Selective Boryl-Anion Migration in a Vinyl sp2 −sp3 Diborane Induced by Soft Borane Lewis Acids

Synthesis of Unsymmetrical Diboranes by Diborane Metathesis

(2018) Anne-Frédérique Pécharman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diborane heterolysis: breaking and making B–B bonds at magnesium

(2018) Anne-Frédérique Pécharman et al.   DALTON TRANSACTIONS

gem-Diborylalkanes: recent advances in their preparation, transformation and application

(2018) Rajender Nallagonda et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Base-controlled highly selective synthesis of alkyl 1,2-bis(boronates) or 1,1,2-tris(boronates) from terminal alkynes

(2017) Guoliang Gao et al.   GREEN CHEMISTRY

Tris(pentafluorophenyl)borane and Beyond: Modern Advances in Borylation Chemistry

(2017) James R. Lawson et al.   INORGANIC CHEMISTRY

Transition-metal-free synthesis of 1,1-diboronate esters with a fully substituted benzylic center via diborylation of lithiated carbamates

(2017) Haonan Zhao et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

50 Years of Zweifel Olefination: A Transition-Metal-Free Coupling

(2017) Varinder Aggarwal et al.   SYNTHESIS-STUTTGART

Synthesis and Reactivity of 1,1-Diborylalkanes towards C-C Bond Formation and Related Mechanisms

(2017) Núria Miralles et al.   ADVANCED SYNTHESIS & CATALYSIS

Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse

(2016) Emily C. Neeve et al.   CHEMICAL REVIEWS

Opportunegem-Silylborylation of Carbonyl Compounds: A Modular and Stereocontrolled Entry to Tetrasubstituted Olefins

(2016) Enrico La Cascia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct and Base-Catalyzed Diboration of Alkynes Using the Unsymmetrical Diborane(4), pinB-BMes2

(2016) Chiemi Kojima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of 1,1-Diborylalkenes through a Brønsted Base Catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron

(2015) Akira Morinaga et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Application of a nucleophilic boryl complex in the frustrated Lewis pair: activation of H–H, B–H and CC bonds with B(C6F5)3 and boryl–borate lithium

(2015) Junhao Zheng et al.   CHEMICAL COMMUNICATIONS

sp2–sp3 diboranes: astounding structural variability and mild sources of nucleophilic boron for organic synthesis

(2015) Rian D. Dewhurst et al.   CHEMICAL COMMUNICATIONS

Synthesis, Structure, and Reactivity of Anionic sp2-sp3Diboron Compounds: Readily Accessible Boryl Nucleophiles

(2015) Sabrina Pietsch et al.   CHEMISTRY-A EUROPEAN JOURNAL

Trans-Diborylation of Alkynes: Pseudo-Intramolecular Strategy Utilizing a Propargylic Alcohol Unit

(2014) Yuki Nagashima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Simple Access to Elusive α-Boryl Carbanions and Their Alkylation: An Umpolung Construction for Organic Synthesis

(2014) Kai Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiomerically Enriched Tris(boronates): Readily Accessible Conjunctive Reagents for Asymmetric Synthesis

(2014) John R. Coombs et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroxyl-Directed Stereoselective Diboration of Alkenes

(2014) Thomas P. Blaisdell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Borylation of Alkyl, Allyl, and Aryl Halides: Isolation of an Iron(I) Boryl Complex

(2014) Robin B. Bedford et al.   ORGANOMETALLICS

Formal Carbon Insertion of N-Tosylhydrazone into B–B and B–Si Bonds: gem-Diborylation and gem-Silylborylation of sp3 Carbon

(2013) Huan Li et al.   ORGANIC LETTERS

Metal-Free Catalytic Enantioselective C–B Bond Formation: (Pinacolato)boron Conjugate Additions to α,β-Unsaturated Ketones, Esters, Weinreb Amides, and Aldehydes Promoted by Chiral N-Heterocyclic Carbenes

(2012) Hao Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-Metal-Free Diboration Reaction by Activation of Diboron Compounds with Simple Lewis Bases

(2011) Amadeu Bonet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Construction of Quaternary Stereogenic Centers from Tertiary Boronic Esters: Methodology and Applications

(2011) Ravindra P. Sonawane et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Spectroscopic and Structural Characterization of the CyNHC Adduct of B2pin2 in Solution and in the Solid State

(2011) Christian Kleeberg et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereospecific Cross-Coupling between Alkenylboronates and Alkyl Halides Catalyzed by Iron–Bisphosphine Complexes

(2011) Toru Hashimoto et al.   JOURNAL OF ORGANIC CHEMISTRY

Metal-Free Catalytic Boration at the β-Position of α,β-Unsaturated Compounds: A Challenging Asymmetric Induction

(2010) Amadeu Bonet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient C−B Bond Formation Promoted by N-Heterocyclic Carbenes: Synthesis of Tertiary and Quaternary B-Substituted Carbons through Metal-Free Catalytic Boron Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls

(2009) Kang-sang Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY