Recent Advances in the Synthesis of Heterocycles and Related Substances Based on α-Imino Rhodium Carbene Complexes Derived fromN-Sulfonyl-1,2,3-triazoles

Rhodium(II)-Catalysed Skeletal Rearrangement of Ether TetheredN-Sulfonyl 1,2,3-Triazoles: a Rapid Approach to 2-Aminoindanone and Dihydroisoquinoline Derivatives

(2016) Yinghua Yu et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium-Catalyzed Synthesis of 4-Bromo-1,2-dihydroisoquinolines: Access to Bromonium Ylides by the Intramolecular Reaction of a Benzyl Bromide and an α-Imino Carbene

(2016) Jun He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(II)-Catalyzed and Thermally Induced Intramolecular Migration ofN-Sulfonyl-1,2,3-triazoles: New Approaches to 1,2-Dihydroisoquinolines and 1-Indanones

(2016) Run Sun et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Reaction of Triazoles with Thioesters to Produce β-Sulfanyl Enamides by Insertion of an Enamine Moiety into the Sulfur-Carbonyl Bond

(2015) Tomoya Miura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(II) Azavinyl Carbenes and their Recent Application to Organic Synthesis

(2015) Samantha C. Hockey et al.   AUSTRALIAN JOURNAL OF CHEMISTRY

Intramolecular annulation of aromatic rings with N-sulfonyl 1,2,3-triazoles: divergent synthesis of 3-methylene-2,3-dihydrobenzofurans and 3-methylene-2,3-dihydroindoles

(2015) Xiang-Ying Tang et al.   CHEMICAL COMMUNICATIONS

Rh(ii)-catalyzed cycloadditions of 1-tosyl 1,2,3-triazoles with 2H-azirines: switchable reactivity of Rh-azavinylcarbene as [2C]- or aza-[3C]-synthon

(2015) Yuanhao Wang et al.   CHEMICAL COMMUNICATIONS

A Rh-catalyzed 1,2-sulfur migration/aza-Diels–Alder cascade initiated by aza-vinyl carbenoids from sulfur-tethered N-sulfonyl-1,2,3-triazoles

(2015) Yu Jiang et al.   CHEMICAL COMMUNICATIONS

RhII-Catalyzed [3+2] Cycloaddition of 2 H-Azirines withN-Sulfonyl-1,2,3-Triazoles

(2015) Yun-Zhou Zhao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Synthesis of 2,5-Epoxybenzo[f][1,4]oxazepines by Tandem Reaction of 1-Sulfonyl-1,2,3-triazoles and Salicylaldehydes

(2015) Yinping Shi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Pyrazines from Rhodium-Catalyzed Reaction of 2H-Azirines with N-Sulfonyl 1,2,3-Triazoles

(2015) Taekyu Ryu et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of β-Amino-α,β-unsaturated Ketone Derivatives via Sequential Rhodium-Catalyzed Sulfur Ylide Formation/Rearrangement

(2015) Jun He et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-catalyzed denitrogenative thioacetalization of N-sulfonyl-1,2,3-triazoles with disulfides: an entry to diverse transformation of terminal alkynes

(2015) Hao Zhang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium(ii)-catalyzed intramolecular formal [4 + 3] cycloadditions of dienyltriazoles: rapid access to fused 2,5-dihydroazepines

(2015) Yu Tian et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Facile Synthesis of 2,5-Disubstituted Thiazoles from Terminal Alkynes, Sulfonyl Azides, and Thionoesters

(2015) Tomoya Miura et al.   ORGANIC LETTERS

Rhodium(II)-Catalyzed Formal [3 + 2] Cycloaddition of N-Sulfonyl-1,2,3-triazoles with Isoxazoles: Entry to Polysubstituted 3-Aminopyrroles

(2015) Xiaoqiang Lei et al.   ORGANIC LETTERS

Rhodium-Azavinylcarbene: A Versatile Synthon-Enabling Divergent Synthesis of Nitrogen Heterocycles

(2015) Yefeng Tang et al.   SYNLETT

Tandem 1,2-sulfur migration and (aza)-Diels–Alder reaction of β-thio-α-diazoimines: rhodium catalyzed synthesis of (fused)-polyhydropyridines, and cyclohexenes

(2015) Dongari Yadagiri et al.   Chemical Science

Divergent synthesis of indole-fused polycycles via Rh(ii)-catalyzed intramolecular [3 + 2] cycloaddition and C–H functionalization of indolyltriazoles

(2015) Yong-Sheng Zhang et al.   Organic Chemistry Frontiers

Rhodium-catalyzed synthesis of multi-substituted furans from N-sulfonyl-1,2,3-triazoles bearing a tethered carbonyl group

(2015) Wen-Biao Zhang et al.   Organic Chemistry Frontiers

The [3 + 3]-Cycloaddition Alternative for Heterocycle Syntheses: Catalytically Generated Metalloenolcarbenes as Dipolar Adducts

(2014) Xinfang Xu et al.   ACCOUNTS OF CHEMICAL RESEARCH

The Divergent Synthesis of Nitrogen Heterocycles by Rhodium(II)-Catalyzed Cycloadditions of 1-Sulfonyl 1,2,3-Triazoles with 1,3-Dienes

(2014) Hai Shang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Expedient Synthesis of Fused Azepine Derivatives Using a Sequential Rhodium(II)-Catalyzed Cyclopropanation/1-Aza-Cope Rearrangement of Dienyltriazoles

(2014) Erica E. Schultz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Transannulation of NH-1,2,3-Triazoles with Olefins

(2014) Sen Wai Kwok et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(II)-Catalyzed Intramolecular Cycloisomerizations of Methylenecyclopropanes withN-Sulfonyl 1,2,3-Triazoles

(2014) Kai Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unprecedented synthesis of aza-bridged benzodioxepine derivatives through a tandem Rh(ii)-catalyzed 1,3-rearrangement/[3+2] cycloaddition of carbonyltriazoles

(2014) Yong-Sheng Zhang et al.   CHEMICAL COMMUNICATIONS

A Rh-catalyzed regio- and stereoselective route to enamides: benzamides as assembling reagents

(2014) Dong Jin Lee et al.   CHEMICAL COMMUNICATIONS

Reactions of metallocarbenes derived from N-sulfonyl-1,2,3-triazoles

(2014) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

Concise Stereoselective Synthesis of Oxaspirocycles with 1-Tosyl-1,2,3-triazoles: Application to the Total Syntheses of (±)-Tuberostemospiroline and (±)-Stemona-lactam R

(2014) Junkai Fu et al.   CHEMISTRY-A EUROPEAN JOURNAL

One-Pot Synthesis of 2,5-Dihydropyrroles from Terminal Alkynes, Azides, and Propargylic Alcohols by Relay Actions of Copper, Rhodium, and Gold

(2014) Tomoya Miura et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Transannulation of 1,2,3-Triazoles to Polysubstituted Pyrroles

(2014) Shanmugam Rajasekar et al.   JOURNAL OF ORGANIC CHEMISTRY

From Triazoles to Imidazolines through the Sequential N–H Insertion of α-Imino Rhodium–Carbenes into β-Enamino Esters/Enamine–Imine Tautomerization/Conjugate Addition Cascade

(2014) Hyun Ji Jeon et al.   JOURNAL OF ORGANIC CHEMISTRY

Intramolecular Dearomatizing [3 + 2] Annulation of α-Imino Carbenoids with Aryl Rings Furnishing 3,4-Fused Indole Skeletons

(2014) Tomoya Miura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multicomponent [5 + 2] Cycloaddition Reaction for the Synthesis of 1,4-Diazepines: Isolation and Reactivity of Azomethine Ylides

(2014) Dong Jin Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of trans-Cycloalkenes via Enantioselective Cyclopropanation and Skeletal Rearrangement

(2014) Tomoya Miura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of N-Acylamidines via Rhodium-Catalyzed Reaction of Nitrosobenzene Derivatives with N-Sulfonyl-1,2,3-triazoles

(2014) Rui-Qiao Ran et al.   ORGANIC LETTERS

Diastereoselective N-Sulfonylaminoalkenylation of Azulenes from Terminal Alkynes and Azides via N-Sulfonyl-1,2,3-triazoles

(2014) Sangjune Park et al.   ORGANIC LETTERS

Direct Production of Enaminones from Terminal Alkynes via Rhodium-Catalyzed Reaction of Formamides with N-Sulfonyl-1,2,3-triazoles

(2014) Tomoya Miura et al.   ORGANIC LETTERS

Rhodium Catalyzed Direct Arylation of α-Diazoimines

(2014) Dongari Yadagiri et al.   ORGANIC LETTERS

One-Step Synthesis of Nitrogen-Containing Medium-Sized Rings via α-Imino Diazo Intermediates

(2014) Florian Medina et al.   ORGANIC LETTERS

Synthesis of Substituted 3-Indolylimines and Indole-3-carboxaldehydes by Rhodium(II)-Catalyzed Annulation

(2014) Basker Rajagopal et al.   ORGANIC LETTERS

Rhodium-Catalyzed Transannulation of N-Sulfonyl-1,2,3-triazoles and Epoxides: Regioselective Synthesis of Substituted 3,4-Dihydro-2H-1,4-oxazines

(2014) Xueji Ma et al.   ORGANIC LETTERS

Rhodium(II)-Catalyzed Stereocontrolled Synthesis of Dihydrofuran-3-imines from 1-Tosyl-1,2,3-triazoles

(2014) Alistair Boyer   ORGANIC LETTERS

Tunable and Chemoselective Syntheses of Dihydroisobenzofurans and Indanones via Rhodium-Catalyzed Tandem Reactions of 2-Triazole-benzaldehydes and 2-Triazole-alkylaryl Ketones

(2014) Hongjuan Shen et al.   ORGANIC LETTERS

One-Pot Protocol to Functionalized Benzopyrrolizidine Catalyzed Successively by Rh2(OAc)4 and Cu(OTf)2: A Transition Metal–Lewis Acid Catalysis Relay

(2014) Hua-Dong Xu et al.   ORGANIC LETTERS

Synthesis of 3-Pyrrolin-2-ones by Rhodium-Catalyzed Transannulation of 1-Sulfonyl-1,2,3-triazole with Ketene Silyl Acetal

(2014) Rui-Qiao Ran et al.   ORGANIC LETTERS

DMF as a Source of Oxygen and Aminomethine: Stereoselective 1,2-Insertion of Rhodium(II) Azavinyl Carbenes into the C═O Bond of Formamides for the Synthesis of cis-Diamino Enones

(2014) Da Jung Jung et al.   ORGANIC LETTERS

Synthesis of Pyrroles from Terminal Alkynes, N-Sulfonyl Azides, and Alkenyl Alkyl Ethers through 1-Sulfonyl-1,2,3-triazoles

(2014) Cheol-Eui Kim et al.   ORGANIC LETTERS

Recent Advances in Transition-Metal-Catalyzed Denitrogenative Transformations­ of 1,2,3-Triazoles and Related Compounds

(2014) Pazhamalai Anbarasan et al.   SYNTHESIS-STUTTGART

Aza-[4+3] and Aza-[3+2] Annulations for Synthesis of Dihydroazepines and Dihydropyrroles from Alkynes, Sulfonyl Azides, and 1,3-Dienes

(2014) Sanghyuck Kim et al.   Asian Journal of Organic Chemistry

Novel Multicomponent Reactions via Trapping of Protic Onium Ylides with Electrophiles

(2013) Xin Guo et al.   ACCOUNTS OF CHEMICAL RESEARCH

Rhodium-Catalyzed Tandem Cyclopropanation/Cope Rearrangement of 4-Alkenyl-1-sulfonyl-1,2,3-triazoles with Dienes

(2013) Brendan T. Parr et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-Pot Procedure for the Introduction of Three Different Bonds onto Terminal Alkynes throughN-Sulfonyl-1,2,3-Triazole Intermediates

(2013) Tomoya Miura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Versatile Reactivity of Rhodium-Iminocarbenes Derived fromN-Sulfonyl Triazoles

(2013) Anton V. Gulevich et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Doyle–Kirmse Reaction Using Triazoles Leading to One-pot Multifunctionalization of Terminal Alkynes

(2013) Tomoya Miura et al.   CHEMISTRY LETTERS

Catalytic Asymmetric Synthesis of Pyrroloindolines via a Rhodium(II)-Catalyzed Annulation of Indoles

(2013) Jillian E. Spangler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Synthesis of 2,3-Dihydropyrroles from Terminal Alkynes, Azides, and α,β-Unsaturated Aldehydes via N-Sulfonyl-1,2,3-triazoles

(2013) Tomoya Miura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transannulation of 1-Sulfonyl-1,2,3-triazoles with Heterocumulenes

(2013) Stepan Chuprakov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Application of In Situ-Generated Rh-Bound Trimethylenemethane Variants to the Synthesis of 3,4-Fused Pyrroles

(2013) Erica E. Schultz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conversion of Cyclic Ketones to 2,3-Fused Pyrroles and Substituted Indoles

(2013) Joshua S. Alford et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective 1,3-Insertions of Rhodium(II) Azavinyl Carbenes

(2013) Stepan Chuprakov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Conversion of Furans to Highly Functionalized Pyrroles

(2013) Brendan T. Parr et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Transannulation of Alkynyl Triazoles via Alkyne–Carbene Metathesis Step: Access to Fused Pyrroles

(2013) Yi Shi et al.   ORGANIC LETTERS

Catalytic Cascade Reactions Involving Metal Carbene Migratory Insertion

(2013) Ying Xia et al.   ACS Catalysis

Diazo Compounds and N-Tosylhydrazones: Novel Cross-Coupling Partners in Transition-Metal-Catalyzed Reactions

(2012) Qing Xiao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Ring Expansion and Rearrangements of Rhodium(II) Azavinyl Carbenes

(2012) Nicklas Selander et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sulfonyl-1,2,3-Triazoles: Convenient Synthones for Heterocyclic Compounds

(2012) Mikhail Zibinsky et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Arylation of Rhodium(II) Azavinyl Carbenes with Boronic Acids

(2012) Nicklas Selander et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Enaminones by Rhodium-Catalyzed Denitrogenative Rearrangement of 1-(N-Sulfonyl-1,2,3-triazol-4-yl)alkanols

(2012) Tomoya Miura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Expanding the Scope of Donor/Acceptor Carbenes to N-Phthalimido Donor Groups: Diastereoselective Synthesis of 1-Cyclopropane α-Amino Acids

(2012) Joshua S. Alford et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Denitrogenative Transannulation: Converting Triazoles into Other Heterocyclic Systems

(2011) Buddhadeb Chattopadhyay et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tosylhydrazones: New Uses for Classic Reagents in Palladium-Catalyzed Cross-Coupling and Metal-Free Reactions

(2011) José Barluenga et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Tosylhydrazones: versatile reagents for metal-catalyzed and metal-free cross-coupling reactions

(2011) Zhihui Shao et al.   CHEMICAL SOCIETY REVIEWS

Catalytic Asymmetric C–H Insertions of Rhodium(II) Azavinyl Carbenes

(2011) Stepan Chuprakov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of α-Amino Ketones from Terminal Alkynes via Rhodium-Catalyzed Denitrogenative Hydration of N-Sulfonyl-1,2,3-triazoles

(2011) Tomoya Miura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-Catalyzed Transannulation ofN-Tosyl-1,2,3-Triazoles with Terminal Alkynes

(2011) Buddhadeb Chattopadhyay et al.   ORGANIC LETTERS

Synthesis and Reactivity of Sulfamoyl Azides and 1-Sulfamoyl-1,2,3-triazoles

(2011) Jeffrey C. Culhane et al.   ORGANIC LETTERS

An Efficient Approach to Fused Indolines via a Copper(I)-Catalyzed Reaction of Sulfonyl Azide with 2-Ethynylaryl Methylenecyclopropane

(2011) Shaoyu Li et al.   ORGANIC LETTERS

Highly controlling selectivity of copper(I)-catalyzed azide/alkyne cycloaddition (CuAAC) between sulfonyl azids and normal alkynes or propynoates

(2011) Yantao Liu et al.   TETRAHEDRON

Synthesis and Reactivity of Rhodium(II)N-Triflyl Azavinyl Carbenes

(2010) Neil Grimster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Synthesis of 1-Sulfonyl-1,2,3-triazoles

(2010) Jessica Raushel et al.   ORGANIC LETTERS

Nickel-catalysed denitrogenative alkyne insertion reactions of N-sulfonyl-1,2,3-triazoles

(2009) Tomoya Miura et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed Enantioselective Cyclopropanation of Olefins withN-Sulfonyl 1,2,3-Triazoles

(2009) Stepan Chuprakov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-Catalyzed Cycloisomerizations of Enynes: A Mechanistic Perspective

(2008) Eloísa Jiménez-Núñez et al.   CHEMICAL REVIEWS

Rhodium-Catalyzed Transannulation of 1,2,3-Triazoles with Nitriles

(2008) Tony Horneff et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY