Mechanism, selectivity, and reactivity of iridium- and rhodium-catalyzed intermolecular ketone α-alkylation with unactivated olefins via an enamide directing strategy

Mechanism and origins of the directing group-controlled endo- versus exo-selectivity of iridium-catalysed intramolecular hydroalkenylation of 1,1-disubstituted alkenes

(2018) Yanmin Lang et al.   CHEMICAL COMMUNICATIONS

Mechanism and Origins of Regio- and Enantioselectivities of Iridium-Catalyzed Hydroarylation of Alkenyl Ethers

(2018) Mei Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

sp3 C–H activation via exo-type directing groups

(2018) Yan Xu et al.   Chemical Science

Transient Directing Groups for Transformative C–H Activation by Synergistic Metal Catalysis

(2018) Parthasarathy Gandeepan et al.   Chem

Catalytic Coupling between Unactivated Aliphatic C–H Bonds and Alkynes via a Metal–Hydride Pathway

(2017) Yan Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand–Substrate Dispersion Facilitates the Copper-Catalyzed Hydroamination of Unactivated Olefins

(2017) Gang Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Catalytic B–H Arylation of o-Carboranyl Aldehydes by a Transient Directing Strategy

(2017) Xiaolei Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Branched-Selective Intermolecular Ketone α-Alkylation with Unactivated Alkenes via an Enamide Directing Strategy

(2017) Dong Xing et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanisms and Origins of Chemo- and Regioselectivities of Ru(II)-Catalyzed Decarboxylative C–H Alkenylation of Aryl Carboxylic Acids with Alkynes: A Computational Study

(2017) Jing-Lu Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism and Stereoselectivity of the BINOL-Catalyzed Allylboration of Skatoles

(2017) Genping Huang et al.   ORGANIC LETTERS

Mechanism and Origin of Et2Al(OEt)-Induced Chemoselectivity of Nickel-Catalyzed Three-Component Coupling of One Diketene and Two Alkynes

(2017) Yuxia Liu et al.   ACS Catalysis

Comparative investigation of the reactivities between catalysts [Cp*RhCl2]2 and [Cp*IrCl2]2 in the oxidative annulation of isoquinolones with alkynes: a combined experimental and computational study

(2017) Chaoyue Zhao et al.   Organic Chemistry Frontiers

Mechanism and origins of selectivity in rhodium-catalyzed intermolecular [3 + 2] cycloadditions of vinylaziridines with allenes

(2017) Li Wang et al.   Organic Chemistry Frontiers

Elucidation of Mechanisms and Selectivities of Metal-Catalyzed Reactions using Quantum Chemical Methodology

(2016) Stefano Santoro et al.   ACCOUNTS OF CHEMICAL RESEARCH

Practical Direct α-Arylation of Cyclopentanones by Palladium/Enamine Cooperative Catalysis

(2016) Yan Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Buttressing Salicylaldehydes: A Multipurpose Directing Group for C(sp3)−H Bond Activation

(2016) Akira Yada et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Combinations of Aminocatalysts and Metal Catalysts: A Powerful Cooperative Approach in Selective Organic Synthesis

(2016) Samson Afewerki et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Transformations of Alkyl C–H Bonds

(2016) Jian He et al.   CHEMICAL REVIEWS

Transition-Metal-Catalyzed C–H Bond Addition to Carbonyls, Imines, and Related Polarized π Bonds

(2016) Joshua R. Hummel et al.   CHEMICAL REVIEWS

Branch Selective Murai-type Alkene Hydroarylation Reactions

(2016) Giacomo E. M. Crisenza et al.   CHEMISTRY LETTERS

Mechanism of Ligand-Controlled Regioselectivity-Switchable Copper-Catalyzed Alkylboration of Alkenes

(2016) Zheng-Yang Xu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanism and Selectivity of RuII- and RhIII-Catalyzed Oxidative Spiroannulation of Naphthols and Phenols with Alkynes through a C−H Activation/Dearomatization Strategy

(2016) Mei Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanism of iridium-catalysed branched-selective hydroarylation of vinyl ethers: a computational study

(2016) Mei Zhang et al.   DALTON TRANSACTIONS

Why is the Ir(III)-Mediated Amido Transfer Much Faster Than the Rh(III)-Mediated Reaction? A Combined Experimental and Computational Study

(2016) Yoonsu Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Alkylation of N-Sulfonylbenzamides with Vinyl Ethers via C–H Bond Activation Catalyzed by Hydroxoiridium/Chiral Diene Complexes

(2016) Miyuki Hatano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic activation of carbon–carbon bonds in cyclopentanones

(2016) Ying Xia et al.   NATURE

Advances in the development of catalytic tethering directing groups for C–H functionalization reactions

(2016) Huan Sun et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Functionalization of C(sp3)-H bonds using a transient directing group

(2016) F.-L. Zhang et al.   SCIENCE

Asymmetric Transformations under Iridium/Chiral Diene Catalysis

(2016) Midori Nagamoto et al.   ACS Catalysis

Mechanism and Origins of Ligand-Controlled Linear Versus Branched Selectivity of Iridium-Catalyzed Hydroarylation of Alkenes

(2016) Genping Huang et al.   ACS Catalysis

Very Important Publication: Iridium-Catalyzed Intramolecular Enantioselective CH Alkylation at the C-2 Position ofN-Alkenylindoles

(2015) Takanori Shibata et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Intramolecular Ketone Alkylation with Olefins by Dual Activation

(2015) Hee Nam Lim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Branch-Selective Alkene Hydroarylation by Cooperative Destabilization: Iridium-Catalyzedortho-Alkylation of Acetanilides

(2015) Giacomo E. M. Crisenza et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Catalyzed Direct Addition of Unactivated C–H Bonds to Polar Unsaturated Bonds

(2015) Lei Yang et al.   CHEMICAL REVIEWS

Transition metal-catalyzed C–H functionalization of N-oxyenamine internal oxidants

(2015) Huawen Huang et al.   CHEMICAL SOCIETY REVIEWS

Mechanism and Selectivity in Rhodium-Catalyzed [7 + 2] Cycloaddition and Cyclopropanation/Cyclization of Allenylcyclopentane-alkynes: Metallacycle-Directed C(sp3)-C(sp3) vs C(sp3)-H Activation

(2015) Genping Huang   JOURNAL OF ORGANIC CHEMISTRY

Mechanistic Insight into Ketone α-Alkylation with Unactivated Olefins via C–H Activation Promoted by Metal–Organic Cooperative Catalysis (MOCC): Enriching the MOCC Chemistry

(2015) Yanfeng Dang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bifunctional Ligand-Assisted Catalytic Ketone α-Alkenylation with Internal Alkynes: Controlled Synthesis of Enones and Mechanistic Studies

(2015) Fanyang Mo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Formal Dehydrative [4 + 2] Cycloaddition of Enamides and Alkynes for the Synthesis of Highly Substituted Pyridines: Reaction Development and Mechanistic Study

(2015) Jicheng Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed C–H Activation of Phenacyl Ammonium Salts Assisted by an Oxidizing C–N Bond: A Combination of Experimental and Theoretical Studies

(2015) Songjie Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Branch-Selective Hydroarylation of Vinyl Ethers via C–H Bond Activation

(2015) Yusuke Ebe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Rhodium-Catalyzed Cyclopropanation/Cyclization of Allenynes

(2015) Genping Huang   ORGANIC LETTERS

Mechanistic Understanding of the Aryl-Dependent Ring Formations in Rh(III)-Catalyzed C–H Activation/Cycloaddition of Benzamides and Methylenecyclopropanes by DFT Calculations

(2015) Wei Guo et al.   ORGANOMETALLICS

Mechanism, reactivity, and selectivity of the iridium-catalyzed C(sp3)–H borylation of chlorosilanes

(2015) Genping Huang et al.   Chemical Science

Carbon–hydrogen (C–H) bond activation at PdIV: a Frontier in C–H functionalization catalysis

(2015) Joseph J. Topczewski et al.   Chemical Science

Computational Exploration of Mechanism and Selectivities of (NHC)Nickel(II)hydride-Catalyzed Hydroalkenylations of Styrene with α-Olefins

(2015) Xin Hong et al.   ACS Catalysis

Mechanistic Insight into the Gold-Catalyzed Carboxylative Cyclization of Propargylamines

(2015) Ruming Yuan et al.   ACS Catalysis

Mechanism and Origins of Selectivities in the Copper-Catalyzed Dearomatization-Induced ortho C–H Cyanation of Vinylarenes

(2015) Yang Yang et al.   ACS Catalysis

Cationic iridium-catalyzed C–H alkylation of 2-substituted pyridine N-oxides with acrylates

(2015) Takanori Shibata et al.   Organic Chemistry Frontiers

Iridium(I)-Catalyzed Direct CH Bond Alkylation of the C-7 Position of Indolines with Alkenes

(2014) Shiguang Pan et al.   ADVANCED SYNTHESIS & CATALYSIS

Development of Cobalt-Catalyzed C–H Bond Functionalization Reactions

(2014) Naohiko Yoshikai   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Cyclometalated [Cp*M(C^X)] (M = Ir, Rh; X = N, C, O, P) complexes

(2014) Ying-Feng Han et al.   CHEMICAL SOCIETY REVIEWS

Mechanistic Insights into the Pd-Catalyzed Intermolecular Asymmetric Allylic Dearomatization of Multisubstituted Pyrroles: Understanding the Remarkable Regio- and Enantioselectivity

(2014) Chao Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Computational Mechanistic Study of an Unprecedented Heck-Type Relay Reaction: Insight into the Origins of Regio- and Enantioselectivities

(2014) Yanfeng Dang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed, Intermolecular Hydroamination of Unactivated Alkenes with Indoles

(2014) Christo S. Sevov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Branch-Selective, Iridium-Catalyzed Hydroarylation of Monosubstituted Alkenes via a Cooperative Destabilization Strategy

(2014) Giacomo E. M. Crisenza et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism, Reactivity, and Selectivity in Palladium-Catalyzed Redox-Relay Heck Arylations of Alkenyl Alcohols

(2014) Liping Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cooperative activation of cyclobutanones and olefins leads to bridged ring systems by a catalytic [4 + 2] coupling

(2014) Haye Min Ko et al.   Nature Chemistry

Comparative Investigations of Cp*-Based Group 9 Metal-Catalyzed Direct C–H Amination of Benzamides

(2014) Travis M. Figg et al.   ORGANOMETALLICS

Regioselective ketone  -alkylation with simple olefins via dual activation

(2014) F. Mo et al.   SCIENCE

Catalytic CC bond forming transformations via direct β-CH functionalization of carbonyl compounds

(2014) Zhongxing Huang et al.   TETRAHEDRON LETTERS

Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C–H/Het–H Bond Functionalizations

(2013) Lutz Ackermann   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic intermolecular β-C–H alkenylation of α-enamino-ketones with simple alkynes

(2013) Zhiqian Wang et al.   CHEMICAL COMMUNICATIONS

Mechanistic Study on Ligand-Controlled Cobalt-Catalyzed Regioselectivity-Switchable Hydroarylation of Styrenes

(2013) Zhiwei Yang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Theoretical Studies on the Mechanism of the C–H Amination of Silyl Cyclopropenes by Azodicarboxylates

(2013) Genping Huang et al.   JOURNAL OF ORGANIC CHEMISTRY

Iridium-Catalyzed, Intermolecular Hydroetherification of Unactivated Aliphatic Alkenes with Phenols

(2013) Christo S. Sevov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism and Selectivity of Rhodium-Catalyzed 1:2 Coupling of Aldehydes and Allenes

(2013) Genping Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Intermolecular Asymmetric Hydroheteroarylation of Bicycloalkenes

(2013) Christo S. Sevov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

Recent development of direct asymmetric functionalization of inert C–H bonds

(2013) Chao Zheng et al.   RSC Advances

Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

(2012) Percia Beatrice Arockiam et al.   CHEMICAL REVIEWS

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Ir(I)-Catalyzed C–H Bond Alkylation of C2-Position of Indole with Alkenes: Selective Synthesis of Linear or Branched 2-Alkylindoles

(2012) Shiguang Pan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Intermolecular Hydroamination of Unactivated Aliphatic Alkenes with Amides and Sulfonamides

(2012) Christo S. Sevov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand Effects on Rates and Regioselectivities of Rh(I)-Catalyzed (5 + 2) Cycloadditions: A Computational Study of Cyclooctadiene and Dinaphthocyclooctatetraene as Ligands

(2012) Xiufang Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Intermolecular C-Alkylation of 1,2-Diketones with Simple Olefins: A Recyclable Directing Group Strategy

(2012) Zhiqian Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[Ir(cod)2]BARF-Catalyzed C–H Bond Alkenylation and Alkylation of Ferrocenes

(2012) Satoshi Takebayashi et al.   ORGANOMETALLICS

Mechanistic Origin of Regioselectivity in Nickel-Catalyzed Olefin Hydroheteroarylation through C–H Activation

(2012) Yuan-Ye Jiang et al.   ORGANOMETALLICS

Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

(2011) Denise A. Colby et al.   ACCOUNTS OF CHEMICAL RESEARCH

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Borylation and Silylation of C–H Bonds: A Platform for Diverse C–H Bond Functionalizations

(2011) John F. Hartwig   ACCOUNTS OF CHEMICAL RESEARCH

A New Direction in Enantioselective Catalysis: Scaffolding Ligands in Olefin Hydroformylation

(2011) Charles S. Yeung et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent developments in natural product synthesis using metal-catalysed C–H bond functionalisation

(2011) Lindsay McMurray et al.   CHEMICAL SOCIETY REVIEWS

Effect of the damping function in dispersion corrected density functional theory

(2011) Stefan Grimme et al.   JOURNAL OF COMPUTATIONAL CHEMISTRY

Mild and Efficient Nickel-Catalyzed Heck Reactions with Electron-Rich Olefins

(2011) Thomas M. Gøgsig et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Copolymerization of Methyl Acrylate with Carbon Monoxide: Structures, Properties and Mechanistic Aspects toward Ligand Design

(2011) Akifumi Nakamura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct C−H Transformation via Iron Catalysis

(2010) Chang-Liang Sun et al.   CHEMICAL REVIEWS

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

(2010) Stefan Grimme et al.   JOURNAL OF CHEMICAL PHYSICS

Computational Studies of the Relative Rates for Migratory Insertions of Alkenes into Square-Planar, Methyl, −Amido, and −Hydroxo Complexes of Rhodium

(2009) Jesse W. Tye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The effects of amine and acid catalysts on efficient chelation-assisted hydroacylation of alkene with aliphatic aldehyde

(2009) Eun-Ae Jo et al.   TETRAHEDRON LETTERS

Metal−Organic Cooperative Catalysis in C−H and C−C Bond Activation and Its Concurrent Recovery

(2008) Young Jun Park et al.   ACCOUNTS OF CHEMICAL RESEARCH

Drug design: hiding in full view

(2008) Norman S. Radin   DRUG DEVELOPMENT RESEARCH

Cationic iridium–BINAP complex-catalyzed addition of aryl ketones to alkynes and alkenes via directed C–H bond cleavage

(2008) Kyoji Tsuchikama et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Intermolecular, Catalytic Asymmetric Hydroamination of Bicyclic Alkenes and Dienes in High Yield and Enantioselectivity

(2008) Jianrong (Steve) Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY