N,P-Heterocyclic Germylene/B(C6 F5 )3 Adducts: A Lewis Pair with Multi-reactive Sites

A Stable Heterocyclic Amino(phosphanylidene-σ4 -phosphorane) Germylene

(2016) Natalia Del Rio et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective reduction of carbon dioxide to bis(silyl)acetal catalyzed by a PBP-supported nickel complex

(2016) Pablo Ríos et al.   CHEMICAL COMMUNICATIONS

A Systematic Study of Structure and E−H Bond Activation Chemistry by Sterically Encumbered Germylene Complexes

(2016) Matthew Usher et al.   CHEMISTRY-A EUROPEAN JOURNAL

Selective Reduction of CO2 to CH4 by Tandem Hydrosilylation with Mixed Al/B Catalysts

(2016) Jiawei Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrophosphination of CO2and Subsequent Formate Transfer in the 1,3,2-Diazaphospholene-CatalyzedN-Formylation of Amines

(2015) Che Chang Chong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Exploiting Electrostatics To Generate Unsaturation: Oxidative GeE Bond Formation Using a Non π-Donor Stabilized [R(L)Ge:]+ Cation

(2015) Arnab Rit et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frustrated Lewis Pair Chemistry: Development and Perspectives

(2015) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis, Structures and Thermal Decomposition of Monomeric Aluminium, Gallium and Indium Silylphosphanides

(2015) Manuel Kapitein et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Aromaticity as Stabilizing Element in the Bidentate Activation for the Catalytic Reduction of Carbon Dioxide

(2015) Zhenpin Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Insertion of a Cationic Metallogermylene into E–H Bonds (E = H, B, Si)

(2015) Koya Inomata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Reduction of CO2 into Methylene: Formation of C–N, C–O, and C–C Bonds

(2015) Guanghua Jin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Hydroboration of Carbonyl Derivatives, Imines, and Carbon Dioxide

(2015) Che Chang Chong et al.   ACS Catalysis

Stabilization of a Diphosphagermylene through pπ-pπ Interactions with a Trigonal-Planar Phosphorus Center

(2014) Keith Izod et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Hydrogenation of Unsaturated Hydrocarbons Employing Molecular Hydrogen

(2014) Jan Paradies   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Free Catalytic Reduction of Carbon Dioxide

(2014) Frédéric-Georges Fontaine et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reducing CO2 to Methanol Using Frustrated Lewis Pairs: On the Mechanism of Phosphine–Borane-Mediated Hydroboration of CO2

(2014) Marc-André Courtemanche et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Temperature-Dependent Chemoselective Hydrosilylation of Carbon Dioxide to Formaldehyde or Methanol Oxidation State

(2014) Toni T. Metsänen et al.   ORGANOMETALLICS

Selective Hydrosilation of CO2to a Bis(silylacetal) Using an Anilido Bipyridyl-Ligated Organoscandium Catalyst

(2013) Francis A. LeBlanc et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Highly Active Phosphine–Borane Organocatalyst for the Reduction of CO2 to Methanol Using Hydroboranes

(2013) Marc-André Courtemanche et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic CO2 Activation Assisted by Rhenium Hydride/B(C6F5)3 Frustrated Lewis Pairs—Metal Hydrides Functioning as FLP Bases

(2013) Yanfeng Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Frustrated Lewis Pair Catalyzed Hydrogenations

(2013) Jan Paradies   SYNLETT

Homogeneous catalytic reduction of CO2 with hydrosilanes

(2013) Francisco J. Fernández-Alvarez et al.   Catalysis Science & Technology

Isolable Phosphanylidene Phosphorane with a Sterically Accessible Two-Coordinate Phosphorus Atom

(2012) Brian A. Surgenor et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silyl Cation Mediated Conversion of CO2into Benzoic Acid, Formic Acid, and Methanol

(2012) André Schäfer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silyl-migrations in frustrated Lewis pair chemistry: reactions of ((CH3)3Si)3P and B(C6F4H)3 with H2 and CO2

(2012) Katsuhiko Takeuchi et al.   CHEMICAL COMMUNICATIONS

Enantioselective Hydrosilylation with Chiral Frustrated Lewis Pairs

(2012) Dianjun Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Stable Two-Coordinate Acyclic Silylene

(2012) Andrey V. Protchenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

“Frustrated Lewis pair” hydrogenations

(2012) Douglas W. Stephan   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis and Structural Characterization of Metallogermylenes, Cp-Substituted Germylene, and a Germanium(II)-Borane Adduct from Pyridyl-1-azaallyl Germanium(II) Chloride

(2012) Wing-Por Leung et al.   ORGANOMETALLICS

Recent advances in catalytic hydrogenation of carbon dioxide

(2011) Wei Wang et al.   CHEMICAL SOCIETY REVIEWS

An Ylide-like Phosphasilene and Striking Formation of a 4π-Electron, Resonance-Stabilized 2,4-Disila-1,3-diphosphacyclobutadiene

(2011) Shigeyoshi Inoue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of SiH, BH, and PH Bonds at a Single Nonmetal Center

(2010) Guido D. Frey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tandem Frustrated Lewis Pair/Tris(pentafluorophenyl)borane-Catalyzed Deoxygenative Hydrosilylation of Carbon Dioxide

(2010) Andreas Berkefeld et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

Synthesis and Reactivity of Low-Valent Group 14 Element Compounds 

(2010) Brian P. Johnson et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Stable singlet carbenes as mimics for transition metal centers

(2010) David Martin et al.   Chemical Science

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactions of phosphines with electron deficient boranes

(2009) Gregory C. Welch et al.   DALTON TRANSACTIONS

Oxidative Addition of Ammonia at a Silicon(II) Center and an Unprecedented Hydrogenation Reaction of Compounds with Low-Valent Group 14 Elements Using Ammonia Borane

(2009) Anukul Jana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction of Hydrogen or Ammonia with Unsaturated Germanium or Tin Molecules under Ambient Conditions: Oxidative Addition versus Arene Elimination

(2009) Yang Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A “Push−Pull” Phosphasilene and Phosphagermene and Their Anion-Radicals

(2009) Vladimir Ya. Lee et al.   ORGANOMETALLICS

Addition of H2 to distannynes under ambient conditions

(2008) Yang Peng et al.   CHEMICAL COMMUNICATIONS

Diarylstannylene Activation of Hydrogen or Ammonia with Arene Elimination

(2008) Yang Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible, Metal-Free, Heterolytic Activation of H2at Room Temperature

(2008) Matthias Ullrich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile Access to a Stable Divalent Germanium Compound with a Terminal PH2Group and Related PR2Derivatives

(2008) Shenglai Yao et al.   ORGANOMETALLICS