Transition-Metal-Free Synthesis of Pinacol Alkylboronates from Tosylhydrazones

Transition-Metal-Free Intramolecular Ullmann-Type O-Arylation: Synthesis of Chromone Derivatives

(2011) Jie Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic, Oxidative, Intramolecular CH Bond Amination and Metal-free Cross-Amination of Unactivated Arenes at Ambient Temperature

(2011) Andrey P. Antonchick et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkylboronic Esters from Copper-Catalyzed Borylation of Primary and Secondary Alkyl Halides and Pseudohalides

(2011) Chu-Ting Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mizoroki-Heck-Type Reaction Mediated by Potassium tert-Butoxide

(2011) Eiji Shirakawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tosylhydrazones: New Uses for Classic Reagents in Palladium-Catalyzed Cross-Coupling and Metal-Free Reactions

(2011) José Barluenga et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cross-Coupling Reactions Of Organoboranes: An Easy Way To Construct CC Bonds (Nobel Lecture)

(2011) Akira Suzuki   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Suzuki–Miyaura cross-couplings of secondary allylic boronic esters

(2011) Ben W. Glasspoole et al.   CHEMICAL COMMUNICATIONS

Transmetalation of Unsaturated Carbon Nucleophiles from Boron-Containing Species to the Mid to Late d-Block Metals of Relevance to Catalytic C−X Coupling Reactions (X = C, F, N, O, Pb, S, Se, Te)

(2011) David V. Partyka   CHEMICAL REVIEWS

Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners

(2011) Ranjan Jana et al.   CHEMICAL REVIEWS

N-Tosylhydrazones: versatile reagents for metal-catalyzed and metal-free cross-coupling reactions

(2011) Zhihui Shao et al.   CHEMICAL SOCIETY REVIEWS

Direct Arylation of Alkenes with Aryl Iodides/Bromides through an Organocatalytic Radical Process

(2011) Chang-Liang Sun et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Developments in Pd-Catalyzed Reactions of Diazo Compounds

(2011) Yan Zhang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Room Temperature Aryl Trifluoromethylation via Copper-Mediated Oxidative Cross-Coupling

(2011) Todd D. Senecal et al.   JOURNAL OF ORGANIC CHEMISTRY

Intermolecular Oxidative C–N Bond Formation under Metal-Free Conditions: Control of Chemoselectivity between Aryl sp2and Benzylic sp3C–H Bond Imidation

(2011) Hyun Jin Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Intermolecular Oxidative C–N Bond Formation via Tandem C–H and N–H Bond Functionalization

(2011) Abhishek A. Kantak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Inversion or Retention? Effects of Acidic Additives on the Stereochemical Course in Enantiospecific Suzuki–Miyaura Coupling of α-(Acetylamino)benzylboronic Esters

(2011) Tomotsugu Awano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photochemically Promoted Transition Metal-Free Cross-Coupling of Acylsilanes with Organoboronic Esters

(2011) Kazuta Ito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective preparation and chemoselective cross-coupling of 1,1-diboron compounds

(2011) Jack Chang Hung Lee et al.   Nature Chemistry

Copper-Catalyzed Trifluoromethylation of Aryl and Vinyl Boronic Acids with An Electrophilic Trifluoromethylating Reagent

(2011) Tianfei Liu et al.   ORGANIC LETTERS

A Metal-Free Amination of Benzoxazoles – The First Example of an Iodide-Catalyzed Oxidative Amination of Heteroarenes

(2011) Tanja Froehr et al.   ORGANIC LETTERS

Straightforward Synthesis of Ethers: Metal-Free Reductive Coupling of Tosylhydrazones with Alcohols or Phenols

(2010) José Barluenga et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Catalytic Boration at the β-Position of α,β-Unsaturated Compounds: A Challenging Asymmetric Induction

(2010) Amadeu Bonet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Conversion of Arylamines to Pinacol Boronates: A Metal-Free Borylation Process

(2010) Fanyang Mo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From Noble Metal to Nobel Prize: Palladium-Catalyzed Coupling Reactions as Key Methods in Organic Synthesis

(2010) Xiao-Feng Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A General Rhodium-Catalyzed Cyanation of Aryl and Alkenyl Boronic Acids

(2010) Pazhamalai Anbarasan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

tert-Butoxide-Mediated Arylation of Benzene with Aryl Halides in the Presence of a Catalytic 1,10-Phenanthroline Derivative

(2010) Eiji Shirakawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalysis in Cross-Coupling: DMEDA-Catalyzed Direct C−H Arylation of Unactivated Benzene

(2010) Wei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereospecific Suzuki−Miyaura Coupling of Chiral α-(Acylamino)benzylboronic Esters with Inversion of Configuration

(2010) Toshimichi Ohmura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereospecific Cross-Coupling of Secondary Alkyl β-Trifluoroboratoamides

(2010) Deidre L. Sandrock et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Opportunity for Mg-Catalyzed Grignard-Type Reactions: Direct Coupling of Benzylic Halides with Pinacolborane with 10 mol % of Magnesium

(2010) Christine Pintaric et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cyanation of Arenes via Iridium-Catalyzed Borylation

(2010) Carl W. Liskey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Origins of the Selectivity for Borylation of Primary over Secondary C−H Bonds Catalyzed by Cp*-Rhodium Complexes

(2010) Carolyn S. Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An efficient organocatalytic method for constructing biaryls through aromatic C–H activation

(2010) Chang-Liang Sun et al.   Nature Chemistry

Synthesis of thioethers via metal-free reductive coupling of tosylhydrazones with thiols

(2010) Qiuping Ding et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper-Mediated Oxidative Trifluoromethylation of Boronic Acids

(2010) Lingling Chu et al.   ORGANIC LETTERS

Copper-Promoted Carbon-Heteroatom Bond Cross-Coupling with Boronic Acids and Derivatives

(2010) Jennifer Qiao et al.   SYNTHESIS-STUTTGART

Expanding the scope of transformations of organoboron species: carbon–carbon bond formation with retention of configuration

(2009) Cathleen M. Crudden et al.   CHEMICAL COMMUNICATIONS

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

Rhodium-Catalyzed Tandem Transformations with Organoboron Reagents: Sequential Multiple C-C Bond Formations

(2009) So Won Youn   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Cross Coupling Reactions of Chiral Secondary Organoboronic Esters With Retention of Configuration

(2009) Daisuke Imao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-free carbon–carbon bond-forming reductive coupling between boronic acids and tosylhydrazones

(2009) José Barluenga et al.   Nature Chemistry

Arylation and Vinylation of α-Diazocarbonyl Compounds with Boroxines

(2009) Cheng Peng et al.   ORGANIC LETTERS

Fluorination of Boronic Acids Mediated by Silver(I) Triflate

(2009) Takeru Furuya et al.   ORGANIC LETTERS

Metal-free electrophilic fluorination of alkyl trifluoroborates and boronic acids

(2009) Clément Cazorla et al.   TETRAHEDRON LETTERS

Palladium-Mediated Fluorination of Arylboronic Acids

(2008) Takeru Furuya et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Catalyzed Reactions of Organoboronic Acids and Esters

(2008) Norio Miyaura   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Suzuki–Miyaura Cross-Coupling Reactions of Alkylboronic Acid Derivatives or Alkyltrifluoroborates with Aryl, Alkenyl or Alkyl Halides and Triflates

(2008) Henri Doucet   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY