Enantioselective synthesis of gem-diarylalkanes by transition metal-catalyzed asymmetric arylations (TMCAAr)

Asymmetric Cu-Catalyzed Intermolecular Trifluoromethylarylation of Styrenes: Enantioselective Arylation of Benzylic Radicals

(2017) Lianqian Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Copper-Catalyzed Intermolecular Aminoarylation of Styrenes: Efficient Access to Optical 2,2-Diarylethylamines

(2017) Dinghai Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Asymmetric Reductive Cross-Coupling To Access 1,1-Diarylalkanes

(2017) Kelsey E. Poremba et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Enantioselective Reductive Cross-Coupling of Styrenyl Aziridines

(2017) Brian P. Woods et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed, Enantioselective α-Arylation of α-Fluorooxindoles

(2017) Yushu Jin et al.   ORGANIC LETTERS

Chiral Cyclic Ligand-Enabled Iridium-Catalyzed Asymmetric Arylation of Unactivated Racemic Allylic Alcohols with Anilines

(2017) Hua Tian et al.   ORGANIC LETTERS

The development and mechanistic investigation of a palladium-catalyzed 1,3-arylfluorination of chromenes

(2017) Richard T. Thornbury et al.   Chemical Science

Modular Synthesis of Enantioenriched 1,1,2-Triarylethanes by an Enantioselective Arylboration and Cross-Coupling Sequence

(2017) Bin Chen et al.   ACS Catalysis

Catalytic Enantioselective Arylboration of Alkenylarenes

(2016) Kaitlyn M. Logan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Enantioselective Bidentate Auxiliary Directed Palladium-Catalyzed Benzylic C−H Arylation of Amines Using a BINOL Phosphate Ligand

(2016) Hao Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Rhodium-Catalyzed Addition of Arylboroxines to Simple Aryl Ketones: Efficient Synthesis of Escitalopram

(2016) Linwei Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Conjugate Addition of Organoboron Reagents to Common Enones Using Copper Catalysts

(2016) Chunlin Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Development and Analysis of a Pd(0)-Catalyzed Enantioselective 1,1-Diarylation of Acrylates Enabled by Chiral Anion Phase Transfer

(2016) Eiji Yamamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Hydroarylation of Vinylarenes Using a Synergistic Combination of CuH and Pd Catalysis

(2016) Stig D. Friis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A nordehydroabietyl amide-containing chiral diene for rhodium-catalysed asymmetric arylation to nitroolefins

(2016) Ruikun Li et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Aryloxymethyltrifluoroborates for Rhodium-Catalyzed Asymmetric Conjugate Arylation. o-Methoxyarylation through 1,4-Rhodium Shift

(2016) Jialin Ming et al.   ORGANIC LETTERS

Functionalization of C(sp3)-H bonds using a transient directing group

(2016) F.-L. Zhang et al.   SCIENCE

Ligand-accelerated enantioselective methylene C(sp3)–H bond activation

(2016) Gang Chen et al.   SCIENCE

Rh-catalysed asymmetric conjugate addition of boronic acids to nitroalkenes employing a P-chiral P,π-hybrid ligand

(2016) Joshua D. Sieber et al.   Organic Chemistry Frontiers

Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C–C Bonds

(2015) Alan H. Cherney et al.   CHEMICAL REVIEWS

Synthesis of a Class of Chiral-Bridged Phosphoramidite Ligands and Their Applications in the First Iridium-Catalyzed Asymmetric Addition of Arylboronic Acids to Isatins

(2015) Yue Zhuang et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective and Regiodivergent Copper-Catalyzed Electrophilic Arylation of Allylic Amides with Diaryliodonium Salts

(2015) Elise Cahard et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Arylation of α-Aryl-α-diazoacetates with Aniline Derivatives

(2015) Bin Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Asymmetric 1,4-Addition of α,β-Unsaturated Imino Esters Using Chiral Bicyclic Bridgehead Phosphoramidite Ligands

(2015) Ansoo Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings

(2015) Osvaldo Gutierrez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Diarylmethanes via Copper-Catalyzed Asymmetric Allylic Arylation with Organolithium Compounds

(2015) Sureshbabu Guduguntla et al.   ORGANIC LETTERS

Rhodium-Catalyzed Asymmetric Arylation of Cyclic N-Sulfonyl Aryl Alkyl Ketimines: Efficient Access to Highly Enantioenriched α-Tertiary Amines

(2015) Tao Jiang et al.   ORGANIC LETTERS

Pd(II)-Catalyzed Asymmetric Addition of Arylboronic Acids to Isatin-Derived Ketimines

(2015) Qun He et al.   ORGANIC LETTERS

Palladium-Catalyzed Asymmetric Arylation of C(sp3)–H Bonds of Aliphatic Amides: Controlling Enantioselectivity Using Chiral Phosphoric Amides/Acids

(2015) Shao-Bai Yan et al.   ORGANIC LETTERS

Palladium-Catalyzed Asymmetric Addition of Arylboronic Acids to Nitrostyrenes

(2015) Qun He et al.   ORGANIC LETTERS

Cobalt co-catalysis for cross-electrophile coupling: diarylmethanes from benzyl mesylates and aryl halides

(2015) Laura K. G. Ackerman et al.   Chemical Science

Chiral Phosphite-Olefin Ligands：Application in Rh-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to β-Aryl-α,β-unsaturated Sulfonates

(2015) Yue-Na Yu et al.   ACTA CHIMICA SINICA

High Performance of a Palladium Phosphinooxazoline Catalyst in the Asymmetric Arylation of CyclicN-Sulfonyl Ketimines

(2014) Chunhui Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Asymmetric Arylation of β,γ-Unsaturated α-Ketoamides for the Construction of Nonracemic γ,γ-Diarylcarbonyl Compounds

(2014) Juanjuan Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Addition of Aryl Grignard Reagents to Ketones

(2014) Emilio Fernández-Mateos et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

“Sulfolefin”: a mixed sulfinamido-olefin ligand in enantioselective rhodium-catalyzed addition of arylboronic acids to trifluoromethyl ketones

(2014) Victoria Valdivia et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium-Catalyzed Highly Enantioselective Arylation of Cyclic Diketimines: Efficient Synthesis of Chiral Tetrasubstituted 1,2,5-Thiadiazoline 1,1-Dioxides

(2014) Hui Wang et al.   ORGANIC LETTERS

Rhodium catalyzed asymmetric 1,4-addition of arylboronic acids to β,γ-unsaturated α-keto ester using chiral tert-butanesulfinylphosphines ligands

(2014) Juanjuan Wang et al.   TETRAHEDRON LETTERS

Rh(I)-catalyzed asymmetric 1,2-additions of arylboronic acids to isatins with chiral sulfur–alkene hybrid ligands

(2014) Xiangqing Feng et al.   TETRAHEDRON LETTERS

Deoxycholic Acid-Derived Biaryl Phosphites as Versatile and Enantioselective Ligands in the Rhodium-Catalyzed Conjugate Addition of Arylboronic Acids to Nitroalkenes

(2013) Varsha R. Jumde et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective Additions of Aryltitanium Tris(isopropoxide) to Ketones: Structure of [(i-PrO)2Ti{μ-(S)-BINOLate}(μ-O-i-Pr)TiPh(O-i-Pr)2], Study of Mechanistic and Stereochemical Insights

(2013) Kuo-Hui Wu et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective Rhodium-Catalyzed Addition of Arylboronic Acids to Trifluoromethyl Ketones

(2013) Renshi Luo et al.   ADVANCED SYNTHESIS & CATALYSIS

A Palladium-Catalyzed Enantioselective Addition of Arylboronic Acids to Cyclic Ketimines

(2013) Guoqiang Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bioinspired Total Synthesis of Montanine-TypeAmaryllidaceaeAlkaloids

(2013) Xu Bao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of a class of new phosphine-oxazoline ligands and their applications in palladium-catalyzed asymmetric addition of arylboronic acids to isatins

(2013) Qing Li et al.   APPLIED CATALYSIS A-GENERAL

Nickel/Bis(oxazoline)-Catalyzed Asymmetric Negishi Arylations of Racemic Secondary Benzylic Electrophiles to Generate Enantioenriched 1,1-Diarylalkanes

(2013) Hien-Quang Do et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Simple Branched Sulfur–Olefins as Chiral Ligands for Rh-Catalyzed Asymmetric Arylation of Cyclic Ketimines: Highly Enantioselective Construction of Tetrasubstituted Carbon Stereocenters

(2013) Hui Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to β-Nitroolefins: Formal Synthesis of (S)-SKF 38393

(2013) Kung-Chih Huang et al.   ORGANIC LETTERS

Chiral 1,1-diaryl compounds as important pharmacophores

(2013) Dana Ameen et al.   MedChemComm

Me-BIPAM for the Synthesis of Optically Active 3-Aryl-3-hydroxy-2-oxindoles by Ruthenium-catalyzed Addition of Arylboronic Acids to Isatins

(2012) Yasunori Yamamoto et al.   Chemistry-An Asian Journal

Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to Indolylnitroalkenes

(2012) Junwei Xing et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Nitroalkenes Using Olefin–Sulfoxide Ligands

(2012) Feng Xue et al.   JOURNAL OF ORGANIC CHEMISTRY

Effect of Chiral Diene Ligands in Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to α,β-Unsaturated Sulfonyl Compounds

(2012) Takahiro Nishimura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(I)/Diene-Catalyzed Addition Reactions of Arylborons with Ketones

(2012) Yuan-Xi Liao et al.   ORGANIC LETTERS

Rh(I)-Catalyzed Asymmetric 1,2-Addition to α-Diketones with Chiral Sulfur–Alkene Hybrid Ligands

(2012) Xiangqing Feng et al.   ORGANIC LETTERS

Rh/chiral sulfinylphosphine catalyzed asymmetric 1,4-addition of arylboronic acids to chalcones

(2012) Guihua Chen et al.   TETRAHEDRON

Rh(I)-catalyzed asymmetric addition of arylboronic acids to NH isatins

(2012) Jiangyang Gui et al.   TETRAHEDRON-ASYMMETRY

Copper-Catalyzed 1,4-Addition of Organoboronates to Alkylidene Cyanoacetates: Mechanistic Insight and Application to Asymmetric Catalysis

(2011) Keishi Takatsu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Application of 2,6-Bis(trifluoromethyl)-4-pyridyl Phosphanes: The Most Electron-Poor Aryl Phosphanes with Moderate Bulkiness

(2011) Toshinobu Korenaga et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed, Highly Enantioselective 1,2-Addition of Aryl Boronic Acids to α-Ketoesters and α-Diketones Using Simple, Chiral Sulfur-Olefin Ligands

(2011) Ting-Shun Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Aryl- and Alkenylboronates

(2011) Ryo Shintani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Highly Enantioselective Addition of Arylboronic Acids to 2-Nitrostyrenes by tert-Butanesulfinylphosphine Ligand

(2011) Feng Lang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ru/Me-BIPAM-Catalyzed Asymmetric Addition of Arylboronic Acids to Aliphatic Aldehydes and α-Ketoesters

(2011) Yasunori Yamamoto et al.   MOLECULES

Catalytic Asymmetric Addition of Arylboronic Acids to Isatins usingC2-Symmetric CationicN-Heterocyclic Carbenes (NHCs) Pd2+Diaqua Complexes as Catalysts

(2011) Zhen Liu et al.   ORGANIC LETTERS

Asymmetric palladium-catalyzed hydroarylation of styrenes and dienes

(2011) Susanne M. Podhajsky et al.   TETRAHEDRON

Rhodium-Catalyzed Asymmetric Arylation

(2011) Ping Tian et al.   ACS Catalysis

Quaternary Carbon Stereogenic Centers through Copper-Catalyzed Enantioselective Allylic Substitutions with Readily Accessible Aryl- or Heteroaryllithium Reagents and Aluminum Chlorides

(2010) Fang Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Asymmetric Conjugate Addition of Organoboronic Acids to Nitroalkenes Using Chiral Bicyclo[3.3.0] Diene Ligands

(2010) Zhi-Qian Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed asymmetric addition of arylboronates to isatins: a catalytic cycle involving alkoxocopper intermediates

(2010) Ryo Shintani et al.   CHEMICAL COMMUNICATIONS

Synthetic applications of rhodium catalysed conjugate addition

(2010) Hannah J. Edwards et al.   CHEMICAL SOCIETY REVIEWS

Rhodium-Catalyzed Asymmetric Arylation ofN-Tosyl Ketimines

(2010) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A chiral Rh–phosphite complex displaying high activity in the enantioselective Rh-catalyzed addition of arylboronic acids to carbonyl compounds: when and why atropos is better than tropos

(2010) Varsha R. Jumde et al.   TETRAHEDRON-ASYMMETRY

Efficient Chiral N-Heterocyclic Carbene/Copper(I)-Catalyzed Asymmetric Allylic Arylation with Aryl Grignard Reagents

(2009) Khalid B. Selim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Enantioselective α-Arylation and α-Vinylation of Oxindoles Facilitated by an Axially Chiral P-Stereogenic Ligand

(2009) Alexander M. Taylor et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of SM-130686 Based on the Development of Asymmetric Cu(I)F Catalysis To Access 2-Oxindoles Containing a Tetrasubstituted Carbon

(2009) Daisuke Tomita et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective addition of organozinc reagents to ketones catalyzed by grafted isoborneolsulfonamide polymers and titanium isopropoxide

(2009) Vicente J. Forrat et al.   TETRAHEDRON-ASYMMETRY

A New Aspect of Magnesium Bromide‐Promoted Enantioselective Aryl Additions of Triaryl(tetrahydrofuran)aluminum to Ketones Catalyzed by a Titanium(IV) Catalyst oftrans‐1,2‐Bis(hydroxycamphorsulfonylamino)cyclohexane

(2008) Chien‐An Chen et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective Rhodium-Catalyzed Addition of Arylboronic Acids to α-Ketoesters

(2008) Hai-Feng Duan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stepwise Palladium-Catalyzed 1,4-Addition of Arylboronic Acids to Enones and Regioselective Baeyer–Villiger Oxidation for Enantioselective Synthesis of β-Diaryl Esters and (+)-(R)-Tolterodine

(2008) Kenya Kobayashi et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Copper-catalyzed asymmetric allylic substitution with aryl and ethyl Grignard reagents

(2008) Khalid B. Selim et al.   CHEMICAL COMMUNICATIONS

Enantioselective Iridium-Catalyzed Allylic Arylation

(2008) Damien Polet et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Novel Enantiopure BiphenylP,N-Ligands and Application in Palladium-Catalyzed Asymmetric Addition of Arylboronic Acids toN-Benzylisatin

(2008) Hongshan Lai et al.   JOURNAL OF ORGANIC CHEMISTRY