期刊
SYNLETT
卷 -, 期 11, 页码 1613-1617出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0030-1260788
关键词
polymers; iodine; oxidation; iodosylbenzene; recyclable reagent
资金
- Foundation of Jiaxing University
- National Science Foundation [CHE-1009038]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1009038] Funding Source: National Science Foundation
A facile preparation of novel polystyrene-supported iodosylbenzene (PS-ISB, loading of IO up to 1.50 mmol/g) from iodopolystyrene is described. This resin has been successfully used for efficient oxidation of a diverse collection of alcohols to aldehydes and ketones in the presence of BF3 center dot OEt2. PS-ISB can also be employed as efficient co-catalyst in combination with RuCl3 in the catalytic oxidation of alcohols and aromatic hydrocarbons, respectively, to corresponding carboxylic acids and ketones using Oxone as the stoichiometric oxidant.
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