期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2008, 期 31, 页码 5315-5328出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200800741
关键词
Hypervalent iodine reagents; Organocatalysis; Oxidation; Stereoselective synthesis
资金
- Cardiff University and the Royal Society of Chemistry (RSC)
- Engineering and Physical Sciences Research Council (EPSRC)
- National Mass Spectrometry Service Centre, Swansea
- Michigan State University Mass Spectrometry Services
- EPSRC
- US National Science Foundation [INT-0209956]
- Albion College
The alpha-oxysulfonylation of ketones catalysed by enantio enriched iodoarenes using mCPBA as stoichiometric oxidant is reported to give useful synthetic intermediates in good yield and modest enantioselectivity. We believe this to be the first report of an enantioselective organocatalytic reaction involving hypervalent iodine reagents which should open up a new field for enantioselective organocatalysis of oxidation reactions. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
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