A Redox-Switchable Germylene and its Ligating Properties in Selected Transition Metal Complexes

A combined experimental and quantum chemical study on thallium(I) tris(pyrazolyl)methanide

(2017) Istemi Kuzu et al.   POLYHEDRON

A Boron-Fluorinated Tris(pyrazolyl)borate Ligand (F Tp*) and Its Mono- and Dinuclear Copper Complexes [Cu(F Tp*)2 ] and [Cu2 (F Tp*)2 ]: Synthesis, Structures, and DFT Calculations

(2016) Timo Augenstein et al.   CHEMISTRY-A EUROPEAN JOURNAL

Redox-Active N-Heterocyclic Germylenes and Stannylenes with a Ferrocene-1,1′-diyl Backbone

(2016) Jan Oetzel et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ferrocenyl-Imidazolylidene Ligand for Redox-Switchable Gold-Based Catalysis. A Detailed Study on the Redox-Switching Abilities of the Ligand

(2016) Susana Ibáñez et al.   ORGANOMETALLICS

Redox-Controlled Olefin (Co)Polymerization Catalyzed by Ferrocene-Bridged Phosphine-Sulfonate Palladium Complexes

(2015) Min Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterobimetallic complexes with redox-active mesoionic carbenes as metalloligands: electrochemical properties, electronic structures and catalysis

(2015) Lara Hettmanczyk et al.   CHEMICAL COMMUNICATIONS

Artificial switchable catalysts

(2015) Victor Blanco et al.   CHEMICAL SOCIETY REVIEWS

Beyond Stereoselectivity, Switchable Catalysis: Some of the Last Frontier Challenges in Ring-Opening Polymerization of Cyclic Esters

(2015) Sophie M. Guillaume et al.   CHEMISTRY-A EUROPEAN JOURNAL

Differential Many-Body Cooperativity in Electronic Spectra of Oligonuclear Transition-Metal Complexes

(2015) Jiří Chmela et al.   CHEMPHYSCHEM

The transition-metal chemistry of amidinatosilylenes, -germylenes and -stannylenes

(2015) Lucía Álvarez-Rodríguez et al.   COORDINATION CHEMISTRY REVIEWS

A Stable Planar-Chiral N-Heterocyclic Carbene with a 1,1′-Ferrocenediyl Backbone

(2015) Alex R. Petrov et al.   INORGANIC CHEMISTRY

Protic N-Heterocyclic Germylenes and Stannylenes: Synthesis and Reactivity

(2015) Sergei Krupski et al.   ORGANOMETALLICS

Time-resolved IR spectroscopy of a trinuclear palladium complex in solution

(2015) M. Zimmer et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Nitrogen fixation catalyzed by ferrocene-substituted dinitrogen-bridged dimolybdenum–dinitrogen complexes: unique behavior of ferrocene moiety as redox active site

(2015) Shogo Kuriyama et al.   Chemical Science

SHELXT– Integrated space-group and crystal-structure determination

(2015) George M. Sheldrick   Acta Crystallographica A-Foundation and Advances

PLATONSQUEEZE: a tool for the calculation of the disordered solvent contribution to the calculated structure factors

(2015) Anthony L. Spek   Acta Crystallographica Section C-Structural Chemistry

Crystal structure refinement withSHELXL

(2015) George M. Sheldrick   Acta Crystallographica Section C-Structural Chemistry

Redox Control of a Dendritic Ferrocenyl-Based Homogeneous Catalyst

(2014) Paul Neumann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tris(3,5-dimethylpyrazolyl)methane-Based Heterobimetallic Complexes that Contain Zn and CdTransition-Metal Bonds: Synthesis, Structures, and Quantum Chemical Calculations

(2014) Jens Meyer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Frequency and Zero-Point Vibrational Energy Scale Factors for Double-Hybrid Density Functionals (and Other Selected Methods): Can Anharmonic Force Fields Be Avoided?

(2014) Manoj K. Kesharwani et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Redox Control of Group 4 Metal Ring-Opening Polymerization Activity toward l-Lactide and ε-Caprolactone

(2014) Xinke Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An overview of N-heterocyclic carbenes

(2014) Matthew N. Hopkinson et al.   NATURE

Half-Wave Potential Splittings ΔE1/2 as a Measure of Electronic Coupling in Mixed-Valent Systems: Triumphs and Defeats

(2014) Rainer F. Winter   ORGANOMETALLICS

Coinage Metal Complexes of Tris(pyrazolyl)methanide-Based Redox-Active Metalloligands

(2014) Sandra González-Gallardo et al.   ORGANOMETALLICS

In-depth exploration of the photophysics of a trinuclear palladium complex

(2014) Y. Schmitt et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

A New Facile Two-Step Synthetic Procedure of 1,1′-Diaminoferrocene

(2013) Mohammad A. Abdulmalic et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Molecularly designed architectures – the metalloligand way

(2013) Girijesh Kumar et al.   CHEMICAL SOCIETY REVIEWS

Quantifying and understanding the electronic properties of N-heterocyclic carbenes

(2013) David J. Nelson et al.   CHEMICAL SOCIETY REVIEWS

Redox-Switchable Ring-Closing Metathesis: Catalyst Design, Synthesis, and Study

(2013) Kuppuswamy Arumugam et al.   CHEMISTRY-A EUROPEAN JOURNAL

Homoleptic Tetrakis(silyl) Complexes of Pd0and Pt0Featuring Metal-Centred Heterocubane Structures: Evidence for the Existence of the Corresponding Mononuclear PdIand PtIComplexes

(2013) Felix Armbruster et al.   CHEMISTRY-A EUROPEAN JOURNAL

Heterobimetallic Cuprates Consisting of a Redox-Switchable, Silicon-Based Metalloligand: Synthesis, Structures, and Electronic Properties

(2013) Steffen Styra et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and study of olefin metathesis catalysts supported by redox-switchable diaminocarbene[3]ferrocenophanes

(2013) C. Daniel Varnado et al.   DALTON TRANSACTIONS

Polymetallic complexes linked to a single-frame ligand: cooperative effects in catalysis

(2013) Ielyzaveta Bratko et al.   DALTON TRANSACTIONS

A metallacyclic alkyl-amido carbene complex (MCAAC)

(2013) Ina Trapp et al.   DALTON TRANSACTIONS

Unsymmetrical N-heterocyclic carbenes with a 1,1′-ferrocenediyl backbone

(2013) Stefan Rittinghaus et al.   DALTON TRANSACTIONS

Benzannulated N-heterocyclic germylenes and stannylenes with sterically demanding N,N′-substituents

(2013) Sergei Krupski et al.   DALTON TRANSACTIONS

Cationic Iridium Complexes Containing Anionic Iridium Counterions Supported by Redox-Active N-Heterocyclic Carbenes

(2013) Kuppuswamy Arumugam et al.   ORGANOMETALLICS

Synthesis and Characterization of Redox-Active Mononuclear Fe(κ2-dppe)(η5-C5Me5)-Terminated π-Conjugated Wires

(2013) Katy Green et al.   ORGANOMETALLICS

Large-Scale Preparation of 1,1′-Ferrocenedicarboxylic Acid, a Key Compound for the Synthesis of 1,1′-Disubstituted Ferrocene Derivatives

(2013) Alex R. Petrov et al.   ORGANOMETALLICS

Coordination of non-stabilized germylenes, stannylenes, and plumbylenes to transition metals

(2013) Judith Baumgartner et al.   REVIEWS IN INORGANIC CHEMISTRY

Exploring the solution behavior of f-element coordination compounds: a case study on some trivalent rare earth and plutonium complexes

(2013) Matthias W. Löble et al.   Chemical Science

Bis(silylenyl)- and Bis(germylenyl)-Substituted Ferrocenes: Synthesis, Structure, and Catalytic Applications of Bidentate Silicon(II)-Cobalt Complexes

(2012) Wenyuan Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A sandwich-type phthalocyaninato metal sextuple-decker complex: synthesis and NLO properties

(2012) Hailong Wang et al.   CHEMICAL COMMUNICATIONS

Cooperative bimetallic catalysis in asymmetric transformations

(2012) Jongwoo Park et al.   CHEMICAL SOCIETY REVIEWS

Redox-active ligands in catalysis

(2012) Oana R. Luca et al.   CHEMICAL SOCIETY REVIEWS

On the Solution Behaviour of Benzyllithium⋅(−)-Sparteine Adducts and Related Lithium Organyls - A Case Study on Applying7Li,15N{1H} HMQC and Further NMR Methods, Including Some Investigation into Asymmetric Synthesis

(2012) María Casimiro et al.   CHEMISTRY-A EUROPEAN JOURNAL

Expanding the Chemistry of CationicN-Heterocyclic Carbenes: Alternative Synthesis, Reactivity, and Coordination Chemistry

(2012) Björn Hildebrandt et al.   CHEMISTRY-A EUROPEAN JOURNAL

Coordination site-dependent cation binding and multi-responsible redox properties of Janus-head metalloligand, [MoV(1,2-mercaptophenolato)3]

(2012) Takeshi Matsumoto et al.   DALTON TRANSACTIONS

Singlet Carbenes Derived from Ferrocene and Closely Related Sandwich Complexes

(2012) Ulrich Siemeling   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cooperative & Redox Non-Innocent Ligands in Directing Organometallic Reactivity (Eur. J. Inorg. Chem. 3/2012)

(2012) Karen Hindson et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

The Shrinking World of Innocent Ligands: Conventionaland Non-Conventional Redox-Active Ligands

(2012) Wolfgang Kaim   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

[W(bipy)(CN)6]−: A Suitable Metalloligand in the Design of Heterotrimetallic Complexes. The First CuIILnIIIWV Trinuclear Complexes

(2012) Maria-Gabriela Alexandru et al.   INORGANIC CHEMISTRY

Synthesis and Characterization of Rigid Ditopic N-Heterocyclic Benzobisgermylenes and -stannylenes

(2012) Sergei Krupski et al.   ORGANOMETALLICS

An experimental and computational study of 1,1′-ferrocene diamines

(2012) Selma Duhović et al.   POLYHEDRON

Investigations on the Steric Accessibility of the Carbanionic Moiety in Zwitterionic Magnesium Tris(pyrazolyl)methanide Complexes. Synthesis and Characterisation of Bi- and Tri­metallic Complexes

(2012) Jens Meyer et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions

(2012) Volodymyr Lyaskovskyy et al.   ACS Catalysis

Ligands that Store and Release Electrons during Catalysis

(2011) Wojciech I. Dzik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Experimental charge density distribution of non-coordinating sp3 carbanions in [Mg{(pz*)3C}2]

(2011) Daniel Kratzert et al.   CHEMICAL COMMUNICATIONS

Redox control of a polymerization catalyst by changing the oxidation state of the metal center

(2011) Erin M. Broderick et al.   CHEMICAL COMMUNICATIONS

Group 10 Metal Complexes of a Ferrocene-Based N-Heterocyclic Carbene: Syntheses, Structures and Catalytic Applications

(2011) Ulrich Siemeling et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cooperative Catalysis with First-Row Late Transition Metals

(2011) Jarl Ivar van der Vlugt   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Preface: Forum on Redox-Active Ligands

(2011) Paul J. Chirik   INORGANIC CHEMISTRY

Manifestations of Noninnocent Ligand Behavior

(2011) Wolfgang Kaim   INORGANIC CHEMISTRY

Synthesis of symmetrically and unsymmetrically 3,5-dimethylbenzyl-substituted 1,1′-ferrocene diamines

(2011) Jason A. Lee et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Redox Control of a Ring-Opening Polymerization Catalyst

(2011) Erin M. Broderick et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Cationic N-Heterocyclic Carbene with an Organometallic Backbone: Synthesis and Reactivity

(2011) Björn Hildebrandt et al.   ORGANOMETALLICS

Steric and Electronic Parameters Characterizing Bulky and Electron-Rich Dialkylbiarylphosphines

(2011) Olivier Diebolt et al.   ORGANOMETALLICS

The Measure of All Rings-N-Heterocyclic Carbenes

(2010) Thomas Dröge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Percent buried volume for phosphine and N-heterocyclic carbene ligands: steric properties in organometallic chemistry

(2010) Hervé Clavier et al.   CHEMICAL COMMUNICATIONS

Cooperative multimetallic catalysis using metallosalens

(2010) Robert M. Haak et al.   CHEMICAL COMMUNICATIONS

A triangulopalladium cluster consisting of μ3-capping silyl ligands

(2010) Felix Armbruster et al.   CHEMICAL COMMUNICATIONS

N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands†

(2010) Matthew Asay et al.   CHEMICAL REVIEWS

Beyond catalysis: N-heterocyclic carbene complexes as components for medicinal, luminescent, and functional materials applications

(2010) Laszlo Mercs et al.   CHEMICAL SOCIETY REVIEWS

Multifunctional ligands in transition metal catalysis

(2010) Robert H. Crabtree   NEW JOURNAL OF CHEMISTRY

Radical-Type Reactivity of Metalla[1.1.1]propellanes of Group 14: Syntheses, Structures, and Reduction Chemistry of Transition Metal-Terminated Bicyclo[1.1.1]pentastannanes

(2010) Dominik Nied et al.   ORGANOMETALLICS

Syntheses and Structural Diversity of Group 2 and Group 12 Tris(pyrazolyl)methaneand Zwitterionic Tris(pyrazolyl)methanideCompounds

(2010) Michael G. Cushion et al.   ORGANOMETALLICS

Halogermanium(II) Complexes Having Phenylamidinate As Supporting Ligands: Syntheses, Characterizations, and Reactivities

(2010) Dimitri Matioszek et al.   ORGANOMETALLICS

N-heterocyclic carbenes which readily add ammonia, carbon monoxide and other small molecules,

(2010) Ulrich Siemeling et al.   Chemical Science

7Li,15N heteronuclear multiple quantum shift correlation—a fast and reliable 2D NMR method on natural abundant nuclei

(2009) Ignacio Fernández et al.   CHEMICAL COMMUNICATIONS

Stable Noncyclic Singlet Carbenes

(2009) Joan Vignolle et al.   CHEMICAL REVIEWS

Carbocyclic Carbene Metal Complexes

(2009) K. Öfele et al.   CHEMICAL REVIEWS

Syntheses, Structures and Electronic Properties of Zwitterionic Iron(II) and Cobalt(II) Complexes Featuring Ambidentate Tris(pyrazolyl)methanide Ligands

(2009) Istemi Kuzu et al.   CHEMISTRY-A EUROPEAN JOURNAL

1,1′-Bis(N-benzimidazolylidene)ferrocene: synthesis and study of a novel ditopic ligand and its transition metal complexes

(2009) C. Daniel Varnado Jr et al.   DALTON TRANSACTIONS

Neutral and cationic main group element cages of germanium(ii) with pyrazolyl ligands: solid state structures, DFT calculations and advanced solution NMR investigations

(2009) Ivo Krummenacher et al.   DALTON TRANSACTIONS

Syntheses, structures, and reactivity of poly(pyrazolyl)silanes, -disilanes, and the ambidentate κ1Si/κ3N-coordinating tris(3,5-dimethylpyrazolyl)silanide ligand [Si(3,5-Me2pz)3]− (MeTpsd)

(2009) Felix Armbruster et al.   DALTON TRANSACTIONS

A ligand knowledge base for carbenes (LKB-C): maps of ligand space

(2009) Natalie Fey et al.   DALTON TRANSACTIONS

Six-Membered N-Heterocyclic Carbenes with a 1,1′-Ferrocenediyl Backbone: Bulky Ligands with Strong Electron-Donor Capacity and Unusual Non-Innocent Character

(2009) Ulrich Siemeling et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

SambVca: A Web Application for the Calculation of the Buried Volume of N-Heterocyclic Carbene Ligands

(2009) Albert Poater et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Redox-Active N-Heterocyclic Carbenes: Design, Synthesis, and Evaluation of Their Electronic Properties

(2009) Evelyn L. Rosen et al.   ORGANOMETALLICS

Diaminocarbene[3]ferrocenophanes and Their Transition-Metal Complexes

(2008) Dimitri M. Khramov et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

(2008) F. Ekkehardt Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A stable crystalline N-heterocyclic carbene with a 1,1′-ferrocenediyl backbone

(2008) Ulrich Siemeling et al.   CHEMICAL COMMUNICATIONS

Syntheses, Reactivity and DFT Studies of Group 2 and Group 12 Metal Complexes of Tris(pyrazolyl)methanides Featuring “Free” Pyramidal Carbanions

(2008) Helen R. Bigmore et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carbenes: Synthesis, properties, and organometallic chemistry

(2008) Pierre de Frémont et al.   COORDINATION CHEMISTRY REVIEWS

Multidentate ligand systems featuring dual functionality

(2008) Istemi Kuzu et al.   DALTON TRANSACTIONS

Mono- and Bidentate Benzannulated N-Heterocyclic Germylenes, Stannylenes and Plumbylenes

(2008) Alexander V. Zabula et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Transition Metal Complexes of N-Heterocyclic Germylenes

(2008) Farman Ullah et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis of (NHC)Rh(cod)Cl and (NHC)RhCl(CO)2 complexes – Translation of the Rh- into the Ir-scale for the electronic properties of NHC ligands

(2008) Stefanie Wolf et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

The Chemistry of Aluminum(I), Silicon(II), and Germanium(II)

(2008) Selvarajan Nagendran et al.   ORGANOMETALLICS

Benzannulated Bisgermylenes - Aggregation Behavior and Coordination Chemistry

(2008) F. Ekkehardt Hahn et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Determination of N-Heterocyclic Carbene (NHC) Steric and Electronic Parameters using the [(NHC)Ir(CO)2Cl] System

(2007) Roy A. Kelly III et al.   ORGANOMETALLICS