期刊
JOURNAL OF FLUORINE CHEMISTRY
卷 137, 期 -, 页码 99-104出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2012.03.002
关键词
Fluoroalkyl-substituted methanols; Sodium 2-iodobenzenesulfonate; Oxone (R); Hypervalent iodine(V)
Oxidation of various fluoroalkyl-substituted methanol derivatives under the influence of a catalytic amount of sodium 2-iodobenzenesulfonate and Oxone (R) in CH3CN or CH3NO2 was investigated in detail. The efficiency of the newly developed oxidation was also evaluated by comparison to other oxidations, such as Dess-Martin, PDC, and Swern oxidation. (c) 2012 Elsevier B.V. All rights reserved.
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