期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 362, 期 3, 页码 594-600出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201901172
关键词
redox-active ligands; iron catalysis; metal-ligand cooperativity; multicomponent dehydrogenative coupling; pyrimidines
资金
- DST, Govt. of India [YSS/2015/001552]
- CSIR
- IIESTS
- UGC
Herein we report an iron-catalyzed multicomponent dehydrogenative functionalization of alcohols to pyrimidines under atmospheric conditions. Using a well-defined Fe(II)-complex featuring redox noninnocent 2-phenylazo-(1,10-phenanthroline) ligand, as a catalyst, a wide array of 2,4,6-trisubstituted pyrimidines were prepared via dehydrogenative coupling of primary and secondary alcohols with amidines under air at 100 degrees C. A few control experiments were carried out to understand and unveil the plausible reaction mechanism.
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