Enantioselective Synthesis of α-All-Carbon Quaternary Center-Containing Carbazolones via Amino-palladation/Desymmetrizing Nitrile Addition Cascade

Recent Advances and Perspectives in the Synthesis and Applications of Tetrahydrocarbazol‐4‐ones

(2020) Muhammad Usman et al.   CHINESE JOURNAL OF CHEMISTRY

Enantioselective Assembly of Cycloenones with a Nitrile-Containing All-Carbon Quaternary Center from Malononitriles Enabled by Ni Catalysis

(2020) Zhiwu Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of Kopsinitarine E

(2020) Karre Nagaraju et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Aminopalladation‐Heck Cascade

(2020) Jieping Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthetic Approaches to Tricyclic Aminoketones in the Total Synthesis of Aspidosperma and Kopsia Alkaloids

(2020) Nengzhong Wang et al.   CHEMICAL RECORD

Total Synthesis of (+)-Aspidospermidine

(2019) Hongjin Xu et al.   ORGANIC LETTERS

Asymmetric Total Synthesis of (+)-Winchinine B

(2019) Zaimin Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Thiourea-Catalyzed Asymmetric Michael Addition of Carbazolones to 2-Chloroacrylonitrile: Total Synthesis of 5,22-Dioxokopsane, Kopsinidine C, and Demethoxycarbonylkopsin

(2018) Dongshun Ni et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Divergent Strategy in Natural Product Total Synthesis

(2018) Lei Li et al.   CHEMICAL REVIEWS

Enantioselective palladium-catalyzed allylic alkylation reactions in the synthesis of Aspidosperma and structurally related monoterpene indole alkaloids

(2018) Beau P. Pritchett et al.   NATURAL PRODUCT REPORTS

Enantioselective Electrophilic Cyanation of Boron Enolates: Scope and Mechanistic Studies

(2018) Takaya Nagata et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Active Platinum Catalysts for Nitrile and Cyanohydrin Hydration: Catalyst Design and Ligand Screening via High-Throughput Techniques

(2018) Xiangyou Xing et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Divergent Coupling of 2-Carbonyl-anilines and Diazo-cyclopentanones: Asymmetric Total Synthesis of (+)-Leucomidine A

(2018) Xiaotong Yao et al.   ORGANIC LETTERS

Palladium(II)-Catalyzed Asymmetric Tandem Cyclization of 2-Aminoaryl Alkynones: An Approach to Chiral 1,2,3,4-Tetrahydro-β-carbolines

(2018) Junjie Chen et al.   ORGANIC LETTERS

Monoterpenoid Indole Alkaloids from Kopsia officinalis and the Immunosuppressive Activity of Rhazinilam

(2017) Ting Zeng et al.   JOURNAL OF NATURAL PRODUCTS

Recent advances on the total synthesis of alkaloids in mainland China

(2017) Yong Li et al.   National Science Review

Catalytic Enantioselective Desymmetrization Reactions to All-Carbon Quaternary Stereocenters

(2016) Xing-Ping Zeng et al.   CHEMICAL REVIEWS

Organocatalytic enantioselective desymmetrisation

(2016) A. Borissov et al.   CHEMICAL SOCIETY REVIEWS

Chiral N,N′-Dioxide Organocatalyzed Asymmetric Electrophilic α-Cyanation of β-Keto Esters and β-Keto Amides

(2016) Baiwei Ma et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Enantioselective Construction of Quaternary Stereocenters: Assembly of Key Building Blocks for the Synthesis of Biologically Active Molecules

(2015) Yiyang Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Aqueous Titanium Trichloride Promoted Reductive Cyclization ofo-Nitrostyrenes to Indoles: Development and Application to the Synthesis of Rizatriptan and Aspidospermidine

(2015) Shuo Tong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aspidofractinine and Eburnane Alkaloids from a North Borneo Kopsia. Ring-Contracted, Additional Ring-Fused, and Paucidactine-Type Aspidofractinine Alkaloids from K. pauciflora

(2015) Wai-Sum Yap et al.   JOURNAL OF NATURAL PRODUCTS

Enantioselective Synthesis of α-Quaternary Mannich Adducts by Palladium-Catalyzed Allylic Alkylation: Total Synthesis of (+)-Sibirinine

(2015) Yoshitaka Numajiri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Concise total synthesis of (±)-aspidospermidine

(2015) Haichen Ma et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Catalytic Enantioselective and Divergent Total Synthesis of (+)-10-Oxocylindrocarpidine, (+)-Cylindrocarpidine, (−)-N-Acetylcylindrocarpinol, and (+)-Aspidospermine

(2014) Xiao-Lei Shen et al.   JOURNAL OF ORGANIC CHEMISTRY

All-Carbon Quaternary Stereogenic Centers in Acyclic Systems through the Creation of Several C–C Bonds per Chemical Step

(2014) Ilan Marek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic enantioselective synthesis of quaternary carbon stereocentres

(2014) Kyle W. Quasdorf et al.   NATURE

Catalytic Asymmetric Assembly of C3-Monosubstituted Chiral Carbazolones and Concise Formal Synthesis of (−)-Aspidofractinine: Application of Enantioselective Pd-Catalyzed Decarboxylative Protonation of Carbazolones

(2014) Ruirui Zhao et al.   ORGANIC LETTERS

Pd(II)-Catalyzed One-Step Construction of Cycloalkane-Fused Indoles and Its Application in Formal Synthesis of (±)-Aspidospermidine

(2014) Guoqin Xia et al.   ORGANIC LETTERS

Biosynthetically Inspired Divergent Approach to Monoterpene Indole Alkaloids: Total Synthesis of Mersicarpine, Leuconodines B and D, Leuconoxine, Melodinine E, Leuconolam, and Rhazinilam

(2014) Yang Yang et al.   ORGANIC LETTERS

Recent advances of desymmetrization protocol applied in natural product total synthesis

(2014) Ming Wang et al.   TETRAHEDRON LETTERS

Enantioselective Palladium-Catalyzed Decarboxylative Allylation of Carbazolones: Total Synthesis of (−)-Aspidospermidine and (+)-Kopsihainanine A

(2013) Zeqian Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of the Indole Alkaloid (±)- and (+)-MethylN-Decarbomethoxychanofruticosinate

(2013) Yi Wei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

General Entry to Aspidosperma Alkaloids: Enantioselective Total Synthesis of (−)-Aspidophytine

(2013) Rongwen Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Palladium-Catalyzed Decarboxylative Allylation of Carbazolones and Indolones: Formal Synthesis of (+)-Kopsihainanine A

(2013) Christopher J. Gartshore et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Studies on the Enantioselective Synthesis of Carbazolones as Intermediates in Aspidosperma and Kopsia Alkaloid Synthesis

(2013) Christopher J. Gartshore et al.   AUSTRALIAN JOURNAL OF CHEMISTRY

The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total Synthesis

(2013) Allen Y. Hong et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Total Synthesis of (−)-Limaspermidine and Formal Synthesis of (−)-1-Acetylaspidoalbidine

(2013) Shao-Xiong Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of 3-Acylindoles by Palladium-Catalyzed Acylation of Free (N–H) Indoles with Nitriles

(2013) Tao-Shan Jiang et al.   ORGANIC LETTERS

Palladium(II)-Catalyzed Cyclization Reaction of 2-(Alk-2′-ynyl- oxy)benzonitriles or 2-(Alk-2′-ynylamino)benzonitriles: A Facile Way to 2H-Chromene and 1,2-Dihydroquinoline Derivatives

(2012) Guoqin Xia et al.   ADVANCED SYNTHESIS & CATALYSIS

Total Synthesis of (±)-Kopsihainanine A

(2012) Peng Jing et al.   CHEMISTRY-A EUROPEAN JOURNAL

Forming all-carbon quaternary stereogenic centres in acyclic systems from alkynes

(2012) Yury Minko et al.   NATURE

Transition Metal-Catalyzed Decarboxylative Allylation and Benzylation Reactions

(2011) Jimmie D. Weaver et al.   CHEMICAL REVIEWS

Nitrile Ligated Transition Metal Complexes with Weakly Coordinating Counteranions and Their Catalytic Applications

(2009) Silvana F. Rach et al.   CHEMICAL REVIEWS