Stable singlet carbenes as mimics for transition metal centers

An isolable dialkylsilylene and its derivatives. A step toward comprehension of heavy unsaturated bonds

(2010) Mitsuo Kira   CHEMICAL COMMUNICATIONS

Ammonia N–H activation by a N,N′-diamidocarbene

(2010) Todd W. Hudnall et al.   CHEMICAL COMMUNICATIONS

Early-Transition-Metal-Mediated Activation and Transformation of White Phosphorus

(2010) Brandi M. Cossairt et al.   CHEMICAL REVIEWS

P4Activation by Late-Transition Metal Complexes†‡

(2010) Maria Caporali et al.   CHEMICAL REVIEWS

π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium

(2010) Roland C. Fischer et al.   CHEMICAL REVIEWS

P4Activation by Main Group Elements and Compounds

(2010) Manfred Scheer et al.   CHEMICAL REVIEWS

Advances in selective activation and application of ammonia in homogeneous catalysis

(2010) Jarl Ivar van der Vlugt   CHEMICAL SOCIETY REVIEWS

Steering S−H and N−H Bond Activation by a Stable N-Heterocyclic Silylene: Different Addition of H2S, NH3, and Organoamines on a Silicon(II) Ligand versus Its Si(II)→Ni(CO)3Complex

(2010) Antje Meltzer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

EPR Studies of the Generation, Structure, and Reactivity of N-Heterocyclic Carbene Borane Radicals

(2010) John C. Walton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Crystalline Phosphinyl Radical Cation

(2010) Olivier Back et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbenes−Borane Complexes: A New Class of Initiators for Radical Photopolymerization

(2010) Mohamad-Ali Tehfe et al.   MACROMOLECULES

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

Isolation of crystalline carbene-stabilized P2-radical cations and P2-dications

(2010) Olivier Back et al.   Nature Chemistry

P-Heterocyclic carbenes as effective catalysts for the activation of single and multiple bonds. A theoretical study

(2010) Markus Rullich et al.   NEW JOURNAL OF CHEMISTRY

Estimated Rate Constants for Hydrogen Abstraction from N-Heterocyclic Carbene−Borane Complexes by an Alkyl Radical†

(2010) Andrey Solovyev et al.   ORGANIC LETTERS

Radical Deoxygenation of Xanthates and Related Functional Groups with New Minimalist N-Heterocyclic Carbene Boranes

(2010) Shau-Hua Ueng et al.   ORGANIC LETTERS

Nonmetal-Mediated Fragmentation of P4: Isolation of P1and P2Bis(carbene) Adducts

(2009) Olivier Back et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Complexed Triphosphaallyl Radical, Cation, and Anion Family

(2009) Manfred Scheer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Are Allenes with Zwitterionic Character Still Allenes? Of Course!

(2009) Vincent Lavallo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Ligand Properties of a Persistent, All-Carbon Four-Membered-Ring Allene

(2009) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Addition of Hydrogen or Ammonia to a Low-Valent Group 13 Metal Species at 25 °C and 1 Atmosphere

(2009) Zhongliang Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Spirocyclic boronium ions: precursors to persistent neutral radicals

(2009) Thomas K. Wood et al.   CHEMICAL COMMUNICATIONS

Insertion into dihydrogen employing the nitrogen centre of a borylnitrene

(2009) Holger F. Bettinger et al.   CHEMICAL COMMUNICATIONS

Carbenes Introduction

(2009) Anthony J. Arduengo et al.   CHEMICAL REVIEWS

Do Extremely Bent Allenes Exist?

(2009) Mikko M. Hänninen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Divalent Silicon(0) Compounds

(2009) Nozomi Takagi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Divalent E(0) Compounds (E=Si-Sn)

(2009) Nozomi Takagi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carbene Stabilization of Diarsenic: From Hypervalency to Allotropy

(2009) Mariham Y. Abraham et al.   CHEMISTRY-A EUROPEAN JOURNAL

Frustrated Lewis pairs: a new strategy to small molecule activation and hydrogenation catalysis

(2009) Douglas W. Stephan   DALTON TRANSACTIONS

Dehydrogenation reactivity of a frustrated carbene–borane Lewis pair

(2009) Dirk Holschumacher et al.   DALTON TRANSACTIONS

Frustrated Lewis pairs derived from N-heterocyclic carbenes and Lewis acids

(2009) Preston A. Chase et al.   DALTON TRANSACTIONS

Carbodiphosphorane C(PPh3)2as a Single and Twofold Lewis Base with Boranes: Synthesis, Crystal Structures and Theoretical Studies on [H3B{C(PPh3)2}] and [{(μ-H)H4B2}{C(PPh3)2}]+

(2009) Wolfgang Petz et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cleavage of a N−H Bond of Ammonia at Room Temperature by a Germylene

(2009) Anukul Jana et al.   INORGANIC CHEMISTRY

Silylenes and germylenes: The activation of H–H bond in hydrogen molecule

(2009) Yong Wang et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Chemical Bonding in Silicon−Carbene Complexes

(2009) Z. Liu   JOURNAL OF PHYSICAL CHEMISTRY A

Effect of Lewis base coordination on boryl radical reactivity: investigation using laser flash photolysis and kinetic ESR

(2009) Jacques Lalevée et al.   JOURNAL OF PHYSICAL ORGANIC CHEMISTRY

Preparation of the [(DippNP)2(P4)2]2+-Dication by the Reaction of [DippNPCl]2and a Lewis Acid with P4

(2009) Michael H. Holthausen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Unusual Bonding in Trisilaallene and Related Heavy Allenes

(2009) Mitsuo Kira et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbene Boryl Radicals: A New Class of Boron-Centered Radical

(2009) Shau-Hua Ueng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative Addition of Ammonia at a Silicon(II) Center and an Unprecedented Hydrogenation Reaction of Compounds with Low-Valent Group 14 Elements Using Ammonia Borane

(2009) Anukul Jana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Exocyclic Delocalization at the Expense of Aromaticity in 3,5-bis(π-Donor) Substituted Pyrazolium Ions and Corresponding Cyclic Bent Allenes†

(2009) Israel Fernández et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of a Simplified Version of Stable Bulky and Rigid Cyclic (Alkyl)(amino)carbenes, and Catalytic Activity of the Ensuing Gold(I) Complex in the Three-Component Preparation of 1,2-Dihydroquinoline Derivatives

(2009) Xiaoming Zeng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Room-Temperature Reaction of Carbon Monoxide with a Stable Diarylgermylene

(2009) Xinping Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Nonmetal Catalyst for Molecular Hydrogen Activation with Comparable Catalytic Hydrogenation Capability to Noble Metal Catalyst

(2009) Baojun Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction of Hydrogen or Ammonia with Unsaturated Germanium or Tin Molecules under Ambient Conditions: Oxidative Addition versus Arene Elimination

(2009) Yang Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

AnN,N′-Diamidocarbene: Studies in C−H Insertion, Reversible Carbonylation, and Transition-Metal Coordination Chemistry

(2009) Todd W. Hudnall et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Coordination chemistry at carbon

(2009) Manuel Alcarazo et al.   Nature Chemistry

Rethinking carbon

(2009) C. Adam Dyker et al.   Nature Chemistry

Activation of P4by Singlet Silylene (SiH2): A Computational Study

(2009) Robert Damrauer et al.   ORGANOMETALLICS

Tolman’s Electronic Parameters for Divalent Carbon(0) Compounds

(2009) Ralf Tonner et al.   ORGANOMETALLICS

A Borenium Cation Stabilized by an N-Heterocyclic Carbene Ligand

(2009) Takeshi Matsumoto et al.   ORGANOMETALLICS

Autocatalytic degradation of white phosphorus with silylenes

(2009) Wolfgang W. Schoeller   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Carbenes As Catalysts for Transformations of Organometallic Iron Complexes

(2009) V. Lavallo et al.   SCIENCE

Facile Synthesis of AsP3

(2009) B. M. Cossairt et al.   SCIENCE

Carbodicarbenes: Divalent Carbon(0) Compounds

(2008) Oliver Kaufhold et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Niobium-Mediated Cycle Producing Phosphorus-Rich Organic Molecules from White Phosphorus (P4) through Activation, Functionalization, and Transfer Reactions

(2008) Brandi M. Cossairt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Ligand Properties of Stable Five‐Membered‐Ring Allenes Containing Only Second‐Row Elements

(2008) Vincent Lavallo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Coordination Chemistry of Ene-1,1-diamines and a Prototype “Carbodicarbene”

(2008) Alois Fürstner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of an Extremely Bent Acyclic Allene (A “Carbodicarbene”): A Strong Donor Ligand

(2008) C. Adam Dyker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen and Amine Activation by a Frustrated Lewis Pair of a Bulky N-Heterocyclic Carbene and B(C6F5)3

(2008) Preston A. Chase et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterolytic Dihydrogen Activation by a Frustrated Carbene-Borane Lewis Pair

(2008) Dirk Holschumacher et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Addition of H2 to distannynes under ambient conditions

(2008) Yang Peng et al.   CHEMICAL COMMUNICATIONS

Divalent Carbon(0) Chemistry, Part 1: Parent Compounds

(2008) Ralf Tonner et al.   CHEMISTRY-A EUROPEAN JOURNAL

Divalent Carbon(0) Chemistry, Part 2: Protonation and Complexes with Main Group and Transition Metal Lewis Acids

(2008) Ralf Tonner et al.   CHEMISTRY-A EUROPEAN JOURNAL

First and Second Proton Affinities of Carbon Bases

(2008) Ralf Tonner et al.   CHEMPHYSCHEM

P2Addition to Terminal Phosphide MP Triple Bonds: A Rational Synthesis ofcyclo-P3Complexes

(2008) Nicholas A. Piro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Complexes of Borane and N-Heterocyclic Carbenes: A New Class of Radical Hydrogen Atom Donor

(2008) Shau-Hua Ueng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diarylstannylene Activation of Hydrogen or Ammonia with Arene Elimination

(2008) Yang Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbene-Stabilized Diphosphorus

(2008) Yuzhong Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Singlet and Triplet Methylene (CH2) Plus P4: A Computational Study

(2008) Robert Damrauer et al.   ORGANOMETALLICS

CHEMISTRY: Soluble Allotropes of Main-Group Elements

(2008) C. A. Dyker et al.   SCIENCE

A Stable Silicon(0) Compound with a Si=Si Double Bond

(2008) Y. Wang et al.   SCIENCE

Making Stable Radicals of Heavy Elements of Groups 14 and 13: The Might of Silyl Substitution

(2007) Vladimir Ya. Lee et al.   CHEMISTRY LETTERS