[RhIII(Cp*)]-Catalyzedortho-Selective Direct C(sp2)H Bond Amidation/Amination of Benzoic Acids byN-Chlorocarbamates andN-Chloromorpholines. A Versatile Synthesis of Functionalized Anthranilic Acids

Rhodium(III)-Catalyzed C(sp2)H Activation and Electrophilic Amidation withN-Fluorobenzenesulfonimide

(2013) Ren-Jin Tang et al.   ADVANCED SYNTHESIS & CATALYSIS

Directed Amination of Non-Acidic Arene CH Bonds by a Copper-Silver Catalytic System

(2013) Ly Dieu Tran et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct CH Amination of Arenes with Alkyl Azides under Rhodium Catalysis

(2013) Kwangmin Shin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Azidation and Nitration of Arenes by CH Activation

(2013) Fang Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed oxidative direct C–H/C–H cross coupling of anilides with β-keto esters

(2013) Wai-Wing Chan et al.   CHEMICAL COMMUNICATIONS

Ru(ii)-catalyzed intermolecular C–H amidation of weakly coordinating ketones

(2013) Qing-Zhong Zheng et al.   CHEMICAL COMMUNICATIONS

Ru(ii)-catalyzed intermolecular ortho-C–H amidation of aromatic ketones with sulfonyl azides

(2013) M. Bhanuchandra et al.   CHEMICAL COMMUNICATIONS

[Cp*RhCl2]2-catalyzed ortho-C–H bond amination of acetophenone o-methyloximes with primary N-chloroalkylamines: convenient synthesis of N-alkyl-2-acylanilines

(2013) Ka-Ho Ng et al.   CHEMICAL COMMUNICATIONS

C–H nitrogenation and oxygenation by ruthenium catalysis

(2013) Vedhagiri S. Thirunavukkarasu et al.   CHEMICAL COMMUNICATIONS

Ruthenium-Catalyzed Direct CH Amidation of Arenes Including Weakly Coordinating Aromatic Ketones

(2013) Jiyu Kim et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed C3-Selective Alkenylation of Substituted Thiophene-2-carboxylic Acids and Related Compounds

(2013) Tomonori Iitsuka et al.   JOURNAL OF ORGANIC CHEMISTRY

Sterically Controlled, Palladium-Catalyzed Intermolecular Amination of Arenes

(2013) Ruja Shrestha et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ir(III)-Catalyzed Mild C–H Amidation of Arenes and Alkenes: An Efficient Usage of Acyl Azides as the Nitrogen Source

(2013) Jaeyune Ryu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Aryl C–H Imidation with Arene as the Limiting Reagent

(2013) Gregory B. Boursalian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile Synthesis of Unsymmetrical Acridines and Phenazines by a Rh(III)-Catalyzed Amination/Cyclization/Aromatization Cascade

(2013) Yajing Lian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

RhIII/CuII-Cocatalyzed Synthesis of 1H-Indazoles through C–H Amidation and N–N Bond Formation

(2013) Da-Gang Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium(II)-Catalyzed othro-C–H-Benzoxylation of 2-Arylpyridines by Oxidative Coupling with Aryl Acylperoxides

(2013) Wing-Nga Sit et al.   MOLECULES

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

Ortho- and Para-Selective Ruthenium-Catalyzed C(sp2)–H Oxygenations of Phenol Derivatives

(2013) Weiping Liu et al.   ORGANIC LETTERS

Expedient C–H Amidations of Heteroaryl Arenes Catalyzed by Versatile Ruthenium(II) Catalysts

(2013) Vedhagiri S. Thirunavukkarasu et al.   ORGANIC LETTERS

Sulfoximine Directed Intermolecular o-C–H Amidation of Arenes with Sulfonyl Azides

(2013) M. Ramu Yadav et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed C–H Activation and Amidation of Arenes Using N-Arenesulfonated Imides as Amidating Reagents

(2013) Songjie Yu et al.   ORGANIC LETTERS

Rh[III]-Catalyzed C–H Amidation Using Aroyloxycarbamates To Give N-Boc Protected Arylamines

(2013) Christoph Grohmann et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Intermolecular N-Chelator-Directed Aromatic C–H Amidation with Amides

(2013) Huaiqing Zhao et al.   ORGANIC LETTERS

Controlling Site Selectivity in Palladium-Catalyzed C–H Bond Functionalization

(2012) Sharon R. Neufeldt et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Catalyzed Amidation by Chemoselective C(sp3)H Activation: Concise Route to Oxindoles Using a Carbamoyl Chloride Precursor

(2012) Chihiro Tsukano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Intermolecular C(sp3)H Amidation

(2012) Álvaro Iglesias et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Direct CH Amination of Benzamides with Aryl Azides: A Synthetic Route to Diarylamines

(2012) Jaeyune Ryu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

(2012) Nadine Kuhl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A convenient synthesis of anthranilic acids by Pd-catalyzed direct intermolecular ortho-C–H amidation of benzoic acids

(2012) Ka-Ho Ng et al.   CHEMICAL COMMUNICATIONS

Rhodium(iii)-catalyzed allylic C–H bond amination. Synthesis of cyclic amines from ω-unsaturated N-sulfonylamines

(2012) Thomas Cochet et al.   CHEMICAL COMMUNICATIONS

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Mechanism of the Rhodium(III)-Catalyzed Arylation of Imines via C–H Bond Functionalization: Inhibition by Substrate

(2012) Michael E. Tauchert et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Intermolecular Amidation of Arenes with Sulfonyl Azides via Chelation-Assisted C–H Bond Activation

(2012) Ji Young Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed C–H Azidation of Anilines under Mild Conditions

(2012) Conghui Tang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-Catalyzed Intermolecular Carbenoid Functionalization of Aromatic C–H Bonds by α-Diazomalonates

(2012) Wai-Wing Chan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-catalyzed regioselective amidation of indoles with sulfonyl azides via C–H bond activation

(2012) Jingjing Shi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Oxidative Alkenylation of Aromatic Esters by Ruthenium-Catalyzed Twofold C–H Bond Cleavages

(2012) Karolina Graczyk et al.   ORGANIC LETTERS

Copper-Catalyzed Electrophilic Amination of Arylsilanes with Hydroxylamines

(2012) Yuya Miki et al.   ORGANIC LETTERS

Ruthenium-Catalyzed C–H Bond Oxygenations with Weakly Coordinating Ketones

(2012) Vedhagiri S. Thirunavukkarasu et al.   ORGANIC LETTERS

Synthesis of highly substituted isocoumarins by rhodium-catalyzed annulation of readily available benzoic acids

(2012) Yuto Unoh et al.   TETRAHEDRON

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium(II)-Catalyzed Direct ortho-CH Acylation of Anilides by Oxidative Cross-Coupling with Aldehydes using tert-Butyl Hydroperoxide as Oxidant

(2011) Chun-Wo Chan et al.   ADVANCED SYNTHESIS & CATALYSIS

One-Pot Formation of CC and CN Bonds through Palladium-Catalyzed Dual CH Activation: Synthesis of Phenanthridinones

(2011) Guan-Wu Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation

(2011) Seung Hwan Cho et al.   CHEMICAL SOCIETY REVIEWS

The Scope of Ambiphilic Acetate-Assisted Cyclometallation with Half-Sandwich Complexes of Iridium, Rhodium and Ruthenium

(2011) Youcef Boutadla et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transition Metal-Catalyzed Formation of N-Heterocycles via Aryl- or Vinyl C-H Bond Amination

(2011) Benjamin J. Stokes et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Novel Inhibitors of NRH:Quinone Oxidoreductase 2 (NQO2): Crystal Structures, Biochemical Activity, and Intracellular Effects of Imidazoacridin-6-ones

(2011) Mark S. Dunstan et al.   JOURNAL OF MEDICINAL CHEMISTRY

Synthesis of Isochromene and Related Derivatives by Rhodium-Catalyzed Oxidative Coupling of Benzyl and Allyl Alcohols with Alkynes

(2011) Keisuke Morimoto et al.   JOURNAL OF ORGANIC CHEMISTRY

Computational Elucidation of the Internal Oxidant-Controlled Reaction Pathways in Rh(III)-Catalyzed Aromatic C–H Functionalization

(2011) Liang Xu et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Intermolecular Directed C−H Amidation of Aromatic Ketones

(2011) Bin Xiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heterocycle Synthesis via Direct C–H/N–H Coupling

(2011) Enrico T. Nadres et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Efficient Syntheses of Azetidines, Pyrrolidines, and Indolines via Palladium Catalyzed Intramolecular Amination of C(sp3)–H and C(sp2)–H Bonds at γ and δ Positions

(2011) Gang He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed C−H Aminations of Anilides withN-Fluorobenzenesulfonimide

(2011) Kai Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Intermolecular C–H Amination with Alkylamines

(2011) Eun Jeong Yoo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Oxidative C–H Bond Alkenylations in Water: Expedient Synthesis of Annulated Lactones

(2011) Lutz Ackermann et al.   ORGANIC LETTERS

Rhodium-Catalyzed Cross-Coupling Reaction of Arylboronates and Diazoesters and Tandem Alkylation Reaction for the Synthesis of Quaternary α,α-Heterodiaryl Carboxylic Esters

(2011) Yuk-Tai Tsoi et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Intermolecular Direct Amination of Aromatic C–H Bonds with N-Chloroamines

(2011) Ka-Ho Ng et al.   ORGANIC LETTERS

Rh[III]-Catalyzed Direct C–H Amination Using N-Chloroamines at Room Temperature

(2011) Christoph Grohmann et al.   ORGANIC LETTERS

Direct Azole Amination: CH Functionalization as a New Approach to Biologically Important Heterocycles

(2010) Alan Armstrong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of New Acridone Derivatives, Inhibitors of NS3 Helicase, Which Efficiently and Specifically Inhibit Subgenomic HCV Replication

(2010) Anna Stankiewicz-Drogoń et al.   JOURNAL OF MEDICINAL CHEMISTRY

Pd-Catalyzed Intermolecularortho-C−H Amidation of Anilides byN-Nosyloxycarbamate

(2010) Ka-Ho Ng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Amination of Aromatic C−H Bonds with Oxime Esters

(2010) Yichen Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Arene and Alkene C−H Bond Functionalization Leading to Indoles and Pyrroles

(2010) David R. Stuart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Expedient Drug Synthesis and Diversification via ortho-C−H Iodination using Recyclable PdI2as the Precatalyst

(2010) Tian-Sheng Mei et al.   ORGANIC LETTERS

Pd-CatalyzedOrtho-C−H Acylation/Cross Coupling of Aryl KetoneO-Methyl Oximes with Aldehydes Usingtert-Butyl Hydroperoxide as Oxidant

(2010) Chun-Wo Chan et al.   ORGANIC LETTERS

Palladium-Catalyzed Oxidative Cross-Coupling Reaction of Arylboronic Acids with Diazoesters for Stereoselective Synthesis of (E)-α,β-Diarylacrylates

(2010) Yuk-Tai Tsoi et al.   ORGANIC LETTERS

Transition-Metal-Free Electrophilic Amination between Aryl Grignard Reagents andN-Chloroamines

(2010) Takuji Hatakeyama et al.   ORGANIC LETTERS

Dialkylbiaryl phosphines in Pd-catalyzed amination: a user's guide

(2010) David S. Surry et al.   Chemical Science

Palladium-Catalyzed Amidation of Unactivated C(sp3)H Bonds: from Anilines to Indolines

(2009) Julia J. Neumann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic C–H amination: recent progress and future directions

(2009) Florence Collet et al.   CHEMICAL COMMUNICATIONS

Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity

(2009) Ramesh Giri et al.   CHEMICAL SOCIETY REVIEWS

Umpolung Amination: Nickel-Catalyzed Coupling Reactions ofN,N-Dialkyl-N-chloroamines with Diorganozinc Reagents

(2009) Timothy J. Barker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Amination of C−H Bonds Using Single-Electron or Two-electron Oxidants

(2009) Tian-Sheng Mei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Decarboxylative Arylation of C−H Bonds by Aryl Acylperoxides

(2009) Wing-Yiu Yu et al.   ORGANIC LETTERS

C−H Activation of Phenyl Imines and 2-Phenylpyridines with [Cp*MCl2]2(M = Ir, Rh): Regioselectivity, Kinetics, and Mechanism

(2009) Ling Li et al.   ORGANOMETALLICS

Evolution of a Fourth Generation Catalyst for the Amination and Thioetherification of Aryl Halides

(2008) John F. Hartwig   ACCOUNTS OF CHEMICAL RESEARCH

PdII‐Catalyzed MonoselectiveorthoHalogenation of CH Bonds Assisted by Counter Cations: A Complementary Method to Directedortho Lithiation

(2008) Tian‐Sheng Mei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of β-, γ-, and δ-Lactams via Pd(II)-Catalyzed C−H Activation Reactions

(2008) Masayuki Wasa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative Pd(II)-Catalyzed C−H Bond Amination to Carbazole at Ambient Temperature

(2008) James A. Jordan-Hore et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Oxidative Ethoxycarbonylation of Aromatic C−H Bond with Diethyl Azodicarboxylate

(2008) Wing-Yiu Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of 1,2- and 1,3-Dicarboxylic Acids via Pd(II)-Catalyzed Carboxylation of Aryl and Vinyl C−H Bonds

(2008) Ramesh Giri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Cross Coupling Reaction of Benzyl Bromides with Diazoesters for Stereoselective Synthesis of (E)-α,β-Diarylacrylates

(2008) Wing-Yiu Yu et al.   ORGANIC LETTERS

Toward a Synthetically Useful Stereoselective C−H Amination of Hydrocarbons

(2007) Chungen Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY