Hypervalent Iodine-Catalyzed Oxidative Functionalizations Including Stereoselective Reactions

2-Iodoxy-5-Methylbenzenesulfonic Acid-Catalyzed Selective Oxidation of 4-Bromobenzyl Alcohol to 4-Bromobenzaldehyde or 4-Bromobenzoic Acid with Oxone

(2014)   ORGANIC SYNTHESES

Hydrogen Bonding and Alcohol Effects in Asymmetric Hypervalent Iodine Catalysis: Enantioselective Oxidative Dearomatization of Phenols

(2013) Muhammet Uyanik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–H cycloamination of N-aryl-2-aminopyridines and N-arylamidines catalyzed by an in situ generated hypervalent iodine(iii) reagent

(2013) Yimiao He et al.   CHEMICAL COMMUNICATIONS

Chiral aryl iodide catalysts for the enantioselective synthesis of para-quinols

(2013) Kelly A. Volp et al.   CHEMICAL COMMUNICATIONS

Chiral Hypervalent Iodine Reagents: Synthesis and Reactivity

(2013) Alejandro Parra et al.   CHEMISTRY-A EUROPEAN JOURNAL

An efficient chlorination of aromatic compounds using a catalytic amount of iodobenzene

(2013) Ting-Ting Li et al.   CHINESE CHEMICAL LETTERS

Enantioselective Oxidation of Alkenylbenzoates Catalyzed by Chiral Hypervalent Iodine(III) To Yield 4-Hydroxyisochroman-1-ones

(2013) Mio Shimogaki et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Catalytic and Chemoselective Oxidation of Activated Alcohols and Direct Conversion of Diols to Lactones with In Situ-Generated Bis-IBX Catalyst

(2013) Saona Seth et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Terminal Olefins to Linear α,β-Unsaturated Ketones: Pd(II)/Hypervalent Iodine Co-catalyzed Wacker Oxidation–Dehydrogenation

(2013) Marinus A. Bigi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Dearomatizing Spirolactonization of Naphthols Catalyzed by Spirobiindane-Based Chiral Hypervalent Iodine Species

(2013) Toshifumi Dohi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic C–H/C–H′ Cross-Biaryl Coupling: C-Selective Arylation of Sulfonanilides with Aromatic Hydrocarbons

(2013) Motoki Ito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iodobenzene-Catalyzed Oxabicyclo[3.2.1]octane and [4.2.1]Nonane Synthesis via Cascade C–O/C–C Formation

(2013) Marsewi Ngatimin et al.   ORGANIC LETTERS

Hypervalent Iodine Catalyzed Generation of Nitrile Oxides from Oximes and their Cycloaddition with Alkenes or Alkynes

(2013) Akira Yoshimura et al.   ORGANIC LETTERS

Ugi Four-Component Reaction of Alcohols: Stoichiometric and Catalytic Oxidation/MCR Sequences

(2013) Fleur Drouet et al.   ORGANIC LETTERS

Catalytic Oxidative 1,2-Shift in 1,1′-Disubstituted Olefins Using Arene(iodo)sulfonic Acid as the Precatalyst and Oxone as the Oxidant

(2013) Vikram C. Purohit et al.   ORGANIC LETTERS

Iodobenzene Catalyzed C–H Amination of N-Substituted Amidines Using m-Chloroperbenzoic Acid

(2013) Santhosh Kumar Alla et al.   ORGANIC LETTERS

A New Method for the Benzylic Oxidation of Alkylarenes Catalyzed by Hypervalent Iodine(III)

(2013) Jie Yan et al.   SYNTHESIS-STUTTGART

Catalytic fluorination of 1,3-dicarbonyl compounds using iodoarene catalysts

(2013) Tsugio Kitamura et al.   TETRAHEDRON LETTERS

Metal-Free, n-Bu4NI-Catalyzed Regioselective Difunctionalization of Unactivated Alkenes

(2013) Qicai Xue et al.   ACS Catalysis

Total synthesis of (12R)- and (12S)-12-hydroxymonocerins: stereoselective oxylactonization using a chiral hypervalent iodine(iii) species

(2013) Morifumi Fujita et al.   RSC Advances

Metal-Free Synthesis of 3,3-Disubstituted Oxoindoles by Iodine(III)-Catalyzed Bromocarbocyclizations

(2012) David C. Fabry et al.   CHEMISTRY-A EUROPEAN JOURNAL

An environmentally benign benzylic oxidation catalyzed by hypervalent iodine intermediate in water

(2012) Yuan Xu et al.   CHINESE CHEMICAL LETTERS

A new entry for the oxidation of fluoroalkyl-substituted methanol derivatives: Scope and limitation of the organoiodine(V) reagent-catalyzed oxidation

(2012) Yusuke Tanaka et al.   JOURNAL OF FLUORINE CHEMISTRY

Catalytic Enantioselective α-Tosyloxylation of Ketones Using Iodoaryloxazoline Catalysts: Insights on the Stereoinduction Process

(2012) Audrey-Anne Guilbault et al.   JOURNAL OF ORGANIC CHEMISTRY

Hypervalent Iodine Catalyzed Hofmann Rearrangement of Carboxamides Using Oxone as Terminal Oxidant

(2012) Akira Yoshimura et al.   JOURNAL OF ORGANIC CHEMISTRY

IBS-Catalyzed Regioselective Oxidation of Phenols to 1,2-Quinones with Oxone®

(2012) Muhammet Uyanik et al.   MOLECULES

Synthesis of Tetrazole-Fused Glycosides by a Tandem Fragmentation–Cyclization Reaction

(2012) Nieves R. Paz et al.   ORGANIC LETTERS

Metal-Free, Organocatalytic Syn Diacetoxylation of Alkenes

(2012) Wenhe Zhong et al.   ORGANIC LETTERS

Asymmetric Synthesis of 4,8-Dihydroxyisochroman-1-one Polyketide Metabolites Using Chiral Hypervalent Iodine(III)

(2012) Morifumi Fujita et al.   ORGANIC LETTERS

Organocatalytic, Oxidative, Intermolecular Amination and Hydrazination of Simple Arenes at Ambient Temperature

(2012) Rajarshi Samanta et al.   ORGANIC LETTERS

Study on the reactive transient α-λ3-iodanyl-acetophenone complex in the iodine(III)/PhI(I) catalytic cycle of iodobenzene-catalyzed α-acetoxylation reaction of acetophenone by electrospray ionization tandem mass spectrometry

(2012) Hao-Yang Wang et al.   RAPID COMMUNICATIONS IN MASS SPECTROMETRY

Iodine(III)-Mediated Cyclization of Unsaturated O-Alkyl Hydroxamates: Silyl-Assisted Access to α-Vinyl and α-(2-Silylvinyl) Lactams

(2012) Duncan Wardrop et al.   SYNTHESIS-STUTTGART

Oxidative Cyclization Reactions of Tryptamine Utilizing Hypervalent Iodobenzene in Routes for Pyrroloindole Alkaloid Synthesis

(2012) Shigeru Nishiyama et al.   SYNTHESIS-STUTTGART

Chiral Aryl Iodide-Catalyzed Enantioselective α-Oxidation of Ketones

(2012) Wesley Moran et al.   SYNTHESIS-STUTTGART

Hypervalent Iodine Mediated Oxidative Cyclization of o-Hydroxystilbenes into Benzo- and Naphthofurans

(2012) Thomas Wirth et al.   SYNTHESIS-STUTTGART

Facile preparation and reactivity of bifunctional ionic liquid-supported hypervalent iodine reagent: a convenient recyclable reagent for catalytic oxidation

(2012) Chenjie Zhu et al.   TETRAHEDRON LETTERS

Enantioselective α-tosyloxylation of ketones catalyzed by spirobiindane scaffold-based chiral iodoarenes

(2012) Jun Yu et al.   TETRAHEDRON-ASYMMETRY

Novel 2,2,6,6-Tetramethylpiperidine 1-Oxyl-Iodobenzene Hybrid Catalyst for Oxidation of Primary Alcohols to Carboxylic Acids

(2011) Takayuki Yakura et al.   ADVANCED SYNTHESIS & CATALYSIS

Chiral Hypervalent Iodine Reagents in Asymmetric Reactions

(2011) Huan Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic, Oxidative, Intramolecular CH Bond Amination and Metal-free Cross-Amination of Unactivated Arenes at Ambient Temperature

(2011) Andrey P. Antonchick et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Divergent Synthesis of Benzo[d]thiazoles by PIFA-Mediated Cyclization of β-Oxo Thioamides

(2011) Peng Huang et al.   AUSTRALIAN JOURNAL OF CHEMISTRY

Iodobenzene catalysed synthesis of spirofurans and benzopyrans by oxidative cyclisation of vinylogous esters

(2011) Marsewi Ngatimin et al.   CHEMICAL COMMUNICATIONS

A catalytic version of hypervalent aryl-λ3-iodane-induced Hofmann rearrangement of primary carboxamides: iodobenzene as an organocatalyst and m-chloroperbenzoic acid as a terminal oxidant

(2011) Kazunori Miyamoto et al.   CHEMICAL COMMUNICATIONS

Organoiodine(V) Reagents in Organic Synthesis

(2011) Viktor V. Zhdankin   JOURNAL OF ORGANIC CHEMISTRY

TwistDoes aTwistto the Reactivity: Stoichiometric and Catalytic Oxidations withTwistedTetramethyl-IBX

(2011) Jarugu Narasimha Moorthy et al.   JOURNAL OF ORGANIC CHEMISTRY

Effective oxidation of benzylic and alkane C–H bonds catalyzed by sodium o-iodobenzenesulfonate with Oxone as a terminal oxidant under phase-transfer conditions

(2011) Li-Qian Cui et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Iodobenzene-Catalyzed Intramolecular Oxidative Cyclization Reactions of δ-Alkynyl β-Ketoesters

(2011) Arantxa Rodríguez et al.   ORGANIC LETTERS

A Metal-Free Amination of Benzoxazoles – The First Example of an Iodide-Catalyzed Oxidative Amination of Heteroarenes

(2011) Tanja Froehr et al.   ORGANIC LETTERS

Selenium-Catalyzed Regioselective Cyclization of Unsaturated Carboxylic Acids Using Hypervalent Iodine Oxidants

(2011) Fateh V. Singh et al.   ORGANIC LETTERS

Preparation and Reactivity of Polystyrene-Supported Iodosylbenzene: Convenient Recyclable Oxidizing Reagent and Catalyst

(2011) Jiang-Min Chen et al.   SYNLETT

Iodobenzene-Mediated Intramolecular Oxidative Coupling of Substituted 4-Hydroxyphenyl-N-phenylbenzamides for the Synthesis of Spirooxindoles

(2011) Wei Yu et al.   SYNTHESIS-STUTTGART

An Effective Catalytic α-Phosphoryloxylation of Ketones with Iodobenzene

(2011) Jie Yan et al.   SYNTHESIS-STUTTGART

Highly Efficient and Enantioselective α-Arylation of Cycloalkanones by Scandium-Catalyzed Diazoalkane-Carbonyl Homologation

(2011) Jason Kingsbury et al.   SYNTHESIS-STUTTGART

Recyclable silica-supported iodoarene–RuCl3 bifunctional catalysts for oxidation of alcohols and alkylarenes

(2011) Xiao-Mei Zeng et al.   TETRAHEDRON LETTERS

Enantioselective Kita Oxidative Spirolactonization Catalyzed by In Situ Generated Chiral Hypervalent Iodine(III) Species

(2010) Muhammet Uyanik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Catalyzed α-Arylation of Carbonyl and Related Molecules: Novel Trends in CC Bond Formation by CH Bond Functionalization

(2010) Carin C. C. Johansson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Discovery of Catalytic Enantioselective Polyvalent Iodine Mediated Reactions

(2010) Marsewi Ngatimin et al.   AUSTRALIAN JOURNAL OF CHEMISTRY

Recycling and Catalytic Approaches for the Development of a Rare-Metal-Free Synthetic Method Using Hypervalent Iodine Reagent

(2010) Toshifumi Dohi   CHEMICAL & PHARMACEUTICAL BULLETIN

Designer μ-oxo-bridged hypervalent iodine(iii) organocatalysts for greener oxidations

(2010) Toshifumi Dohi et al.   CHEMICAL COMMUNICATIONS

An effective and catalytic oxidation using recyclable fluorous IBX

(2010) Tsuyoshi Miura et al.   CHEMICAL COMMUNICATIONS

Benziodoxole-based hypervalent iodine reagents for atom-transfer reactions

(2010) Jonathan P. Brand et al.   CHEMICAL COMMUNICATIONS

Bromine-Catalyzed Aerobic Oxidation of Alcohols

(2010) Muhammet Uyanik et al.   Chemistry-An Asian Journal

Iodoarene-Mediated Cyclization of N-Methoxy-2-arylethanesulfonamides with Oxone

(2010) Hideo Togo et al.   HETEROCYCLES

Stereoselective Synthesis of 2-Carbamoyl-2-cyanocyclopropanecarboxylates by Tandem Oxidative Cyclization and Neighboring Group-Assisted Decarboxylation

(2010) Hua Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Development of new recyclable reagents and catalytic systems based on hypervalent iodine compounds

(2010) Mekhman S. Yusubov et al.   MENDELEEV COMMUNICATIONS

Catalytic hypervalent iodine oxidation of alcohols to corresponding aldehydes or ketones using 2,2,6,6-tetramethylpiperidinyl-1-oxy and potassium peroxodisulfate

(2010) Chenjie Zhu et al.   MONATSHEFTE FUR CHEMIE

Oxidative Cleavage of Alkenes Using an In Situ Generated Iodonium Ion with Oxone as a Terminal Oxidant

(2010) Prem P. Thottumkara et al.   ORGANIC LETTERS

An Efficient and Regioselective Monobromination of Electron-Rich Aromatic Compounds Using Catalytic Hypervalent Iodine(III) Reagent

(2010) Zhongshi Zhou et al.   SYNTHESIS-STUTTGART

Transition metal-mediated oxidations utilizing monomeric iodosyl- and iodylarene species

(2010) Mekhman S. Yusubov et al.   TETRAHEDRON

‘Aromatic ring umpolung’, a rapid access to the main core of several natural products

(2010) Kimiaka C. Guérard et al.   TETRAHEDRON

2-Iodoxybenzoic acid (IBX): an efficient hypervalent iodine reagent

(2010) Vijay Satam et al.   TETRAHEDRON

Hypervalent iodine oxidation of phenol derivatives using a catalytic amount of 4-iodophenoxyacetic acid and Oxone® as a co-oxidant

(2010) Takayuki Yakura et al.   TETRAHEDRON

A versatile PIFA-mediated approach to structurally diverse pyrrolo(benzo)diazepines from linear alkynylamides

(2010) Leticia M. Pardo et al.   TETRAHEDRON

Chiral hypervalent iodine-catalyzed enantioselective oxidative Kita spirolactonization of 1-naphthol derivatives and one-pot diastereo-selective oxidation to epoxyspirolactones

(2010) Muhammet Uyanik et al.   TETRAHEDRON

Synthetic aspects of the oxidative amidation of phenols

(2010) Huan Liang et al.   TETRAHEDRON

Metal-free intramolecular cyclopropanation of alkenes through iodonium ylide methodology

(2010) Robert M. Moriarty et al.   TETRAHEDRON

A convenient phosphoryloxylactonization of pentenoic acids with catalytic hypervalent iodine(III) reagent

(2010) Zhong-Shi Zhou et al.   TETRAHEDRON LETTERS

Asymmetric Hydroxylative Phenol Dearomatization through In Situ Generation of Iodanes from Chiral Iodoarenes andm-CPBA

(2009) Stéphane Quideau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hypervalent Bromine Compounds: Smaller, More Reactive Analogues of Hypervalent Iodine Compounds

(2009) Umar Farooq et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diaryliodonium Salts: A Journey from Obscurity to Fame

(2009) Eleanor���A. Merritt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organoiodine-Catalyzed Oxidative Spirocyclization of Phenols using Peracetic Acid as a Green and Economic Terminal Oxidant

(2009) Yutaka Minamitsuji et al.   AUSTRALIAN JOURNAL OF CHEMISTRY

Hypervalent iodine-catalyzed oxylactonization of ketocarboxylic acids to ketolactones

(2009) Muhammet Uyanik et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Efficient Synthesis of p-Quinols Using Catalytic Hypervalent Iodine Oxidation of 4-Arylphenols with 4-Iodophenoxyacetic Acid and Oxone®

(2009) Takayuki Yakura et al.   CHEMICAL & PHARMACEUTICAL BULLETIN

Catalytic Hypervalent Iodine Oxidation Using 4-Iodophenoxyacetic Acid and Oxone®: Oxidation of p-Alkoxyphenols to p-Benzoquinones

(2009) Takayuki Yakura et al.   CHEMICAL & PHARMACEUTICAL BULLETIN

Hypervalent iodine reagents as a new entrance to organocatalysts

(2009) Toshifumi Dohi et al.   CHEMICAL COMMUNICATIONS

Hypervalent iodine-mediated oxidation of alcohols

(2009) Muhammet Uyanik et al.   CHEMICAL COMMUNICATIONS

Organocatalysis—after the gold rush

(2009) Søren Bertelsen et al.   CHEMICAL SOCIETY REVIEWS

Iodine(V)/Ruthenium(III)-Cocatalyzed Oxidations: A Highly Efficient Tandem Catalytic System for the Oxidation of Alcohols and Hydrocarbons with Oxone

(2009) Mekhman S. Yusubov et al.   CHEMISTRY-A EUROPEAN JOURNAL

Effects of Aromatic Substituents of Electrochemically Generated Hypervalent Iodine Oxidant on Oxidation Reactions

(2009) Shigeru Nishiyama et al.   HETEROCYCLES

Iodomesitylene-Catalyzed Oxidative Cleavage of Carbon−Carbon Double and Triple Bonds Usingm-Chloroperbenzoic Acid as a Terminal Oxidant

(2009) Kazunori Miyamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

IBS-Catalyzed Oxidative Rearrangement of Tertiary Allylic Alcohols to Enones with Oxone

(2009) Muhammet Uyanik et al.   ORGANIC LETTERS

An Efficient Catalytic Sulfonyloxylactonization of Alkenoic Acids Using Hypervalent Iodine(III) Reagent

(2009) Jie Yan et al.   SYNLETT

Ion-supported PhI-catalyzed cyclization of N-methoxy-2-arylethanesulfonamides with mCPBA

(2009) Yoshihide Ishiwata et al.   TETRAHEDRON LETTERS

A Chiral Hypervalent Iodine(III) Reagent for Enantioselective Dearomatization of Phenols

(2008) Toshifumi Dohi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Hypervalent Iodine Oxidation of p-Dialkoxybenzenes to p-Quinones Using 4-Iodophenoxyacetic Acid and Oxone®

(2008) Takayuki Yakura et al.   CHEMICAL & PHARMACEUTICAL BULLETIN

Chemistry of Polyvalent Iodine

(2008) Viktor V. Zhdankin et al.   CHEMICAL REVIEWS

Catalytic Enantioselective α-Oxysulfonylation of Ketones Mediated by Iodoarenes

(2008) Sabine M. Altermann et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Catalytic Version of and Reuse in Hypervalent Organo-λ3- and -λ5-iodane Oxidation

(2008) Masahito Ochiai et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

2-Iodoxybenzenesulfonic Acid as an Extremely Active Catalyst for the Selective Oxidation of Alcohols to Aldehydes, Ketones, Carboxylic Acids, and Enones with Oxone

(2008) Muhammet Uyanik et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New H2O2/Acid Anhydride System for the Iodoarene-Catalyzed C−C Bond-Forming Reactions of Phenols

(2008) Toshifumi Dohi et al.   ORGANIC LETTERS

Oxidative Dearomatization of Phenols: Why, How and What For?

(2008) Stéphane Quideau et al.   SYNLETT

Modified o-methyl-substituted IBX: room temperature oxidation of alcohols and sulfides in common organic solvents

(2007) Jarugu Narasimha Moorthy et al.   TETRAHEDRON LETTERS