Using N-Heterocyclic Vinyl Ligands to Access Stable Divinylgermylenes and a Germylium Cation

Isolation and Structure of Germylene-Germyliumylidenes Stabilized by N-Heterocyclic Imines

(2016) Tatsumi Ochiai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Group 14 inorganic hydrocarbon analogues

(2016) Eric Rivard   CHEMICAL SOCIETY REVIEWS

Applications of N-heterocyclic imines in main group chemistry

(2016) Tatsumi Ochiai et al.   CHEMICAL SOCIETY REVIEWS

Extremely bulky amide ligands in main group chemistry

(2016) Deborah L. Kays   CHEMICAL SOCIETY REVIEWS

Reactivity in the periphery of functionalised multiple bonds of heavier group 14 elements

(2016) Carsten Präsang et al.   CHEMICAL SOCIETY REVIEWS

A Systematic Study of Structure and E−H Bond Activation Chemistry by Sterically Encumbered Germylene Complexes

(2016) Matthew Usher et al.   CHEMISTRY-A EUROPEAN JOURNAL

N-Heterocyclic olefins as ancillary ligands in catalysis: a study of their behaviour in transfer hydrogenation reactions

(2016) Amaia Iturmendi et al.   DALTON TRANSACTIONS

Structurally versatile phosphine and amine donors constructed from N-heterocyclic olefin units

(2016) Nathan R. Paisley et al.   DALTON TRANSACTIONS

From the parent phosphinidene–carbene adduct NHCPH to cationic P4-rings and P2-cycloaddition products

(2016) Andreas Beil et al.   DALTON TRANSACTIONS

A stable heavier group 14 analogue of vinylidene

(2016) Arnab Rit et al.   Nature Chemistry

Improved synthesis of N -heterocyclic olefins and evaluation of their donor strengths

(2016) Kate Powers et al.   POLYHEDRON

N-Heterocyclic Olefins as Organocatalysts for Polymerization: Preparation of Well-Defined Poly(propylene oxide)

(2015) Stefan Naumann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of vinyl germylenes

(2015) Małgorzata Walewska et al.   CHEMICAL COMMUNICATIONS

An NHC-Stabilized Silicon Analogue of Acylium Ion: Synthesis, Structure, Reactivity, and Theoretical Studies

(2015) Syed Usman Ahmad et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise

(2014) Michèle Soleilhavoup et al.   ACCOUNTS OF CHEMICAL RESEARCH

Accessing Zinc Monohydride Cations through Coordinative Interactions

(2014) Paul A. Lummis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Facile Route to Backbone-Tethered N-Heterocyclic Carbene (NHC) Ligands via NHC to aNHC Rearrangement in NHC Silicon Halide Adducts

(2014) Heidi Schneider et al.   CHEMISTRY-A EUROPEAN JOURNAL

Low Coordinate Germanium(II) and Tin(II) Hydride Complexes: Efficient Catalysts for the Hydroboration of Carbonyl Compounds

(2014) Terrance J. Hadlington et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An overview of N-heterocyclic carbenes

(2014) Matthew N. Hopkinson et al.   NATURE

Controlled Growth of Dichlorogermanium Oligomers from Lewis Basic Hosts

(2013) S. M. Ibrahim Al-Rafia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Facile access to silyl-functionalized N-heterocyclic olefins with HSiCl3

(2013) Rajendra S. Ghadwal et al.   CHEMICAL COMMUNICATIONS

Mono(imidazolin-2-iminato) Titanium Complexes for Ethylene Polymerization at Low Amounts of Methylaluminoxane

(2013) Dana Shoken et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Cyclic Germadicarbene (“Germylone”) from Germyliumylidene

(2013) Yun Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Silylium and Germylium Ions by a Substituent Exchange Reaction

(2013) André Schäfer et al.   ORGANOMETALLICS

Stable Complexes of Parent Digermene: An Inorganic Analogue of Ethylene

(2013) S. M. Ibrahim Al-Rafia et al.   ORGANOMETALLICS

N-Heterocyclic Olefin Stabilized Borenium Cations

(2013) Yuzhong Wang et al.   ORGANOMETALLICS

A Stable Two-Coordinate Acyclic Silylene

(2012) Andrey V. Protchenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Crystalline Singlet Phosphinonitrene: A Nitrogen Atom-Transfer Agent

(2012) F. Dielmann et al.   SCIENCE

Intercepting low oxidation state main group hydrides with a nucleophilic N-heterocyclic olefin

(2011) S. M. Ibrahim Al-Rafia et al.   CHEMICAL COMMUNICATIONS

Interaction of Carbene and Olefin Donors with [Cl2PN]3: Exploration of a Reductive Pathway toward (PN)3

(2011) S. M. Ibrahim Al-Rafia et al.   INORGANIC CHEMISTRY

π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium

(2010) Roland C. Fischer et al.   CHEMICAL REVIEWS

N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands†

(2010) Matthew Asay et al.   CHEMICAL REVIEWS

Synthesis and Structural Characterization of a Series of Dimeric Metal(II) Imido Complexes {M(μ-NAr#)}2[M = Ge, Sn, Pb; Ar#= C6H3-2,6-(C6H2-2,4,6-Me3)2] and the Related Monomeric Primary Amido Derivatives M{N(H)Ar#}2(M = Ge, Sn, Pb): Spectroscopic Manifestations of Secondary Metal−Ligand Interactions

(2010) William A. Merrill et al.   INORGANIC CHEMISTRY

Synthesis of 4- and 4,5-Functionalized Imidazol-2-ylidenes from a Single 4,5-Unsubstituted Imidazol-2-ylidene

(2010) Daniel Mendoza-Espinosa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

Abnormal Reactivity of an N-Heterocyclic Carbene (NHC) with a Phosphaalkene: A Route to a 4-Phosphino-Substituted NHC

(2009) Joshua I. Bates et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stable Heavier Carbene Analogues

(2009) Yoshiyuki Mizuhata et al.   CHEMICAL REVIEWS

A Highly Delocalized Triplet Carbene, 5-Methylhexa-1,2,4-triene-1,3-diyl: Matrix IR Identification, Structure, and Reactions

(2009) Sergey E. Boganov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[(OtBu)2C6H3]3Ge+a free germyl cation with aryl ligands

(2008) Christian Schenk et al.   DALTON TRANSACTIONS

A Stable Silicon(0) Compound with a Si=Si Double Bond

(2008) Y. Wang et al.   SCIENCE