Stabilization of a Chiral Dirhodium Carbene by Encapsulation and a Discussion of the Stereochemical Implications

A Mixed-Ligand Chiral Rhodium(II) Catalyst Enables the Enantioselective Total Synthesis of Piperarborenine B

(2016) Robert A. Panish et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Halogen Bond

(2016) Gabriella Cavallo et al.   CHEMICAL REVIEWS

Design and Synthesis of Novel Chiral Dirhodium(II) Carboxylate Complexes for Asymmetric Cyclopropanation Reactions

(2016) Frady G. Adly et al.   CHEMISTRY-A EUROPEAN JOURNAL

Structures of Reactive Donor/Acceptor and Donor/Donor Rhodium Carbenes in the Solid State and Their Implications for Catalysis

(2016) Christophe Werlé et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-Catalyzed Intermolecular Reactions of α-Alkyl-α-Diazo Carbonyl Compounds with Selectivity over β-Hydride Migration

(2015) Andrew DeAngelis et al.   ACCOUNTS OF CHEMICAL RESEARCH

The First Crystal Structure of a Reactive Dirhodium Carbene Complex and a Versatile Method for the Preparation of Gold Carbenes by Rhodium-to-Gold Transmetalation

(2015) Christophe Werlé et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Modern Organic Synthesis with α-Diazocarbonyl Compounds

(2015) Alan Ford et al.   CHEMICAL REVIEWS

Mechanism and stereoselectivity of the Rh(ii)-catalyzed cyclopropanation of diazooxindole: a density functional theory study

(2015) Yun-Sheng Xue et al.   RSC Advances

Structure of a Reactive Gold Carbenoid

(2014) Günter Seidel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Dirhodium(II) Carboxylates and Carboxamidates as Effective Chemzymes in Asymmetric Synthesis of Three-Membered Carbocycles

(2014) Frady G. Adly et al.   CHIRALITY

Novel Multicomponent Reactions via Trapping of Protic Onium Ylides with Electrophiles

(2013) Xin Guo et al.   ACCOUNTS OF CHEMICAL RESEARCH

Gold Carbenoids: Lessons Learnt from a Transmetalation Approach

(2013) Günter Seidel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Spectroscopic Characterization of a Transitory Dirhodium Donor-Acceptor Carbene Complex

(2013) K. P. Kornecki et al.   SCIENCE

Intramolecular generation and rearrangement of oxonium ylides: methodology studies and their application in synthesis

(2013) Graham K. Murphy et al.   TETRAHEDRON

The Combined C–H Functionalization/Cope Rearrangement: Discovery and Applications in Organic Synthesis

(2012) Huw M. L. Davies et al.   ACCOUNTS OF CHEMICAL RESEARCH

Metal-Catalyzed Nitrogen-Atom Transfer Methods for the Oxidation of Aliphatic C–H Bonds

(2012) Jennifer L. Roizen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Transition-Metal-Catalyzed Enantioselective Heteroatom–Hydrogen Bond Insertion Reactions

(2012) Shou-Fei Zhu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Rh2(S-PTTL)3TPA—a mixed-ligand dirhodium(ii) catalyst for enantioselective reactions of α-alkyl-α-diazoesters

(2012) David T. Boruta et al.   Chemical Science

Design and Synthesis of Chiral Heteroleptic Rhodium(II) Carboxylate Catalysts: Experimental Investigation of Halogen Bond Rigidification Effects in Asymmetric Cyclopropanation

(2012) Vincent N. G. Lindsay et al.   ACS Catalysis

Highly Enantioselective Cyclopropenation Reaction of 1-Alkynes with α-Alkyl-α-Diazoesters Catalyzed by Dirhodium(II) Carboxylates

(2011) Takayuki Goto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The role of three-center/four-electron bonds in superelectrophilic dirhodium carbene and nitrene catalytic intermediates

(2011) John F. Berry   DALTON TRANSACTIONS

Optimizing dirhodium(ii) tetrakiscarboxylates as chiral NMR auxiliaries

(2011) Jens T. Mattiza et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantio- and diastereoselective cyclopropanation with tert-butyl α-diazopropionate catalyzed by dirhodium(II) tetrakis[N-tetrabromophthaloyl-(S)-tert-leucinate]

(2011) Takayuki Goto et al.   TETRAHEDRON LETTERS

The chiral crown conformation in paddlewheel complexes

(2010) Andrew DeAngelis et al.   CHEMICAL COMMUNICATIONS

First X-ray Structure of aN-Naphthaloyl-Tethered Chiral Dirhodium(II) Complex: Structural Basis for Tether Substitution Improving Asymmetric Control in Olefin Cyclopropanation

(2010) Ashraf Ghanem et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Carbene Insertion into C−H Bonds

(2009) Michael P. Doyle et al.   CHEMICAL REVIEWS

Computational Study on the Selectivity of Donor/Acceptor-Substituted Rhodium Carbenoids

(2009) Jørn Hansen et al.   JOURNAL OF ORGANIC CHEMISTRY

Chiral Crown Conformation of Rh2(S-PTTL)4: Enantioselective Cyclopropanation with α-Alkyl-α-diazoesters

(2009) Andrew DeAngelis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental Evidence for the All-Up Reactive Conformation of Chiral Rhodium(II) Carboxylate Catalysts: Enantioselective Synthesis ofcis-Cyclopropane α-Amino Acids

(2009) Vincent N. G. Lindsay et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

(2008) Huw M. L. Davies et al.   NATURE

Recent studies on the reactions of α-diazocarbonyl compounds

(2008) Zhenhua Zhang et al.   TETRAHEDRON