Rhenium‐Catalyzed Decarboxylative Tri‐/Difluoromethylation of Styrenes with Fluorinated Carboxylic Acid‐Derived Hypervalent Iodine Reagents

Rhenium-Catalyzed Phthalide Synthesis from Benzamides and Aldehydes via C–H Bond Activation

(2019) Bing Jia et al.   ORGANIC LETTERS

Recent advances of rhenium separation and enrichment in China: Industrial processes and laboratory trials

(2018) Yin Wang et al.   CHINESE CHEMICAL LETTERS

Visible-Light Photoredox Decarboxylation of Perfluoroarene Iodine(III) Trifluoroacetates for C–H Trifluoromethylation of (Hetero)arenes

(2018) Bin Yang et al.   ACS Catalysis

Metal-free alkene oxy- and amino-perfluoroalkylations via carbocation formation by using perfluoro acid anhydrides: unique reactivity between styrenes and perfluoro diacyl peroxides

(2018) Elena Valverde et al.   Chemical Science

Direct Photoassisted α-Trifluoromethylation of Aromatic Ketones with Trifluoroacetic Anhydride (TFAA)

(2018) Somnath Das et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhenium-Catalyzed Annulation Reactions

(2017) Guoliang Mao et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Iron-Catalyzed Acyloxyalkylation of Styrenes Using Hypervalent Iodine Reagents

(2017) Zijia Wang et al.   ORGANIC LETTERS

The Direct C–H Difluoromethylation of Heteroarenes Based on the Photolysis of Hypervalent Iodine(III) Reagents That Contain Difluoroacetoxy Ligands

(2017) Ryu Sakamoto et al.   ORGANIC LETTERS

Decarboxylative Trifluoromethylating Reagent [Cu(O2 CCF3 )(phen)] and Difluorocarbene Precursor [Cu(phen)2 ][O2 CCF2 Cl]

(2016) Xiaoxi Lin  et al.   CHEMISTRY-A EUROPEAN JOURNAL

A class of effective decarboxylative perfluoroalkylating reagents: [(phen)2Cu](O2CRF)

(2016) Yangjie Huang et al.   DALTON TRANSACTIONS

Decarboxylative Perfluoroalkylation of Vinyl Bromides with Copper(I) Perfluorocarboxylato Complexes

(2016) Chuyi Wu et al.   Asian Journal of Organic Chemistry

Rhenium and base co-catalyzed [3 + 2] annulations of N–H ketimines and alkynes to access unprotected tertiary indenamines through C–H bond activation

(2016) Xiqing Jin et al.   Organic Chemistry Frontiers

Recent Progress in Re-Catalyzed Dehydroxylation Reactions

(2015) Guoliang Mao et al.   CHINESE JOURNAL OF ORGANIC CHEMISTRY

Rhenium-catalyzed C–H aminocarbonylation of azobenzenes with isocyanates

(2015) Xiaoyu Geng et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhenium-catalyzed dehydrogenative olefination of C(sp3)–H bonds with hypervalent iodine(iii) reagents

(2015) Haidong Gu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhenium-Catalyzed [4 + 1] Annulation of Azobenzenes and Aldehydes via Isolable Cyclic Rhenium(I) Complexes

(2015) Xiaoyu Geng et al.   ORGANIC LETTERS

Photoredox-Catalyzed Intramolecular Aminodifluoromethylation of Unactivated Alkenes

(2015) Zuxiao Zhang et al.   ORGANIC LETTERS

A scalable and operationally simple radical trifluoromethylation

(2015) Joel W. Beatty et al.   Nature Communications

Oxidative Trifluoromethylation and Trifluoromethylthiolation Reactions Using (Trifluoromethyl)trimethylsilane as a Nucleophilic CF3 Source

(2014) Lingling Chu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Electrophilic Trifluoromethylation by Use of Hypervalent Iodine Reagents

(2014) Julie Charpentier et al.   CHEMICAL REVIEWS

Amide Groups Switch Selectivity: C–H Trifluoromethylation of α,β-Unsaturated Amides and Subsequent Asymmetric Transformation

(2014) Lei Li et al.   ORGANIC LETTERS

2-Trifluoromethylated Indoles via Radical Trifluoromethylation of Isonitriles

(2014) Bo Zhang et al.   ORGANIC LETTERS

Diastereoselective Aminooxygenation and Diamination of Alkenes with Amidines by Hypervalent Iodine(III) Reagents

(2014) Hui Chen et al.   ORGANIC LETTERS

Silver-Catalyzed C–H Trifluoromethylation of Arenes Using Trifluoroacetic Acid as the Trifluoromethylating Reagent

(2014) Guangfa Shi et al.   ORGANIC LETTERS

Catalytic Cycle for Palladium-Catalyzed Decarbonylative Trifluoromethylation using Trifluoroacetic Esters as the CF3 Source

(2014) Ansis Maleckis et al.   ORGANOMETALLICS

Rapid and Efficient Trifluoromethylation of Aromatic and Heteroaromatic Compounds Using Potassium Trifluoroacetate Enabled by a Flow System

(2013) Mao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Functionalization of Radical Intermediates in Redox Catalysis: Copper-Catalyzed Asymmetric Oxytrifluoromethylation of Alkenes

(2013) Rong Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A room temperature decarboxylation/C–H functionalization cascade by visible-light photoredox catalysis

(2013) Jin Xie et al.   CHEMICAL COMMUNICATIONS

Transition-metal-free oxidative trifluoromethylation of unsymmetrical biaryls with trifluoromethanesulfinate

(2013) Yu-Dong Yang et al.   CHEMICAL COMMUNICATIONS

Regio- and Diastereoselective Cu-Mediated Trifluoromethylation of Functionalized Alkenes

(2013) Tatiana Besset et al.   JOURNAL OF ORGANIC CHEMISTRY

Re/Mg Bimetallic Tandem Catalysis for [4+2] Annulation of Benzamides and Alkynes via C-H/N-H Functionalization

(2013) Qiuzheng Tang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alkene Oxyalkylation Enabled by Merging Rhenium Catalysis with Hypervalent Iodine(III) Reagents via Decarboxylation

(2013) Yin Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Vicinal Difunctionalization of Internal Alkenes: Diastereoselective Synthesis of Diamines

(2012) Claudio Martínez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tamed Arene and Heteroarene Trifluoromethylation

(2012) Tatiana Besset et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Three-component Oxytrifluoromethylation of Alkenes: Highly Efficient and Regioselective Difunctionalization of CC Bonds Mediated by Photoredox Catalysts

(2012) Yusuke Yasu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A “Renaissance” in Radical Trifluoromethylation

(2012) Armido Studer   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Free Trifluoromethylaminoxylation of Alkenes

(2012) Yi Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic, Asymmetric Halofunctionalization of Alkenes-A Critical Perspective

(2012) Scott E. Denmark et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intimate Interactions with Carbonyl Groups: Dipole–Dipole or n→π*?

(2012) Kimberli J. Kamer et al.   JOURNAL OF ORGANIC CHEMISTRY

Electrophilic Trifluoromethylation by Copper-Catalyzed Addition of CF3-Transfer Reagents to Alkenes and Alkynes

(2012) Pär G. Janson et al.   ORGANIC LETTERS

Oxytrifluoromethylation of multiple bonds using copper catalyst under mild conditions

(2012) Hiromichi Egami et al.   TETRAHEDRON LETTERS

Towards a Practical and Efficient Copper-Catalyzed Trifluoromethylation of Aryl Halides

(2012) Thomas Schareina et al.   TOPICS IN CATALYSIS

Palladium-Catalyzed Tunable Functionalization of Allylic Imidates: Regioselective Aminodiacetoxylation and Aziridination

(2011) Sunliang Cui et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Metal-Free Diamination of Styrenes

(2011) Caren Röben et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aromatic Trifluoromethylation with Metal Complexes

(2011) Olesya A. Tomashenko et al.   CHEMICAL REVIEWS

Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications

(2011) Richard I. McDonald et al.   CHEMICAL REVIEWS

Catalysis for fluorination and trifluoromethylation

(2011) Takeru Furuya et al.   NATURE

Rhenium-Catalyzed Regiodivergent Addition of Indoles to Terminal Alkynes

(2011) Dexin Xia et al.   ORGANIC LETTERS

Organic Reactions Catalyzed by Rhenium Carbonyl Complexes

(2010) Yoichiro Kuninobu et al.   CHEMICAL REVIEWS

Decarboxylative trifluoromethylation of aryl halides using well-defined copper–trifluoroacetate and –chlorodifluoroacetate precursors

(2010) Kristen A. McReynolds et al.   JOURNAL OF FLUORINE CHEMISTRY

Metal-Free Highly Regioselective Aminotrifluoroacetoxylation of Alkenes

(2010) Helena M. Lovick et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Diacetoxylation of Olefins using PhI(OAc)2as Oxidant

(2010) Jayasree Seayad et al.   ORGANIC LETTERS

Diaryliodonium Salts: A Journey from Obscurity to Fame

(2009) Eleanor���A. Merritt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A new paradigm for protein design and biological self-assembly

(2009) Gizem Akçay et al.   JOURNAL OF FLUORINE CHEMISTRY

Effect of Highly Fluorinated Amino Acids on Protein Stability at a Solvent-Exposed Position on an Internal Strand of Protein G B1 Domain

(2009) Hsien-Po Chiu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Intramolecular Aminofluorination of Unactivated Alkenes

(2009) Tao Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Oxamidation of UnsaturatedO-Alkyl Hydroxamates: A Remarkably Versatile Entry to Hydroxy Lactams

(2009) Duncan J. Wardrop et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemistry of Polyvalent Iodine

(2008) Viktor V. Zhdankin et al.   CHEMICAL REVIEWS

Influence of Selective Fluorination on the Biological Activity and Proteolytic Stability of Glucagon-like Peptide-1

(2008) He Meng et al.   JOURNAL OF MEDICINAL CHEMISTRY

The Many Roles for Fluorine in Medicinal Chemistry

(2008) William K. Hagmann   JOURNAL OF MEDICINAL CHEMISTRY

Palladium-Catalyzed Olefin Dioxygenation

(2008) Yang Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the regioselectivity of the PIFA-mediated bis(trifluoroacetoxylation) of styrene-type compounds

(2008) Imanol Tellitu et al.   TETRAHEDRON

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS