Isolation of a Diylide-Stabilized Stannylene and Germylene: Enhanced Donor Strength through Coplanar Lone Pair Alignment

Ylide-Functionalized Phosphines: Strong Donor Ligands for Homogenous Catalysis

(2018) Thorsten Scherpf et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hafnocene-based Bicyclo[2.1.1]hexene Germylenes – Formation, Reactivity, and Structural Flexibility

(2018) Zhaowen Dong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactive Dimerization of an N-Heterocyclic Plumbylene: C−H Activation with PbII

(2018) Robin Guthardt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Highly Active Ylide-Functionalized Phosphine for Palladium-Catalyzed Aminations of Aryl Chlorides

(2018) Philip Weber et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metalated Ylides: A New Class of Strong Donor Ligands with Unique Electronic Properties

(2017) Lennart T. Scharf et al.   INORGANIC CHEMISTRY

Using N-Heterocyclic Vinyl Ligands to Access Stable Divinylgermylenes and a Germylium Cation

(2016) Christian Hering-Junghans et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isolation and Structure of Germylene-Germyliumylidenes Stabilized by N-Heterocyclic Imines

(2016) Tatsumi Ochiai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Stable Heterocyclic Amino(phosphanylidene-σ4 -phosphorane) Germylene

(2016) Natalia Del Rio et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From a Phosphaketenyl-Functionalized Germylene to 1,3-Digerma-2,4-diphosphacyclobutadiene

(2016) Shenglai Yao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Bis(pentafluoroethyl)germylene Trimethylphosphane Adduct (C2 F5 )2 Ge⋅PMe3 : Characterization, Ligand Properties, and Reactivity

(2016) Stefanie Pelzer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diverse Activation Modes in the Hydroboration of Aldehydes and Ketones with Germanium, Tin, and Lead Lewis Pairs

(2016) Julia Schneider et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cyclic Amino(Ylide) Silylene: A Stable Heterocyclic Silylene with Strongly Electron-Donating Character

(2016) Isabel Alvarado-Beltran et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N,P-Heterocyclic Germylene/B(C6 F5 )3 Adducts: A Lewis Pair with Multi-reactive Sites

(2016) Natalia Del Rio et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Germylene Stabilized by Homoconjugation

(2016) Zhaowen Dong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Systematic Study of Structure and E−H Bond Activation Chemistry by Sterically Encumbered Germylene Complexes

(2016) Matthew Usher et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Redox-Switchable Germylene and its Ligating Properties in Selected Transition Metal Complexes

(2016) Florian Walz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Redox-Active N-Heterocyclic Germylenes and Stannylenes with a Ferrocene-1,1′-diyl Backbone

(2016) Jan Oetzel et al.   CHEMISTRY-A EUROPEAN JOURNAL

Tin(IV) Chalcogenide Complexes: Single Source Precursors for SnS, SnSe and SnTe Nanoparticle Synthesis

(2016) Joseph R. Thompson et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Regiodiscriminating Reactivity of Isolable NHC-Coordinated Disilenyl Germylene and Its Cyclic Isomer

(2016) David Nieder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bridging the Gap between Bisylides and Methandiides: Isolation, Reactivity, and Electronic Structure of an Yldiide

(2015) Thorsten Scherpf et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Moving toward Ylide-Stabilized Carbenes

(2015) Bitupon Borthakur et al.   CHEMISTRY-A EUROPEAN JOURNAL

Insertion of a Cationic Metallogermylene into E–H Bonds (E = H, B, Si)

(2015) Koya Inomata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Two-coordinate group 14 element(ii) hydrides as reagents for the facile, and sometimes reversible, hydrogermylation/hydrostannylation of unactivated alkenes and alkynes

(2015) Terrance J. Hadlington et al.   Chemical Science

A Bis-Sulfonyl O,C,O Aryl Pincer Ligand and its Tin(II) Complex: Synthesis, Structural Studies, and DFT Calculations

(2014) Mohammad El Ezzi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stabilization of a Diphosphagermylene through pπ-pπ Interactions with a Trigonal-Planar Phosphorus Center

(2014) Keith Izod et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Azavinylidenephosphoranes: A Class of Cyclic Push-Pull Carbenes

(2014) Florie Lavigne et al.   CHEMISTRY-A EUROPEAN JOURNAL

NHC-Stabilized Silagermenylidene: A Heavier Analogue of Vinylidene

(2013) Anukul Jana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Relationship between Gallium Pyramidalization in L·GaCl3Complexes and the Electronic Ligand Properties

(2013) Ahmad El-Hellani et al.   INORGANIC CHEMISTRY

An Acyclic Imino-Substituted Silylene: Synthesis, Isolation, and its Facile Conversion into a Zwitterionic Silaimine

(2012) Shigeyoshi Inoue et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Stable Two-Coordinate Acyclic Silylene

(2012) Andrey V. Protchenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A stable germanone as the first isolated heavy ketone with a terminal oxygen atom

(2012) Liangchun Li et al.   Nature Chemistry

Aromatic Ylide-Stabilized Carbocyclic Silylene

(2011) Matthew Asay et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Reactivity of a Phosphine-Stabilized Monogermanium Analogue of Alkynes

(2011) Juliette Berthe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Neutral, Monomeric Germanium(I) Radical

(2011) William D. Woodul et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules

(2011) Shenglai Yao et al.   ORGANOMETALLICS

N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands†

(2010) Matthew Asay et al.   CHEMICAL REVIEWS

Reactions of germenes with various naphthoquinones controlled by substituent effects

(2010) Dumitru Ghereg et al.   DALTON TRANSACTIONS

Synthesis and Structural Characterization of a Series of Dimeric Metal(II) Imido Complexes {M(μ-NAr#)}2[M = Ge, Sn, Pb; Ar#= C6H3-2,6-(C6H2-2,4,6-Me3)2] and the Related Monomeric Primary Amido Derivatives M{N(H)Ar#}2(M = Ge, Sn, Pb): Spectroscopic Manifestations of Secondary Metal−Ligand Interactions

(2010) William A. Merrill et al.   INORGANIC CHEMISTRY

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

Stable Heavier Carbene Analogues

(2009) Yoshiyuki Mizuhata et al.   CHEMICAL REVIEWS

Group 4 Metallocene Complexes of Disilenes, Digermenes, and a Silagermene

(2009) Michaela Zirngast et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction of Hydrogen or Ammonia with Unsaturated Germanium or Tin Molecules under Ambient Conditions: Oxidative Addition versus Arene Elimination

(2009) Yang Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Ligand Properties of a Stable Five-Membered-Ring Vinylidenephosphorane

(2008) Matthew Asay et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbenes Stabilized by Ylides: Pushing the Limits

(2008) Alois Fürstner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Generation and Coordinating Properties of a Carbene Bearing a Phosphorus Ylide: An Intensely Electron-Donating Ligand

(2008) Shin-ya Nakafuji et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Structural Characterization of Tin Analogues ofN-Heterocyclic Carbenes

(2008) Stephen M. Mansell et al.   INORGANIC CHEMISTRY

Synthesis and Structure of N-Heterocyclic Carbene Complexes of Germanium(II)

(2008) Paul A. Rupar et al.   ORGANOMETALLICS