Group 15 biradicals: synthesis and reactivity of cyclobutane-1,3-diyl and cyclopentane-1,3-diyl analogues

A Dimer of Hydrogen Cyanide Stabilized by a Lewis Acid

(2018) Kevin Bläsing et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Trapping of transient, heavy pnictogen-centred biradicals

(2018) J. Bresien et al.   DALTON TRANSACTIONS

As-N and As-N-P Cage Compounds Generated by [2+2] Addition of Diazenes and Diphosphenes to Diarsadiazanediyls

(2018) Jonas Bresien et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Topics of 1,3-diphosphacyclobutane-2,4-diyl derivatives: Structural aspects and functionality of isolable heavier congeners of cyclobutane-1,3-diyl and the related molecules

(2018) Shigekazu Ito   TETRAHEDRON LETTERS

Metal-Free Activation of Hydrogen, Carbon Dioxide, and Ammonia by the Open-Shell Singlet Biradicaloid [P(μ-NTer)]2

(2016) Alexander Hinz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

On the behaviour of biradicaloid [P(μ-NTer)]2 towards Lewis acids and bases

(2016) Alexander Hinz et al.   CHEMICAL COMMUNICATIONS

Reactive p-block cations stabilized by weakly coordinating anions

(2016) Tobias A. Engesser et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of a Molecule with Four Different Adjacent Pnictogens

(2016) Alexander Hinz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reduction of dichloro(diaza-phospha)stibanes – isolation of a donor-stabilized distibenium dication

(2016) Alexander Hinz et al.   DALTON TRANSACTIONS

Synthesis of a Silylated Phosphorus Biradicaloid and Its Utilization in the Activation of Small Molecules

(2016) Alexander Hinz et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis of Heavy Cyclodipnictadiphosphanes [ClE(μ-P-Ter)]2 [E = P, As, Sb, or Bi; Ter = 2,6-bis(2,4,6-trimethylphenyl)phenyl]

(2016) Alexander Hinz et al.   INORGANIC CHEMISTRY

Activation of small molecules by biradicaloids

(2016) Alexander Hinz et al.   PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS

The stability of biradicaloid versus closed-shell [E(μ-XR)]2 (E = P, As; X = N, P, As) rings. Does aromaticity play a role?

(2016) Rafael Grande-Aztatzi et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Zwitterionic and biradicaloid heteroatomic cyclopentane derivatives containing different group 15 elements

(2016) Alexander Hinz et al.   Chemical Science

Stable Heterocyclopentane-1,3-diyls

(2015) Alexander Hinz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Accessing heavy allyl-analogous [(TerN)2E]− (E = Sb, Bi) ions and their reactivity towards ECl3

(2015) Alexander Hinz et al.   CHEMICAL COMMUNICATIONS

P–P σ-bond activation by gold(I) coordination

(2015) Alexander Hinz et al.   CHEMICAL COMMUNICATIONS

Highly selective visible light-induced Ti–O bond splitting in an ansa-titanocene dihydroxido complex

(2015) Christian Godemann et al.   CHEMICAL COMMUNICATIONS

Cyclo-Pnicta-triazanes: Biradicaloids or Zwitterions?

(2015) Alexander Hinz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tunable Cyclopentane-1,3-diyls Generated by Insertion of Isonitriles into Diphosphadiazanediyls

(2015) Alexander Hinz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Frustrated Lewis Pairs

(2015) Douglas W. Stephan   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise

(2014) Michèle Soleilhavoup et al.   ACCOUNTS OF CHEMICAL RESEARCH

Activation of Small Molecules by Phosphorus Biradicaloids

(2014) Alexander Hinz et al.   CHEMISTRY-A EUROPEAN JOURNAL

New PN Cage Compounds Generated by Small-Molecule Activation

(2014) Alexander Hinz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Oxidizing Elemental Platinum with Oleum under Harsh Conditions: The Unique Tris(disulfato)platinate(IV) [Pt(S2O7)3]2−Anion

(2014) Jörn Bruns et al.   CHEMISTRY-A EUROPEAN JOURNAL

A New Class of Azadipnictiridines Generated by an Unusual Rearrangement Reaction

(2014) Alexander Hinz et al.   INORGANIC CHEMISTRY

On the Bonding Nature of Ozone (O3) and Its Sulfur-Substituted Analogues SO2, OS2, and S3: Correlation between Their Biradical Character and Molecular Properties

(2014) Evangelos Miliordos et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An overview of N-heterocyclic carbenes

(2014) Matthew N. Hopkinson et al.   NATURE

Electronic Structure of N2P2 Four-Membered Rings and the Effect of Their Ligand Coordination to M(CO)5 (Cr, Mo, and W)

(2014) Antonio Bauzá et al.   ORGANOMETALLICS

On The Steric Hindrance of Bulky Substituents - Determination of Their Cone Angles

(2014) Axel Schulz   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

An Arsenic-Nitrogen Biradicaloid: Synthesis, Properties, and Reactivity

(2013) Serhiy Demeshko et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diradicals

(2013) Manabu Abe   CHEMICAL REVIEWS

Exact ligand cone angles

(2013) Jenna A. Bilbrey et al.   JOURNAL OF COMPUTATIONAL CHEMISTRY

Metalloid Sn clusters: properties and the novel synthesis via a disproportionation reaction of a monohalide

(2013) Claudio Schrenk et al.   REVIEWS IN INORGANIC CHEMISTRY

Carbene-stabilized main group radicals and radical ions

(2013) Caleb D. Martin et al.   Chemical Science

Reactions with Oleum under Harsh Conditions: Characterization of the Unique [M(S2O7)3]2−Ions (M=Si, Ge, Sn) in A2[M(S2O7)3] (A=NH4, Ag)

(2012) Christian Logemann et al.   CHEMISTRY-A EUROPEAN JOURNAL

How big is a Cp? Cycloheptatrienyl zirconium complexes with bulky cyclopentadienyl and indenyl ligands

(2012) Andreas Glöckner et al.   DALTON TRANSACTIONS

Low melting mixtures in organic synthesis – an alternative to ionic liquids?

(2012) Carolin Ruß et al.   GREEN CHEMISTRY

Frustrated Lewis pairs: Some recent developments

(2012) Gerhard Erker   PURE AND APPLIED CHEMISTRY

[P(μ-NTer)]2: A Biradicaloid That Is Stable at High Temperature

(2011) Torsten Beweries et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ionic Liquids: New Perspectives for Inorganic Synthesis?

(2011) Dominic Freudenmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Homo- and heteroatomic polycations of groups 15 and 16. Recent advances in synthesis and isolation using room temperature ionic liquids

(2011) Ejaz Ahmed et al.   COORDINATION CHEMISTRY REVIEWS

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium

(2010) Roland C. Fischer et al.   CHEMICAL REVIEWS

Molecular complexes formed by halides of group 4,5,13–15 elements and the thermodynamic characteristics of their vaporization and dissociation found by the static tensimetric method

(2010) E.I. Davydova et al.   COORDINATION CHEMISTRY REVIEWS

meta-Terphenyl Phosphaalkenes Bearing Electron-Donating and -Accepting Groups

(2010) Vittal B. Gudimetla et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

N-heterocyclic carbenes which readily add ammonia, carbon monoxide and other small molecules,

(2010) Ulrich Siemeling et al.   Chemical Science

Stable singlet carbenes as mimics for transition metal centers

(2010) David Martin et al.   Chemical Science

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beyond ConventionalN-Heterocyclic Carbenes: Abnormal, Remote, and Other Classes of NHC Ligands with Reduced Heteroatom Stabilization

(2009) Oliver Schuster et al.   CHEMICAL REVIEWS

Molecular Double-Bond Covalent Radii for Elements Li–E112

(2009) Pekka Pyykkö et al.   CHEMISTRY-A EUROPEAN JOURNAL

Frustrated Lewis pairs: a new strategy to small molecule activation and hydrogenation catalysis

(2009) Douglas W. Stephan   DALTON TRANSACTIONS

The Extension of the Solid-Angle Concept to Bidentate Ligands

(2009) Tobias Niksch et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Consistent van der Waals Radii for the Whole Main Group

(2009) Manjeera Mantina et al.   JOURNAL OF PHYSICAL CHEMISTRY A