NHC-Stabilized Silagermenylidene: A Heavier Analogue of Vinylidene

Chemical Tricks To Stabilize Silanones and Their Heavier Homologues with EO Bonds (E=Si-Pb): From Elusive Species to Isolable Building Blocks

(2013) Yun Xiong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Cyclic Silylone (“Siladicarbene”) with an Electron-Rich Silicon(0) Atom

(2013) Yun Xiong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Stable Singlet Biradicaloid Siladicarbene: (L:)2Si

(2013) Kartik Chandra Mondal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Structural Characterization of Base-Stabilized Oligomeric Heterovinylidenes

(2013) Wing-Por Leung et al.   INORGANIC CHEMISTRY

Acyclic Germylones: Congeners of Allenes with a Central Germanium Atom

(2013) Yan Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Cyclic Germadicarbene (“Germylone”) from Germyliumylidene

(2013) Yun Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ambient-Temperature Isolation of a Compound with a Boron-Boron Triple Bond

(2012) H. Braunschweig et al.   SCIENCE

Addition of a cyclopropyl alkyne to tetramesityldigermene: evidence for a biradical intermediate

(2011) Krysten L. Hurni et al.   CHEMICAL COMMUNICATIONS

Carbene Stabilization of Highly Reactive Main-Group Molecules

(2011) Yuzhong Wang et al.   INORGANIC CHEMISTRY

Structures and energetics of SiGeHz0,+1, Ge2Hz0,+1, and Si2Hz0,+1: A systematic theoretical study

(2011) Liming Wang et al.   INTERNATIONAL JOURNAL OF MASS SPECTROMETRY

Reactivity of a Germene toward Terminal Alkynes: Competition between Cycloaddition, Ene-Addition, and CH-Insertion

(2011) Laura C. Pavelka et al.   ORGANOMETALLICS

Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules

(2011) Shenglai Yao et al.   ORGANOMETALLICS

Synthesis and characterization of a tin(ii) bis(phosphinoyl)methanediide complex: a stannavinylidene derivative

(2010) Jiayi Guo et al.   CHEMICAL COMMUNICATIONS

Ruthenium-Based Olefin Metathesis Catalysts Derived from Alkynes

(2010) Ana M. Lozano-Vila et al.   CHEMICAL REVIEWS

π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium

(2010) Roland C. Fischer et al.   CHEMICAL REVIEWS

N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands†

(2010) Matthew Asay et al.   CHEMICAL REVIEWS

N-Heterocyclic Carbene Stabilized Digermanium(0)

(2009) Anastas Sidiropoulos et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dichotomic Reactivity of a Stable Silylene toward Terminal Alkynes: Facile CH Bond Insertion versus Autocatalytic Formation of Silacycloprop-3-ene

(2008) Shenglai Yao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Reactions of a Stable 1,2-Diaryl-1,2-dibromodisilene: A Precursor for Substituted Disilenes and a 1,2-Diaryldisilyne

(2008) Takahiro Sasamori et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Stable Silicon(0) Compound with a Si=Si Double Bond

(2008) Y. Wang et al.   SCIENCE