Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

N-Heterocyclic Carbenes as Efficient Organocatalysts for CO2Fixation Reactions

(2009) Yoshihito Kayaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Conversion of Carbon Dioxide into Methanol with Silanes over N-Heterocyclic Carbene Catalysts

(2009) Siti Nurhanna Riduan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Active Dizinc Catalyst for the Copolymerization of Carbon Dioxide and Cyclohexene Oxide at One Atmosphere Pressure

(2009) Michael R. Kember et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reversible Metal-Free Carbon Dioxide Binding by Frustrated Lewis Pairs

(2009) Cornelia M. Mömming et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of H2 by frustrated Lewis pairs derived from mono- and bis-phosphinoferrocenes and B(C6F5)3

(2009) Alberto Ramos et al.   CHEMICAL COMMUNICATIONS

Insertion into dihydrogen employing the nitrogen centre of a borylnitrene

(2009) Holger F. Bettinger et al.   CHEMICAL COMMUNICATIONS

On the Possibility of Conversion of Alcohols to Ketones and Aldehydes by Phosphinoboranes R2PBR′R′′: A Computational Study

(2009) Timofei Privalov   CHEMISTRY-A EUROPEAN JOURNAL

Hydrogenation of imines by phosphonium borate zwitterions: a theoretical study

(2009) Timofei Privalov   DALTON TRANSACTIONS

Metal-free dihydrogen activation chemistry: structural and dynamic features of intramolecular P/B pairs

(2009) Patrick Spies et al.   DALTON TRANSACTIONS

Reactions of phosphines with electron deficient boranes

(2009) Gregory C. Welch et al.   DALTON TRANSACTIONS

Frustrated Lewis pairs: a new strategy to small molecule activation and hydrogenation catalysis

(2009) Douglas W. Stephan   DALTON TRANSACTIONS

Betaine Adducts of N-Heterocyclic Carbenes: Synthesis, Properties, and Reactivity

(2009) Lionel Delaude   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Influence of Lewis Acid and Solvent in the Hydrosilylation of Aldehydes and Ketones with Et3SiH; Tris(pentafluorophenyl)borane B(C6F5)3 versus Metal Triflates [M(OTf)3; M = Sc, Bi, Ga, and Al] - Mechanistic Implications

(2009) Peter Bach et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Experimental and theoretical treatment of hydrogen splitting and storage in boron–nitrogen systems

(2009) Victor Sumerin et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Terminal Alkyne Activation by Frustrated and Classical Lewis Acid/Phosphine Pairs

(2009) Meghan A. Dureen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Hydrogenation of Sensitive Organometallic Compounds by Antagonistic N/B Lewis Pair Catalyst Systems

(2009) Kirill V. Axenov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the Mechanism of B(C6F5)3-Catalyzed Direct Hydrogenation of Imines: Inherent and Thermally Induced Frustration

(2009) Tibor András Rokob et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lutidine/B(C6F5)3: At the Boundary of Classical and Frustrated Lewis Pair Reactivity

(2009) Stephen J. Geier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rationalizing the Reactivity of Frustrated Lewis Pairs: Thermodynamics of H2Activation and the Role of Acid−Base Properties

(2009) Tibor András Rokob et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactions of an Intramolecular Frustrated Lewis Pair with Unsaturated Substrates: Evidence for a Concerted Olefin Addition Reaction

(2009) Cornelia M. Mömming et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Computational Studies of Pericyclic Reactions between Aminoalanes and Ethyne, Ethene, and Dienes. A Reactive Aminoalane That Should Prefer [2 + 2] and [4 + 2] Cyclizations to Dimerization

(2009) John M. Bailey et al.   ORGANOMETALLICS

Asymmetric transfer hydrogenation in aqueous media catalyzed by resin-supported peptide having a polyleucine tether

(2009) Kengo Akagawa et al.   TETRAHEDRON-ASYMMETRY

Metal-Free Conversion of Methane and Cycloalkanes to Amines and Amides by Employing a Borylnitrene

(2008) Holger F. Bettinger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Insertion of Carbon Dioxide into Main-Group Complexes: Formation of the [N(CO2)3]3−Ligand

(2008) Diane A. Dickie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Conclusive Evidence for an SN2-Si Mechanism in the B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Compounds: Implications for the Related Hydrogenation

(2008) Sebastian Rendler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Turning Frustration into Bond Activation: A Theoretical Mechanistic Study on Heterolytic Hydrogen Splitting by Frustrated Lewis Pairs

(2008) Tibor András Rokob et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Facile Heterolytic H2Activation by Amines and B(C6F5)3

(2008) Victor Sumerin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen and Amine Activation by a Frustrated Lewis Pair of a Bulky N-Heterocyclic Carbene and B(C6F5)3

(2008) Preston A. Chase et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterolytic Dihydrogen Activation by a Frustrated Carbene-Borane Lewis Pair

(2008) Dirk Holschumacher et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Catalytic Hydrogenation of Enamines, Imines, and Conjugated Phosphinoalkenylboranes

(2008) Patrick Spies et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Early Main-Group Metal Catalysts for the Hydrogenation of Alkenes with H2

(2008) Jan Spielmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Do Special Noncovalent π–π Stacking Interactions Really Exist?

(2008) Stefan Grimme   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tracking reactive intermediates in phosphine-promoted reactions with ambiphilic phosphino-boranes

(2008) Sylvie Moebs-Sanchez et al.   CHEMICAL COMMUNICATIONS

Concerted attack of frustrated Lewis acid–base pairs on olefinic double bonds: a theoretical study

(2008) András Stirling et al.   CHEMICAL COMMUNICATIONS

B–H Activation by frustrated Lewis pairs: borenium or boryl phosphonium cation?

(2008) Meghan A. Dureen et al.   CHEMICAL COMMUNICATIONS

Lewis acid-catalyzed hydrogenation: B(C6F5)3-mediated reduction of imines and nitriles with H2

(2008) Preston A. Chase et al.   CHEMICAL COMMUNICATIONS

Heterolytic dihydrogen activation with the 1,8-bis(diphenylphosphino)naphthalene/B(C6F5)3 pair and its application for metal-free catalytic hydrogenation of silyl enol ethers

(2008) Huadong Wang et al.   CHEMICAL COMMUNICATIONS

Metal-free catalytic hydrogenation of imines with tris(perfluorophenyl)borane

(2008) Dianjun Chen et al.   CHEMICAL COMMUNICATIONS

B–N compounds for chemical hydrogenstorage

(2008) Charles W. Hamilton et al.   CHEMICAL SOCIETY REVIEWS

Aqua-aminoorganoboron Catalyst: Engineering Single Water Molecule to Act as an Acid Catalyst in Nitro Aldol Reaction

(2008) Junichi Yoshimoto et al.   CHEMISTRY LETTERS

Nonpolar Dihydrogen Bonds-On a Gliding Scale from Weak Dihydrogen Interaction to Covalent HH in Symmetric Radical Cations [HnE-H-H-EHn]+

(2008) Andreas Krapp et al.   CHEMISTRY-A EUROPEAN JOURNAL

Phosphoric Acid Catalyzed Enantioselective Transfer Hydrogenation of Imines: A Density Functional Theory Study of Reaction Mechanism and the Origins of Enantioselectivity

(2008) Tommaso Marcelli et al.   CHEMISTRY-A EUROPEAN JOURNAL

Multidentate ligand systems featuring dual functionality

(2008) Istemi Kuzu et al.   DALTON TRANSACTIONS

A Novel Addition Mechanism for the Reaction of “Frustrated Lewis Pairs” with Olefins

(2008) Yong Guo et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Coordination Chemistry of Neutral (Ln)-Z Amphoteric and Ambiphilic Ligands

(2008) Frédéric-Georges Fontaine et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Unusual Concerted Lewis Acid−Lewis Base Mechanism for Hydrogen Activation by a Phosphine−Borane Compound

(2008) Yong Guo et al.   INORGANIC CHEMISTRY

CO2Adducts ofN-Heterocyclic Carbenes: Thermal Stability and Catalytic Activity toward the Coupling of CO2with Epoxides

(2008) Hui Zhou et al.   JOURNAL OF ORGANIC CHEMISTRY

Theoretical Study of the Mechanism of Hantzsch Ester Hydrogenation of Imines Catalyzed by Chiral BINOL-Phosphoric Acids

(2008) Luis Simón et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diarylstannylene Activation of Hydrogen or Ammonia with Arene Elimination

(2008) Yang Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Molecular Tweezers for Hydrogen: Synthesis, Characterization, and Reactivity

(2008) Victor Sumerin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of H2by Phosphinoboranes R2PB(C6F5)2

(2008) Stephen J. Geier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible, Metal-Free, Heterolytic Activation of H2at Room Temperature

(2008) Matthias Ullrich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

“Frustrated Lewis pairs”: a concept for new reactivity and catalysis

(2008) Douglas W. Stephan   ORGANIC & BIOMOLECULAR CHEMISTRY

Asymmetric reduction of ketimines with trichlorosilane employing an imidazole derived organocatalyst

(2008) François-Moana Gautier et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Heterolytic Cleavage of Dihydrogen by Frustrated Lewis Pairs Derived from α-(Dimesitylphosphino)ferrocenes and B(C6F5)3†

(2008) Dominique P. Huber et al.   ORGANOMETALLICS

A Zwitterionic Gold(I) Complex from an Ambiphilic Diphosphino−Alane Ligand

(2008) Marie Sircoglou et al.   ORGANOMETALLICS

Synthesis and Reactivity of Ruthenium Arene Complexes Incorporating Novel Ph2PCH2CH2BR2Ligands. Easy Access to the Four-Membered Ruthenacycle [(p-cymene)RuCl(κC,P-CH2CH2PPh2)]

(2008) Jérôme Vergnaud et al.   ORGANOMETALLICS

Bimetallic Calcium and Zinc Complexes with Bridged β-Diketiminate Ligands: Investigations on Epoxide/CO2Copolymerization

(2008) Dirk F.-J. Piesik et al.   ORGANOMETALLICS

β-Phosphinoethylboranes as Ambiphilic Ligands in Nickel−Methyl Complexes

(2008) Andreas Fischbach et al.   ORGANOMETALLICS

Ambiphilic Diphosphine–Borane Ligands: Metal→Borane Interactions within Isoelectronic Complexes of Rhodium, Platinum and Palladium

(2007) Sébastien Bontemps et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthetic, spectroscopic and structural studies of two novel phosphanyl(organyl)borane compounds

(2007) Sonia G. Thangavelu et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Functionalized Alkali Metal Cyclopentadienides: Structural and Chemical Features†

(2007) Gerhard Erker et al.   ORGANOMETALLICS