Chiral proton-transfer shuttle catalysts for carbene insertion reactions

Enantioselective Nazarov cyclization of indole enones cooperatively catalyzed by Lewis acids and chiral Brønsted acids

(2017) Guo-Peng Wang et al.   Chemical Science

Enantioselective Copper-Catalyzed Intramolecular N−H Bond Insertion: Synthesis of Chiral 2-Carboxytetrahydroquinolines

(2016) Xiao-Guang Song et al.   ADVANCED SYNTHESIS & CATALYSIS

Mechanistic Insights into Asymmetric C–H Insertion Cooperatively Catalyzed by a Dirhodium(II) Complex and Chiral Phosphoric Acid

(2016) Hui Liu et al.   ORGANOMETALLICS

Asymmetric O–H insertion reaction of carbenoids catalyzed by chiral bicyclo bisoxazoline copper(I) and (II) complexes

(2016) Paul Le Maux et al.   TETRAHEDRON

Enantioselective synthesis of α-alkenyl α-amino acids via N–H insertion reactions

(2016) Jun-Xia Guo et al.   Chemical Science

Asymmetric Catalytic Insertion of α-Diazo Carbonyl Compounds into O–H Bonds of Carboxylic Acids

(2016) Fei Tan et al.   ACS Catalysis

Enantioselective Palladium-Catalyzed CH Functionalization of Indoles Using an Axially Chiral 2,2′-Bipyridine Ligand

(2015) Xiang Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Modern Organic Synthesis with α-Diazocarbonyl Compounds

(2015) Alan Ford et al.   CHEMICAL REVIEWS

Axial Coordination Dichotomy in Dirhodium Carbenoid Catalysis: A Curious Case of Cooperative Asymmetric Dual-Catalytic Approach toward Amino Esters

(2015) Hemanta K. Kisan et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Asymmetric Arylation of α-Aryl-α-diazoacetates with Aniline Derivatives

(2015) Bin Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of planar chiral [2.2]paracyclophane-based bisoxazoline ligands bearing no central chirality and application to Cu-catalyzed asymmetric O–H insertion reaction

(2015) Shinji Kitagaki et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective insertion of carbenoids into N–H bonds catalyzed by chiral bicyclobisoxazoline copper(I) complexes

(2015) Paul Le Maux et al.   TETRAHEDRON

Modular construction of multifunctional ligands for the enantioselective ruthenium-catalyzed carbenoid N–H insertion reaction: an enzyme-like and substrate-sensitive catalyst system

(2015) Wei-Sheng Huang et al.   RSC Advances

Magical Chiral Spiro Ligands

(2015) Jianhua Xie et al.   ACTA CHIMICA SINICA

Enantioselective Palladium-Catalyzed Insertion of α-Aryl-α-diazoacetates into the OH Bonds of Phenols

(2014) Xiu-Lan Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric NH Insertion of Secondary and Primary Anilines under the Catalysis of Palladium and Chiral Guanidine Derivatives

(2014) Yin Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective NH Insertion Reaction of α-Aryl α-Diazoketones: An Efficient Route to Chiral α-Aminoketones

(2014) Bin Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Deciphering the origin of cooperative catalysis by dirhodium acetate and chiral spiro phosphoric acid in an asymmetric amination reaction

(2014) Hemanta K. Kisan et al.   CHEMICAL COMMUNICATIONS

Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates

(2014) Dixit Parmar et al.   CHEMICAL REVIEWS

Asymmetric N—H Insertion Reaction ofα-Diazoesters and Carbamates Co-catalyzed by Dirhodium Acetate, Sufonic Acid and Chiral Sulfonamide Urea

(2014) Yi Ni et al.   CHINESE JOURNAL OF ORGANIC CHEMISTRY

Mechanistic Insight into Asymmetric N–H Insertion Cooperatively Catalyzed by a Dirhodium Compound and a Spiro Chiral Phosphoric Acid

(2014) Xu-Chao Wang et al.   ORGANOMETALLICS

Mechanistic Insights on Cooperative Catalysis through Computational Quantum Chemical Methods

(2014) Garima Jindal et al.   ACS Catalysis

Iron-catalyzed transformations of diazo compounds

(2014) Shou-Fei Zhu et al.   National Science Review

Asymmetric C—H Functionalization of Indoles via Enantioselective Protonation

(2013) Huang Qiu et al.   ACTA CHIMICA SINICA

Enantioselective Copper-Catalyzed Intramolecular Phenolic OH Bond Insertion: Synthesis of Chiral 2-Carboxy Dihydrobenzofurans, Dihydrobenzopyrans, and Tetrahydrobenzooxepines

(2013) Xiao-Guang Song et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly enantioselective S–H bond insertion cooperatively catalyzed by dirhodium complexes and chiral spiro phosphoric acids

(2013) Bin Xu et al.   Chemical Science

Transition-Metal-Catalyzed Enantioselective Heteroatom–Hydrogen Bond Insertion Reactions

(2012) Shou-Fei Zhu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Synthesis of Tetrahydropyridazines by a Metal-Carbene-Directed Enantioselective Vinylogous NH Insertion/Lewis Acid-Catalyzed Diastereoselective Mannich Addition

(2012) Xinfang Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cinchona alkaloids induce asymmetry in the insertion reaction of thermally generated carbenes into N−H bonds

(2012) Hiroaki Saito et al.   TETRAHEDRON LETTERS

Asymmetric NH Insertion Reaction Cooperatively Catalyzed by Rhodium and Chiral Spiro Phosphoric Acids

(2011) Bin Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Optically Active 1,1′-Spirobiindane-7,7′-diol (SPINOL)-Based Phosphoric Acids as Highly Enantioselective Catalysts for Asymmetric Organocatalysis

(2011) Chun-Hui Xing et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Carbenoid Insertion into Phenolic O–H Bonds with a Chiral Copper(I) Imidazoindolephosphine Complex

(2011) Takao Osako et al.   ORGANIC LETTERS

SPINOL-Derived Phosphoric Acids: Synthesis and Application in Enantioselective Friedel−Crafts Reaction of Indoles with Imines

(2010) Fangxi Xu et al.   JOURNAL OF ORGANIC CHEMISTRY

Kinetic Resolution of Homoaldols via Catalytic Asymmetric Transacetalization

(2010) Ilija Čorić et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-catalyzed enantioselective carbenoid insertion into S–H bonds

(2009) Yong-Zhen Zhang et al.   CHEMICAL COMMUNICATIONS

Why Is Copper(I) Complex More Competent Than Dirhodium(II) Complex in Catalytic Asymmetric O−H Insertion Reactions? A Computational Study of the Metal Carbenoid O−H Insertion into Water

(2009) Yong Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric intermolecular cyclopropanation of alkenes by diazoketones catalyzed by Halterman iron porphyrins

(2009) Irène Nicolas et al.   TETRAHEDRON LETTERS

Chiral Diphosphine and Monodentate Phosphorus Ligands on a Spiro Scaffold for Transition-Metal-Catalyzed Asymmetric Reactions

(2008) Jian-Hua Xie et al.   ACCOUNTS OF CHEMICAL RESEARCH

Binaphthol-derived phosphoric acid as a versatile catalyst for enantioselective carbon–carbon bond forming reactions

(2008) Masahiro Terada   CHEMICAL COMMUNICATIONS