Mechanism, reactivity, and selectivity of the iridium-catalyzed C(sp3)–H borylation of chlorosilanes

Iridium-Catalyzed C–H Borylation of Heteroarenes: Scope, Regioselectivity, Application to Late-Stage Functionalization, and Mechanism

(2014) Matthew A. Larsen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective Borylation of the C–H Bonds in Alkylamines and Alkyl Ethers. Observation and Origin of High Reactivity of Primary C–H Bonds Beta to Nitrogen and Oxygen

(2014) Qian Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Distortion/Interaction Analysis Reveals the Origins of Selectivities in Iridium-Catalyzed C–H Borylation of Substituted Arenes and 5-Membered Heterocycles

(2014) Aaron G. Green et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-Selective CH Borylation of Quinolines at the C8 Position Catalyzed by a Silica-Supported Phosphane-Iridium System

(2013) Shota Konishi et al.   Chemistry-An Asian Journal

High-Throughput Optimization of Ir-Catalyzed C–H Borylation: A Tutorial for Practical Applications

(2013) Sean M. Preshlock et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed C–H Borylation of Cyclopropanes

(2013) Carl W. Liskey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium–Carbon Bond Energies in Tp′Rh(CNneopentyl)(CH2X)H: Quantifying Stabilization Effects in M–C Bonds

(2013) Yunzhe Jiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides

(2013) Yang Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Borylation of Secondary Benzylic C–H Bonds Directed by a Hydrosilane

(2013) Seung Hwan Cho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Functionalization of Tetraorganosilanes and Permethyloligosilanes at a Methyl Group on Silicon via Iridium-Catalyzed C(sp3)–H Borylation

(2013) Toshimichi Ohmura et al.   ORGANOMETALLICS

On the Interpretation of Deuterium Kinetic Isotope Effects in CH Bond Functionalizations by Transition-Metal Complexes

(2012) Eric M. Simmons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rh-Catalyzed Borylation of N-Adjacent C(sp3)–H Bonds with a Silica-Supported Triarylphosphine Ligand

(2012) Soichiro Kawamorita et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Intermolecular Allylic C–H Trifluoroacetoxylation of Functionalized Alkenes

(2012) Rauful Alam et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Functionalization of Methyl Group on Silicon: Iridium-Catalyzed C(sp3)–H Borylation of Methylchlorosilanes

(2012) Toshimichi Ohmura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Borylation of Secondary C–H Bonds in Cyclic Ethers

(2012) Carl W. Liskey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Outer-Sphere Direction in Iridium C–H Borylation

(2012) Philipp C. Roosen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-catalyzed silyl C(sp3)–H bond activation

(2012) Yun Liang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Iridium-catalyzed C–H borylation of quinolines and unsymmetrical 1,2-disubstituted benzenes: insights into steric and electronic effects on selectivity

(2012) Hazmi Tajuddin et al.   Chemical Science

Borylation and Silylation of C–H Bonds: A Platform for Diverse C–H Bond Functionalizations

(2011) John F. Hartwig   ACCOUNTS OF CHEMICAL RESEARCH

Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners

(2011) Ranjan Jana et al.   CHEMICAL REVIEWS

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Silicon-based cross-coupling reaction: an environmentally benign version

(2011) Yoshiaki Nakao et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation

(2011) Seung Hwan Cho et al.   CHEMICAL SOCIETY REVIEWS

Regioselectivity of the borylation of alkanes and arenes

(2011) John F. Hartwig   CHEMICAL SOCIETY REVIEWS

Inversion or Retention? Effects of Acidic Additives on the Stereochemical Course in Enantiospecific Suzuki–Miyaura Coupling of α-(Acetylamino)benzylboronic Esters

(2011) Tomotsugu Awano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium Catalyzed Allylic C-H Alkylation: A Mechanistic Perspective

(2011) Casper Junker Engelin et al.   MOLECULES

Metal-Catalyzed α-Arylation of Carbonyl and Related Molecules: Novel Trends in CC Bond Formation by CH Bond Functionalization

(2010) Carin C. C. Johansson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electronic effects in iridium C–H borylations: insights from unencumbered substrates and variation of boryl ligand substituents

(2010) Britt A. Vanchura et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

C—H Bond Activation in Transition Metal Species from a Computational Perspective

(2010) David Balcells et al.   CHEMICAL REVIEWS

Functionalization of Organic Molecules by Transition-Metal-Catalyzed C(sp3)H Activation

(2010) Rodolphe Jazzar et al.   CHEMISTRY-A EUROPEAN JOURNAL

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

(2010) Stefan Grimme et al.   JOURNAL OF CHEMICAL PHYSICS

Palladium-Catalyzed Allylic Acyloxylation of Terminal Alkenes in the Presence of a Base

(2010) Emilie Thiery et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereospecific Suzuki−Miyaura Coupling of Chiral α-(Acylamino)benzylboronic Esters with Inversion of Configuration

(2010) Toshimichi Ohmura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conjugated Diene-Assisted Allylic C−H Bond Activation: Cationic Rh(I)-Catalyzed Syntheses of Polysubstituted Tetrahydropyrroles, Tetrahydrofurans, and Cyclopentanes from Ene-2-Dienes

(2010) Qian Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Origins of the Selectivity for Borylation of Primary over Secondary C−H Bonds Catalyzed by Cp*-Rhodium Complexes

(2010) Carolyn S. Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Time-resolved IR Studies on the Mechanism for the Functionalization of Primary C−H Bonds by Photoactivated Cp*W(CO)3(Bpin)

(2010) Karma R. Sawyer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pronounced effects of substituents on the iridium-catalyzed borylation of aryl C–H bonds

(2009) Carl W. Liskey et al.   CHEMICAL COMMUNICATIONS

Boryl ligands and their roles in metal-catalysed borylation reactions

(2009) Li Dang et al.   CHEMICAL COMMUNICATIONS

Getting the sterics just right: a five-coordinate iridium trisboryl complex that reacts with C–H bonds at room temperature

(2009) Ghayoor A. Chotana et al.   CHEMICAL COMMUNICATIONS

Transition Metal-Catalyzed Direct Arylation of Substrates with Activated sp3-Hybridized C−H Bonds and Some of Their Synthetic Equivalents with Aryl Halides and Pseudohalides

(2009) Fabio Bellina et al.   CHEMICAL REVIEWS

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity

(2009) Ramesh Giri et al.   CHEMICAL SOCIETY REVIEWS

The Interplay of Invention, Discovery, Development, and Application in Organic Synthetic Methodology: A Case Study

(2009) Scott E. Denmark   JOURNAL OF ORGANIC CHEMISTRY

Exceptional Sensitivity of Metal−Aryl Bond Energies toortho-Fluorine Substituents: Influence of the Metal, the Coordination Sphere, and the Spectator Ligands on M−C/H−C Bond Energy Correlations

(2009) Eric Clot et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Microwave-Accelerated Iridium-Catalyzed Borylation of Aromatic C−H Bonds

(2009) Peter Harrisson et al.   ORGANIC LETTERS

Palladium-Catalyzed Cross-Coupling Reactions of Organosilanols and Their Salts: Practical Alternatives to Boron- and Tin-Based Methods

(2008) Scott E. Denmark et al.   ACCOUNTS OF CHEMICAL RESEARCH

Metal−Organic Cooperative Catalysis in C−H and C−C Bond Activation and Its Concurrent Recovery

(2008) Young Jun Park et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Intermolecular Linear Allylic C−H Amination via Heterobimetallic Catalysis

(2008) Sean A. Reed et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intra/Intermolecular Direct Allylic Alkylation via Pd(II)-Catalyzed Allylic C−H Activation

(2008) Song Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Preparation of Silylboranes by Silane Borylation and Their Use in the Catalytic Borylation of Arenes

(2008) Timothy A. Boebel et al.   ORGANOMETALLICS