Copper-Catalyzed 1,4-Addition of Organoboronates to Alkylidene Cyanoacetates: Mechanistic Insight and Application to Asymmetric Catalysis

Multinuclear Catalyst for Copper-Catalyzed Asymmetric Conjugate Addition of Organozinc Reagents

(2010) Kohei Endo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly enantioselective Cu(i)–Tol-BINAP-catalyzed asymmetric conjugate addition of Grignard reagents to α,β-unsaturated esters

(2010) Shun-Yi Wang et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed asymmetric addition of arylboronates to isatins: a catalytic cycle involving alkoxocopper intermediates

(2010) Ryo Shintani et al.   CHEMICAL COMMUNICATIONS

Formation of Quaternary Chiral Centers by N-Heterocyclic Carbene-Cu-Catalyzed Asymmetric Conjugate Addition Reactions with Grignard Reagents on Trisubstituted Cyclic Enones

(2010) Stefan Kehrli et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reversal of Stereoselectivity in the Cu-Catalyzed Conjugate Addition Reaction of Dialkylzinc to Cyclic Enone in the Presence of a Chiral Azolium Compound

(2010) Naoatsu Shibata et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Enantioselective Synthesis oftrans-1-Alkyl-2-substituted Cyclopropanes via Tandem Conjugate Addition−Intramolecular Enolate Trapping

(2010) Tim den Hartog et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed γ-Selective Allyl−Alkyl Coupling between Allylic Phosphates and Alkylboranes

(2010) Hirohisa Ohmiya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Conjugate Silyl Additions to Cyclic and Acyclic Unsaturated Carbonyls Catalyzed by Cu Complexes of Chiral N-Heterocyclic Carbenes

(2010) Kang-sang Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Boronate Derivatives via Catalytic Enantioselective Conjugate Addition of Grignard Reagents on 3-Boronyl Unsaturated Esters and Thioesters

(2010) Jack Chang Hung Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Boron-Substituted Quaternary Carbons by NHC−Cu-Catalyzed Boronate Conjugate Additions to Unsaturated Carboxylic Esters, Ketones, or Thioesters

(2010) Jeannette M. O’Brien et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Enantioselective 1,4-Addition to α,β-Unsaturated Aldehydes

(2010) Laëtitia Palais et al.   ORGANIC LETTERS

Enantioselective and Regiodivergent Copper-Catalyzed Conjugate Addition of Trialkylaluminium Reagents to Extended Nitro-Michael Acceptors

(2010) Matthieu Tissot et al.   ORGANIC LETTERS

Catalytic SN2′-Selective Substitution of Allylic Chlorides With Arylboronic Esters

(2010) Aaron M. Whittaker et al.   ORGANIC LETTERS

Efficient Chiral N-Heterocyclic Carbene/Copper(I)-Catalyzed Asymmetric Allylic Arylation with Aryl Grignard Reagents

(2009) Khalid B. Selim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoisomerically Pure Trisubstituted Vinylaluminum Reagents and their Utility in Copper-Catalyzed Enantioselective Synthesis of 1,4-Dienes Containing Z or E Alkenes

(2009) Katsuhiro Akiyama et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic enantioselective boron conjugate addition to cyclic carbonyl compounds: a new approach to cyclic β-hydroxy carbonyls

(2009) Xinhui Feng et al.   CHEMICAL COMMUNICATIONS

Monodentate Non-C2-symmetric ChiralN-Heterocyclic Carbene Complexes for Enantioselective Synthesis. Cu-Catalyzed Conjugate Additions of Aryl- and Alkenylsilylfluorides to Cyclic Enones

(2009) Kang-sang Lee et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Asymmetric Synthesis of Chiral Tertiary Organoboronic Esters through Conjugate Boration of β-Substituted Cyclic Enones

(2009) I-Hon Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Vicinal Diboronates in High Enantiomeric Purity through Tandem Site-Selective NHC−Cu-Catalyzed Boron−Copper Additions to Terminal Alkynes

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic asymmetric conjugate addition of dialkylzinc reagents to α,β-unsaturated sulfones

(2009) Pieter H. Bos et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Construction of a new type of chiral bidentate NHC ligands: copper-catalyzed asymmetric conjugate alkylation

(2009) Tatsuya Uchida et al.   TETRAHEDRON LETTERS

Asymmetric conjugate additions to 1,1′-diactivated cyclic enones—a comparative study

(2009) Xiaoping Tang et al.   TETRAHEDRON-ASYMMETRY

Enantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers by Catalytic Asymmetric Conjugate Additions of Alkyl and Aryl Aluminum Reagents to Five-, Six-, and Seven-Membered-Ring β-Substituted Cyclic Enones

(2008) Tricia L. May et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regiodivergent 1,4 versus 1,6 Asymmetric Copper-Catalyzed Conjugate Addition

(2008) Hélène Hénon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylation of Organoboronic Esters Catalyzed by N‐Heterocyclic Carbene Copper(I) Complexes

(2008) Takeshi Ohishi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cu-catalyzed stereoselective conjugate addition of arylboronic acids to alkynoates

(2008) Yoshihiko Yamamoto et al.   CHEMICAL COMMUNICATIONS

Chiral N-heterocyclic carbene ligands for asymmetric catalytic oxindole synthesis

(2008) Yi-Xia Jia et al.   CHEMICAL COMMUNICATIONS

Catalytic Asymmetric Conjugate Addition and Allylic Alkylation with Grignard Reagents

(2008) Syuzanna R. Harutyunyan et al.   CHEMICAL REVIEWS

Enantioselective Copper-Catalyzed Conjugate Addition and Allylic Substitution Reactions

(2008) A. Alexakis et al.   CHEMICAL REVIEWS

Copper(II) Acetate-Catalyzed Addition of Arylboronic Acids to Aromatic Aldehydes

(2008) Hanmei Zheng et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Asymmetric Conjugate Addition of Grignard Reagents to α,β-Unsaturated Sulfones

(2008) Pieter H. Bos et al.   ORGANIC LETTERS

Rhodium/Chiral Diene-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to Arylmethylene Cyanoacetates

(2008) Sebastian Sörgel et al.   ORGANIC LETTERS

Synthesis of 4-Arylcoumarins via Cu-Catalyzed Hydroarylation with Arylboronic Acids

(2008) Yoshihiko Yamamoto et al.   ORGANIC LETTERS

Copper(I)-Catalyzed Carboxylation of Aryl- and Alkenylboronic Esters

(2008) Jun Takaya et al.   ORGANIC LETTERS

Selectivity Control in 1,2- and 1,4-Additions of Aluminum Organyls to Carbonyl Compounds

(2008) Paultheo von Zezschwitz   SYNTHESIS-STUTTGART

Catalytic Asymmetric Boration of Acyclic α,β-Unsaturated Esters and Nitriles

(2007) Ji-Eon Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION