期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 77, 期 24, 页码 11399-11404出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo302375m
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资金
- National Science Foundation [CHE-1009038]
- Direct For Mathematical & Physical Scien [1009038] Funding Source: National Science Foundation
- Division Of Chemistry [1009038] Funding Source: National Science Foundation
Hofmann rearrangement of carboxamides to carbamates using Ozone as an oxidant can be efficiently catalyzed by iodobenzene. This reaction involves hypervalent iodine species generated in situ from catalytic amount of PhI and Oxone in the presence of 1,1,1,3,3,3-hexafluoroisopropanol (HFIP) in aqueous methanol solutions. Under these conditions, Hofmann rearrangement of various carboxamides affords corresponding carbamates in high yields.
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