes

(2011) Jongwook Choi et al.   CHEMICAL REVIEWS

Guiding principles for site selective and stereoselective intermolecular C–H functionalization by donor/acceptor rhodium carbenes

(2011) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

Intermetallic coinage metal-catalyzed functionalization of alkanes with ethyl diazoacetate: Gold as a ligand

(2011) M. Ángeles Fuentes et al.   INORGANICA CHIMICA ACTA

Experimental Evidence for Cobalt(III)-Carbene Radicals: Key Intermediates in Cobalt(II)-Based Metalloradical Cyclopropanation

(2011) Hongjian Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Exclusive Aromatic vs Aliphatic C–H Bond Functionalization by Carbene Insertion with Gold-Based Catalysts

(2011) Ivan Rivilla et al.   ORGANOMETALLICS

Silver-Catalyzed C-C Bond Formation Between Methane and Ethyl Diazoacetate in Supercritical CO2

(2011) A. Caballero et al.   SCIENCE

Copper(II) Triflate Catalyzed Intermolecular Aromatic Substitution of N,N-Disubstituted Anilines with Diazo Esters

(2010) Eiji Tayama et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

The norcaradiene–cycloheptatriene equilibrium

(2010) Orla A. McNamara et al.   TETRAHEDRON

Catalytic Carbene Insertion into C−H Bonds

(2009) Michael P. Doyle et al.   CHEMICAL REVIEWS

Trapping Reactive Metal-Carbene Complexes by a Bis-Pocket Porphyrin: X-ray Crystal Structures of RuCHCO2Et andtrans-[Ru(CHR)(CO)] Species and Highly Selective Carbenoid Transfer Reactions

(2009) Qing-Hai Deng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Remarkably Stable Copper(I) α-Carbonyl Carbenes: Synthesis, Structure, and Mechanistic Studies of Alkene Cyclopropanation Reactions†

(2009) Igor V. Shishkov et al.   ORGANOMETALLICS

Ru/PNNP-Catalyzed Asymmetric Imine Aziridination by Diazo Ester Activation

(2009) Marco Ranocchiari et al.   ORGANOMETALLICS

Highly Selective Metal Catalysts for Intermolecular Carbenoid Insertion into Primary CH Bonds and Enantioselective CC Bond Formation

(2008) Hung-Yat Thu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diazoalkanes react with a bis(phosphino)borate copper(i) source to generate [Ph2BPtBu2]Cu(η1-N2CR2), [Ph2BPtBu2]Cu(CPh2), and [Ph2BPtBu2]Cu–N(CPh2)(NCPh2)

(2008) Neal P. Mankad et al.   CHEMICAL COMMUNICATIONS

Coinage Metal Catalyzed C−H Bond Functionalization of Hydrocarbons

(2008) M. Mar Díaz-Requejo et al.   CHEMICAL REVIEWS

A Non-Cross-Linked Soluble Polystyrene-Supported Ruthenium Catalyst for Carbenoid Transfer Reactions

(2008) Matthew Kwok-Wai Choi et al.   Chemistry-An Asian Journal

Synthesis of new copper(i) complexes with tris(2-pyridyl) ligands. Applications to carbene and nitrene transfer reactions

(2008) Julio Pérez et al.   DALTON TRANSACTIONS

Synthesis, Molecular Structures, and Reactivity of Mono- and Binuclear Neutral Copper(I) Carbenes

(2008) Peter Hofmann et al.   INORGANIC CHEMISTRY

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

(2008) Huw M. L. Davies et al.   NATURE

Catalytic C−H Insertions Using Iron(III) Porphyrin Complexes

(2008) Harun M. Mbuvi et al.   ORGANOMETALLICS

A New Perfluorinated F21-Tp Scorpionate Ligand: Enhanced Alkane Functionalization by Carbene Insertion with (F21-Tp)M Catalysts (M = Cu, Ag)

(2008) Emmanuelle Despagnet-Ayoub et al.   ORGANOMETALLICS

Silver-Catalyzed C-H Insertion Reactions with Donor-Acceptor Diazoacetates

(2008) Carl Lovely et al.   SYNLETT