期刊
TETRAHEDRON LETTERS
卷 53, 期 12, 页码 1438-1444出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.01.053
关键词
Hypervalent iodine; Hybrid catalysts; Oxidation; Ionic liquids; TEMPO
资金
- Jiangsu Higher Education Institutions [CX2211_0266]
- National Science Foundation [CHE-1009038, MRI CHE-0922366]
- Direct For Mathematical & Physical Scien [1009038] Funding Source: National Science Foundation
- Division Of Chemistry [1009038] Funding Source: National Science Foundation
Novel, efficient, and recyclable bifunctional catalysts bearing ionic liquid supported (2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPO) and iodoarene moieties were developed and used for environmentally benign catalytic oxidation of alcohols. The reactions using peracetic acid as a green and practical co-oxidant afforded the corresponding carbonyl compounds in high yields under mild conditions and convenient work-up. Furthermore, these ionic liquid supported bifunctional catalysts could be simply recovered and reused. (C) 2012 Elsevier Ltd. All rights reserved.
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