期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 84, 期 5, 页码 2626-2641出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b03070
关键词
-
资金
- DST-SERB [YSS/2015/001552]
- CSIR, New Delhi [01(5234)/15]
- UGC
- RJNF
- CSIR
- IIETS
- IIESTS
Simple, straightforward, and atom economic methods for the synthesis of quinolines, 2-aminoquinolines, and quinazolines via biomimetic dehydrogenative condensation/coupling reactions, catalyzed by well-defined inexpensive and easy to prepare singlet diradical Ni(II)-catalysts featuring two antiferromagnetically coupled singlet diradical diamine type ligands are described. Various polysubstituted quinolines, 2-aminoquinolines, and quinazolines were synthesized in moderate to good yields from different low-cost and readily accessible starting materials. Several control experiments were carried out to get insight into the reaction mechanism which shows that the nickel and the coordinated diamine ligands participate in a synergistic way during the dehydrogenation of alcohols.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据