Zn(II)-Catalyzed Multicomponent Sustainable Synthesis of Pyridines in Air

Ligand centered redox enabled sustainable synthesis of triazines and pyrimidines using a zinc-stabilized azo-anion radical catalyst

(2022) Siuli Das et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Ruthenium-Catalyzed Dehydrogenative Functionalization of Alcohols to Pyrroles: A Comparison between Metal–Ligand Cooperative and Non-cooperative Approaches

(2022) Amit Kumar Guin et al.   JOURNAL OF ORGANIC CHEMISTRY

Zn(II)-Catalyzed Selective N-Alkylation of Amines with Alcohols Using Redox Noninnocent Azo-Aromatic Ligand as Electron and Hydrogen Reservoir

(2022) Subhajit Chakraborty et al.   Journal of Organic Chemistry

Enzyme‐Like Supramolecular Iridium Catalysis Enabling C‐H Bond Borylation of Pyridines with meta‐Selectivity

(2021) Rafael Gramage-Doria et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sustainable Four-Component Annulation for the Synthesis of 2,3,4,6-Tetraarylpyridines

(2021) Yuxin Ding et al.   JOURNAL OF ORGANIC CHEMISTRY

Regioselective Synthesis of 2,4-Diaryl-6-trifluoromethylated Pyridines through Copper-Catalyzed Cyclization of CF3-Ynones and Vinyl Azides

(2021) Jixin Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Alkyl Phosphine Free, Metal‐Ligand Cooperative Complex Catalyzed Alcohol Dehydrogenative Coupling Reactions

(2021) Bivas Chandra Roy et al.   Asian Journal of Organic Chemistry

Synthesis of N ‐Heterocycles via Oxidant‐Free Dehydrocyclization of Alcohols Using Heterogeneous Catalysts

(2021) Kangkang Sun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Progress in the Synthesis of Heterocycles through Base Metal‐Catalyzed Acceptorless Dehydrogenative and Borrowing Hydrogen Approach

(2021) Avijit Mondal et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Iron-Catalyzed Alkyne-Based Multicomponent Synthesis of Pyrimidines under Air

(2021) Rakesh Mondal et al.   JOURNAL OF ORGANIC CHEMISTRY

[3 + 2 + 1] Pyridine Skeleton Synthesis Using Acetonitrile as C4N1 Units and Solvent

(2021) Chaolumen Bai et al.   JOURNAL OF ORGANIC CHEMISTRY

Nickelocene as an Air- and Moisture-Tolerant Precatalyst in the Regioselective Synthesis of Multisubstituted Pyridines

(2021) Il Young Cho et al.   JOURNAL OF ORGANIC CHEMISTRY

Practical and Regioselective Synthesis of C-4-Alkylated Pyridines

(2021) Jin Choi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Zinc Stabilized Azo-anion Radical in Dehydrogenative Synthesis of N-Heterocycles. An Exclusively Ligand Centered Redox Controlled Approach

(2021) Siuli Das et al.   ACS Catalysis

Cobalt-catalyzed dehydrogenative functionalization of alcohols: Progress and future prospect

(2021) Ishani Borthakur et al.   COORDINATION CHEMISTRY REVIEWS

Borrowing Hydrogen and Acceptorless Dehydrogenative Coupling in the Multicomponent Synthesis of N‐Heterocycles: A Comparison between Base and Noble Metal Catalysis

(2021) Natalie Hofmann et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

A directive Ni catalyst overrides conventional site selectivity in pyridine C–H alkenylation

(2021) Tao Zhang et al.   Nature Chemistry

Metal–ligand cooperative approaches in homogeneous catalysis using transition metal complex catalysts of redox noninnocent ligands

(2021) Rakesh Mondal et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Eco-friendly and sustainable synthetic approaches to biologically significant fused N-heterocycles

(2020) Shiv Shankar Gupta et al.   Chemistry of Heterocyclic Compounds

Manganese(I)-Catalyzed Sustainable Synthesis of Quinoxaline and Quinazoline Derivatives with the Liberation of Dihydrogen

(2020) Akash Mondal et al.   JOURNAL OF ORGANIC CHEMISTRY

NH4I-Triggered [4 + 2] Annulation of α,β-Unsaturated Ketoxime Acetates with N-Acetyl Enamides for the Synthesis of Pyridines

(2020) Jindian Duan et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Pyridines, Quinolines, and Pyrimidines via Acceptorless Dehydrogenative Coupling Catalyzed by a Simple Bidentate P^N Ligand Supported Ru Complex

(2020) Rajarshi Mondal et al.   ORGANOMETALLICS

Iron-Catalyzed Hydrogen Transfer Reduction of Nitroarenes with Alcohols: Synthesis of Imines and Aza Heterocycles

(2020) Jiajun Wu et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhenium-Catalyzed Dehydrogenative Coupling of Alcohols and Amines to Afford Nitrogen-Containing Aromatics and More

(2019) Matthias Mastalir et al.   ORGANIC LETTERS

Dehydrogenative Synthesis of Quinolines, 2-Aminoquinolines, and Quinazolines Using Singlet Diradical Ni(II)-Catalysts

(2019) Gargi Chakraborty et al.   JOURNAL OF ORGANIC CHEMISTRY

Phosphine Ligand‐Free Ruthenium Complexes as Efficient Catalysts for the Synthesis of Quinolines and Pyridines by Acceptorless Dehydrogenative Coupling Reactions

(2019) Bin Guo et al.   ChemCatChem

A Reusable Cobalt Catalyst for Reversible Acceptorless Dehydrogenation and Hydrogenation of N‐Heterocycles

(2019) Garima Jaiswal et al.   ChemCatChem

Sustainable synthesis of N-heterocycles in water using alcohols following the double dehydrogenation strategy

(2019) Milan Maji et al.   JOURNAL OF CATALYSIS

meta-Selective C–H Borylation of Benzamides and Pyridines by an Iridium–Lewis Acid Bifunctional Catalyst

(2019) Lichen Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron Catalyzed Synthesis of Pyrimidines Under Air

(2019) Rakesh Mondal et al.   ADVANCED SYNTHESIS & CATALYSIS

Cobalt-catalyzed acceptorless dehydrogenative coupling of aminoalcohols with alcohols: direct access to pyrrole, pyridine and pyrazine derivatives

(2018) Siba P. Midya et al.   CHEMICAL COMMUNICATIONS

A nitrogen-ligated nickel-catalyst enables selective intermolecular cyclisation of β- and γ-amino alcohols with ketones: access to five and six-membered N-heterocycles

(2018) Khushboo Singh et al.   GREEN CHEMISTRY

An Azoaromatic Ligand as Four Electron Four Proton Reservoir: Catalytic Dehydrogenation of Alcohols by Its Zinc(II) Complex

(2018) Rajib Pramanick et al.   INORGANIC CHEMISTRY

Synthesis of polysubstituted pyridines from oxime acetates using NH4I as a dual-function promoter

(2018) Yujia Xia et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

NNN-Ruthenium Catalysts for the Synthesis of Pyridines, Quinolines, and Pyrroles by Acceptorless Dehydrogenative Condensation

(2018) Danfeng Deng et al.   ORGANOMETALLICS

Catalytic condensation for the formation of polycyclic heteroaromatic compounds

(2018) Daniel Forberg et al.   Nature Communications

Phosphine free Mn-complex catalysed dehydrogenative C–C and C–heteroatom bond formation: a sustainable approach to synthesize quinoxaline, pyrazine, benzothiazole and quinoline derivatives

(2018) Kalicharan Das et al.   CHEMICAL COMMUNICATIONS

Acceptorless Dehydrogenative Coupling Using Ammonia: Direct Synthesis of N-Heteroaromatics from Diols Catalyzed by Ruthenium

(2018) Prosenjit Daw et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Pyrazines and Quinoxalines via Acceptorless Dehydrogenative Coupling Routes Catalyzed by Manganese Pincer Complexes

(2018) Prosenjit Daw et al.   ACS Catalysis

Iron-Catalyzed Aerobic Oxidative Cleavage and Construction of C−N Bonds: A Facile Method for Synthesis of 2,4,6-Trisubstituted Pyridines

(2018) Kovuru Gopalaiah et al.   Asian Journal of Organic Chemistry

First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands

(2018) Lukas Alig et al.   CHEMICAL REVIEWS

Synthesis of symmetrical pyridines by iron-catalyzed cyclization of ketoxime acetates and aldehydes

(2017) YuKun Yi et al.   GREEN CHEMISTRY

Redox Noninnocent Azo-Aromatic Pincers and Their Iron Complexes. Isolation, Characterization, and Catalytic Alcohol Oxidation

(2017) Suman Sinha et al.   INORGANIC CHEMISTRY

A Versatile Ru(II)-NNP Complex Catalyst for the Synthesis of Multisubstituted Pyrroles and Pyridines

(2017) Huining Chai et al.   ORGANOMETALLICS

Iridium-catalyzed annulation between 1,2-diarylethanone and 3-aminopropanol toward site-specific 2,3-diaryl pyridines

(2017) Ning Gu et al.   TETRAHEDRON LETTERS

Acid-catalyzed tandem reaction for the synthesis of pyridine derivatives via CC/C(sp3)–N bond cleavage of enones and primary amines

(2017) Zhong-Yuan Mao et al.   RSC Advances

Metal-Free Synthesis of Highly Substituted Pyridines by Formal [2+2+2] Cycloaddition under Mild Conditions

(2016) Lan-Gui Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of meta -Functionalized Pyridines by Selective Dehydrogenative Heterocondensation of β- and γ-Amino Alcohols

(2016) Toni Hille et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Synthesis of Pyrroles by Dehydrogenative Coupling of Diols and Amines Catalyzed by Cobalt Pincer Complexes

(2016) Prosenjit Daw et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Discovery of pyridine-based agrochemicals by using Intermediate Derivatization Methods

(2016) Ai-Ying Guan et al.   BIOORGANIC & MEDICINAL CHEMISTRY

HOTf-catalyzed sustainable one-pot synthesis of benzene and pyridine derivatives under solvent-free conditions

(2016) Xu Zhang et al.   GREEN CHEMISTRY

Sustainable Synthesis of Quinolines and Pyrimidines Catalyzed by Manganese PNP Pincer Complexes

(2016) Matthias Mastalir et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed C3-Selective Arylation of Pyridine with (Hetero)arenes

(2016) Guo-Lin Gao et al.   ORGANIC LETTERS

Metal-Free Synthesis of 2,4,6-Trisubstituted Pyridines via Iodine-Initiated Reaction of Methyl Aryl Ketones with Amines under Neat Heating

(2016) Ze Zhang et al.   SYNTHESIS-STUTTGART

A Ruthenium Catalyst with Unprecedented Effectiveness for the Coupling Cyclization of γ-Amino Alcohols and Secondary Alcohols

(2016) Bing Pan et al.   ACS Catalysis

Transition-Metal-Catalyzed Hydrogen-Transfer Annulations: Access to Heterocyclic Scaffolds

(2015) Avanashiappan Nandakumar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cu-Catalyzed Three-Component Cascade Annulation Reaction: An Entry to Functionalized Pyridines

(2015) Huanfeng Jiang et al.   JOURNAL OF ORGANIC CHEMISTRY

Base-Promoted β-C(sp3)–H Functionalization of Enaminones: An Approach to Polysubstituted Pyridines

(2015) Jinhai Shen et al.   JOURNAL OF ORGANIC CHEMISTRY

A Sustainable Multicomponent Pyrimidine Synthesis

(2015) Nicklas Deibl et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Divergent synthesis of 4,6-diarylated pyridin-2(1H)-ones from chalcones: novel access to 2,4,6-triaryl pyridines

(2015) Rajni Khajuria et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Aza-Annulation of Enynyl Azides: A New Approach to Substituted Pyridines

(2015) Chada Raji Reddy et al.   ORGANIC LETTERS

Metal-Free Multicomponent Syntheses of Pyridines

(2014) Christophe Allais et al.   CHEMICAL REVIEWS

The Synthesis of Benzimidazoles and Quinoxalines from Aromatic Diamines and Alcohols by Iridium-Catalyzed Acceptorless Dehydrogenative Alkylation

(2014) Toni Hille et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ligand-Centered Redox in Nickel(II) Complexes of 2-(Arylazo)pyridine and Isolation of 2-Pyridyl-Substituted Triaryl Hydrazines via Catalytic N-Arylation of Azo-Function

(2014) Debabrata Sengupta et al.   INORGANIC CHEMISTRY

Iridium-Catalyzed C–H Borylation of Heteroarenes: Scope, Regioselectivity, Application to Late-Stage Functionalization, and Mechanism

(2014) Matthew A. Larsen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt(III)-Catalyzed Synthesis of Indazoles and Furans by C–H Bond Functionalization/Addition/Cyclization Cascades

(2014) Joshua R. Hummel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Pyridines by Carbenoid-Mediated Ring Opening of 2H-Azirines

(2013) Nicole S. Y. Loy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Synthesis of Highly Functionalized Pyridines at Room Temperature

(2013) Zugui Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

More Sustainable Formation of CN and CC Bonds for the Synthesis of N-Heterocycles

(2013) Johannes Schranck et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselectively Functionalized Pyridines from Sustainable Resources

(2013) Stefan Michlik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Synthesis of Pyrroles by Dehydrogenative Coupling of β-Aminoalcohols with Secondary Alcohols Catalyzed by Ruthenium Pincer Complexes

(2013) Dipankar Srimani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct synthesis of pyridines and quinolines by coupling of γ-amino-alcohols with secondary alcohols liberating H2 catalyzed by ruthenium pincer complexes

(2013) Dipankar Srimani et al.   CHEMICAL COMMUNICATIONS

Modular Pyridine Synthesis from Oximes and Enals through Synergistic Copper/Iminium Catalysis

(2013) Ye Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A sustainable catalytic pyrrole synthesis

(2013) Stefan Michlik et al.   Nature Chemistry

Applications of Acceptorless Dehydrogenation and Related Transformations in Chemical Synthesis

(2013) C. Gunanathan et al.   SCIENCE

Dual Heterogeneous Catalysis for a Regioselective Three- Component Synthesis of Bi- and Tri(hetero)arylpyridines

(2012) Christophe Allais et al.   ADVANCED SYNTHESIS & CATALYSIS

Selective Ruthenium-Catalyzed Three-Component Synthesis of Pyrroles

(2012) Min Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cationic Ruthenium Catalysts for Alkyne Annulations with Oximes by C–H/N–O Functionalizations

(2012) Christoph Kornhaaß et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhenium-Catalyzed Regioselective Synthesis of Multisubstituted Pyridines from β-Enamino Ketones and Alkynes via C–C Bond Cleavage

(2012) Shun-ichi Yamamoto et al.   ORGANIC LETTERS

Metal–Ligand Cooperation by Aromatization–Dearomatization: A New Paradigm in Bond Activation and “Green” Catalysis

(2011) Chidambaram Gunanathan et al.   ACCOUNTS OF CHEMICAL RESEARCH

Mn(III)-Mediated Formal [3+3]-Annulation of Vinyl Azides and Cyclopropanols: A Divergent Synthesis of Azaheterocycles

(2011) Yi-Feng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-Metal-Catalyzed C-H Functionalization for the Synthesis of Substituted Pyridines

(2011) Yoshiaki Nakao   SYNTHESIS-STUTTGART

One-Pot Multicomponent Condensation Reaction of Aldehydes with Cyclic Ketones

(2011) Ping Wu et al.   SYNTHETIC COMMUNICATIONS

Efficient, mild and completely regioselective synthesis of substituted pyridines

(2010) Hans Andersson et al.   CHEMICAL COMMUNICATIONS

Mn(III)-Mediated Reactions of Cyclopropanols with Vinyl Azides: Synthesis of Pyridine and 2-Azabicyclo[3.3.1]non-2-en-1-ol Derivatives

(2009) Yi-Feng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A green protocol for synthesis of benzo-fused N,S-, N,O- and N,N-heterocycles in water

(2008) Qing-Yi Zhang et al.   GREEN CHEMISTRY

A Cascade Approach to Pyridines from 2-Azido-2,4-dienoates and α-Diazocarbonyl Compounds

(2008) Zheng-Bo Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Dihydropyridines and Pyridines from Imines and Alkynes via C−H Activation

(2008) Denise A. Colby et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

One-Pot Synthesis of Highly Functionalized Pyridines via a Rhodium Carbenoid Induced Ring Expansion of Isoxazoles

(2008) James R. Manning et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed One-Pot Synthesis of Substituted Pyridine Derivatives from α,β-Unsaturated Ketoximes and Alkynes

(2007) Kanniyappan Parthasarathy et al.   ORGANIC LETTERS