A New Ligand Design Based on London Dispersion Empowers Chiral Bismuth–Rhodium Paddlewheel Catalysts

Catalytic Asymmetric Fluorination of Copper Carbene Complexes: Preparative Advances and a Mechanistic Rationale

(2020) Michael Buchsteiner et al.   CHEMISTRY-A EUROPEAN JOURNAL

Unveiling the Delicate Balance of Steric and Dispersion Interactions in Organocatalysis Using High-Level Computational Methods

(2020) Diana Yepes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-catalysed anti-Markovnikov hydroarylation of unactivated alkenes with unactivated arenes facilitated by non-covalent interactions

(2020) Noam I. Saper et al.   Nature Chemistry

A Heteroleptic Dirhodium Catalyst for Asymmetric Cyclopropanation with α‐Stannyl α‐Diazoacetate.Stereoretentive Stille Coupling with Formation of Chiral Quarternary Carbon Centers

(2020) Alois Fürstner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition Metal Catalyzed Insertion Reactions with Donor/Donor Carbenes

(2020) Jared Thomas Shaw et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Perspectives on Rearrangement Reactions of Ylides via Carbene Transfer Reactions

(2020) Sripati Jana et al.   CHEMISTRY-A EUROPEAN JOURNAL

Application of Trimethylgermanyl-Substituted Bisphosphine Ligands with Enhanced Dispersion Interactions to Copper-Catalyzed Hydroboration of Disubstituted Alkenes

(2020) Yumeng Xi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral paddle-wheel diruthenium complexes for asymmetric catalysis

(2020) Taku Miyazawa et al.   Nature Catalysis

London Dispersion Rather than Steric Hindrance Determines the Enantioselectivity of the Corey‐Bakshi‐Shibata Reduction

(2020) Christian Eschmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intramolecular London Dispersion Interactions Do Not Cancel in Solution

(2020) Jan M. Schümann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Heterobimetallic Bismuth-Rhodium Paddlewheel Catalysts: A Conceptually New Approach to Asymmetric Cyclopropanation

(2019) Lee R. Collins et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Finding chemical concepts in the Hilbert space: Coupled cluster analyses of noncovalent interactions

(2019) Giovanni Bistoni   Wiley Interdisciplinary Reviews-Computational Molecular Science

In Situ Kinetic Studies of Rh(II)-Catalyzed Asymmetric Cyclopropanation with Low Catalyst Loadings

(2019) Bo Wei et al.   ACS Catalysis

Structure and Reactivity of Half-Sandwich Rh(+3) and Ir(+3) Carbene Complexes. Catalytic Metathesis of Azobenzene Derivatives

(2018) Daniel J. Tindall et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral proton-transfer shuttle catalysts for carbene insertion reactions

(2018) Yuan-Yuan Ren et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enhanced Electrophilicity of Heterobimetallic Bi-Rh Paddlewheel Carbene Complexes: A Combined Experimental, Spectroscopic and Computational Study

(2018) Lee R. Collins et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistically Guided Design of Ligands that Significantly Improve the Efficiency of CuH-Catalyzed Hydroamination Reactions

(2018) Andy A Thomas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Comparison of Reactivity and Enantioselectivity between Chiral Bimetallic Catalysts: Bismuth-Rhodium and Dirhodium Catalyzed Carbene Chemistry

(2018) Zhi Ren et al.   ACS Catalysis

Metal–Metal Bonds: From Fundamentals to Applications

(2017) John F. Berry et al.   INORGANIC CHEMISTRY

Ligand–Substrate Dispersion Facilitates the Copper-Catalyzed Hydroamination of Unactivated Olefins

(2017) Gang Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Software update: the ORCA program system, version 4.0

(2017) Frank Neese   Wiley Interdisciplinary Reviews-Computational Molecular Science

On the Structure of Chiral Dirhodium(II) Carboxylate Catalysts: Stereoselectivity Relevance and Insights

(2017) Frady Adly   Catalysts

London dispersion forces in sterically crowded inorganic and organometallic molecules

(2017) David J. Liptrot et al.   Nature Reviews Chemistry

Stabilization of a Chiral Dirhodium Carbene by Encapsulation and a Discussion of the Stereochemical Implications

(2016) Christophe Werlé et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dispersion-Corrected Mean-Field Electronic Structure Methods

(2016) Stefan Grimme et al.   CHEMICAL REVIEWS

Metal-Metal Single Bonds with the Magnetic Anisotropy of Quadruple Bonds: A Systematic Series of Heterobimetallic Bismuth(II)-Rhodium(II) Formamidinate Complexes

(2016) Travis L. Sunderland et al.   CHEMISTRY-A EUROPEAN JOURNAL

Design and Synthesis of Novel Chiral Dirhodium(II) Carboxylate Complexes for Asymmetric Cyclopropanation Reactions

(2016) Frady G. Adly et al.   CHEMISTRY-A EUROPEAN JOURNAL

Expanding the family of heterobimetallic Bi–Rh paddlewheel carboxylate complexes via equatorial carboxylate exchange

(2016) Travis L. Sunderland et al.   DALTON TRANSACTIONS

Decomposition of Intermolecular Interaction Energies within the Local Pair Natural Orbital Coupled Cluster Framework

(2016) Wolfgang B. Schneider et al.   Journal of Chemical Theory and Computation

The first bismuth(II)–rhodium(II) oxypyridinate paddlewheel complexes: synthesis and structural characterization

(2016) Travis L. Sunderland et al.   JOURNAL OF COORDINATION CHEMISTRY

Structures of Reactive Donor/Acceptor and Donor/Donor Rhodium Carbenes in the Solid State and Their Implications for Catalysis

(2016) Christophe Werlé et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(I)-Catalyzed Highly Enantioselective Insertion of Carbenoid into Si–H: Efficient Access to Functional Chiral Silanes

(2016) Diao Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-selective and stereoselective functionalization of unactivated C–H bonds

(2016) Kuangbiao Liao et al.   NATURE

Metal–Metal Bonds in Catalysis

(2016) Ian G. Powers et al.   ACS Catalysis

Rh-Catalyzed Intermolecular Reactions of α-Alkyl-α-Diazo Carbonyl Compounds with Selectivity over β-Hydride Migration

(2015) Andrew DeAngelis et al.   ACCOUNTS OF CHEMICAL RESEARCH

The First Crystal Structure of a Reactive Dirhodium Carbene Complex and a Versatile Method for the Preparation of Gold Carbenes by Rhodium-to-Gold Transmetalation

(2015) Christophe Werlé et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

London Dispersion in Molecular Chemistry-Reconsidering Steric Effects

(2015) J. Philipp Wagner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Modern Organic Synthesis with α-Diazocarbonyl Compounds

(2015) Alan Ford et al.   CHEMICAL REVIEWS

Catalytic functionalization of low reactive C(sp3)–H and C(sp2)–H bonds of alkanes and arenes by carbene transfer from diazo compounds

(2015) Ana Caballero et al.   DALTON TRANSACTIONS

Mechanism and stereoselectivity of the Rh(ii)-catalyzed cyclopropanation of diazooxindole: a density functional theory study

(2015) Yun-Sheng Xue et al.   RSC Advances

2,2,2-Trichloroethyl Aryldiazoacetates as Robust Reagents for the Enantioselective C–H Functionalization of Methyl Ethers

(2014) David M. Guptill et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dispersion Makes the Difference: Bisligated Transition States Found for the Oxidative Addition of Pd(PtBu3)2 to Ar-OSO2R and Dispersion-Controlled Chemoselectivity in Reactions with Pd[P(iPr)(tBu2)]2

(2014) Eirik Lyngvi et al.   ORGANOMETALLICS

Catalytic X–H insertion reactions based on carbenoids

(2013) Dennis Gillingham et al.   CHEMICAL SOCIETY REVIEWS

Guide to enantioselective dirhodium(II)-catalyzed cyclopropanation with aryldiazoacetates

(2013) Kathryn M. Chepiga et al.   TETRAHEDRON

The Combined C–H Functionalization/Cope Rearrangement: Discovery and Applications in Organic Synthesis

(2012) Huw M. L. Davies et al.   ACCOUNTS OF CHEMICAL RESEARCH

Transition-Metal-Catalyzed Enantioselective Heteroatom–Hydrogen Bond Insertion Reactions

(2012) Shou-Fei Zhu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Highly enantioselective intermolecular carbene insertion to C–H and Si–H bonds catalyzed by a chiral iridium(iii) complex of a D4-symmetric Halterman porphyrin ligand

(2012) Jing-Cui Wang et al.   CHEMICAL COMMUNICATIONS

Highly Enantioselective Cyclopropenation Reaction of 1-Alkynes with α-Alkyl-α-Diazoesters Catalyzed by Dirhodium(II) Carboxylates

(2011) Takayuki Goto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From Solid State to Solution: Advancing Chemistry of Bi–Bi and Bi–Rh Paddlewheel Carboxylates

(2011) Alexander S. Filatov et al.   INORGANIC CHEMISTRY

Optimizing dirhodium(ii) tetrakiscarboxylates as chiral NMR auxiliaries

(2011) Jens T. Mattiza et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantio- and diastereoselective cyclopropanation with tert-butyl α-diazopropionate catalyzed by dirhodium(II) tetrakis[N-tetrabromophthaloyl-(S)-tert-leucinate]

(2011) Takayuki Goto et al.   TETRAHEDRON LETTERS

The chiral crown conformation in paddlewheel complexes

(2010) Andrew DeAngelis et al.   CHEMICAL COMMUNICATIONS

Synthesis and Applications oftert-Butanesulfinamide

(2010) MaryAnn T. Robak et al.   CHEMICAL REVIEWS

First X-ray Structure of aN-Naphthaloyl-Tethered Chiral Dirhodium(II) Complex: Structural Basis for Tether Substitution Improving Asymmetric Control in Olefin Cyclopropanation

(2010) Ashraf Ghanem et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metallopeptides for Asymmetric Dirhodium Catalysis

(2010) Ramya Sambasivan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium(III)-Catalyzed Enantioselective Si−H Bond Insertion and Formation of an Enantioenriched Silicon Center

(2010) Yoichi Yasutomi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Carbene Insertion into C−H Bonds

(2009) Michael P. Doyle et al.   CHEMICAL REVIEWS

Catalytic [2,3]-sigmatropic rearrangement of sulfur ylide derived from metal carbene

(2009) Yan Zhang et al.   COORDINATION CHEMISTRY REVIEWS

Combined Experimental and Computational Studies of Heterobimetallic Bi−Rh Paddlewheel Carboxylates as Catalysts for Metal Carbenoid Transformations

(2009) Jo̷rn Hansen et al.   JOURNAL OF ORGANIC CHEMISTRY

Chiral Crown Conformation of Rh2(S-PTTL)4: Enantioselective Cyclopropanation with α-Alkyl-α-diazoesters

(2009) Andrew DeAngelis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental Evidence for the All-Up Reactive Conformation of Chiral Rhodium(II) Carboxylate Catalysts: Enantioselective Synthesis ofcis-Cyclopropane α-Amino Acids

(2009) Vincent N. G. Lindsay et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Why Is Copper(I) Complex More Competent Than Dirhodium(II) Complex in Catalytic Asymmetric O−H Insertion Reactions? A Computational Study of the Metal Carbenoid O−H Insertion into Water

(2009) Yong Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Reactions of Donor/Acceptor Carbenoids Derived from α-Aryl-α-Diazoketones

(2009) Justin R. Denton et al.   ORGANIC LETTERS

Copper-Catalyzed Highly Enantioselective Carbenoid Insertion into SiH Bonds

(2008) Yong-Zhen Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

(2008) Huw M. L. Davies et al.   NATURE

Recent studies on the reactions of α-diazocarbonyl compounds

(2008) Zhenhua Zhang et al.   TETRAHEDRON