A Palladium-Catalyzed Enantioselective Addition of Arylboronic Acids to Cyclic Ketimines

Hydroxorhodium/Chiral Diene Complexes as Effective Catalysts for the Asymmetric Arylation of 3-Aryl-3-hydroxyisoindolin-1-ones

(2013) Takahiro Nishimura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed [3 + 2] Annulation of Cyclic N-Sulfonyl Ketimines with 1,3-Dienes via C–H Activation

(2013) Takahiro Nishimura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Simple Branched Sulfur–Olefins as Chiral Ligands for Rh-Catalyzed Asymmetric Arylation of Cyclic Ketimines: Highly Enantioselective Construction of Tetrasubstituted Carbon Stereocenters

(2013) Hui Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Catalytic Asymmetric Alkynylation of Ketoimines

(2013) Liang Yin et al.   ORGANIC LETTERS

Palladium/Chiral Amine Co-catalyzed Enantioselective β-Arylation of α,β-Unsaturated Aldehydes

(2012) Ismail Ibrahem et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Rhodium-Catalyzed Nucleophilic Allylation of Cyclic Imines with Allylboron Reagents

(2012) Yunfei Luo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Rhodium-Catalyzed Addition of Potassium Alkenyltrifluoroborates to Cyclic Imines

(2012) Yunfei Luo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Asymmetric Aerobic Aza-Wacker-Type Cyclization: Synthesis of Isoindolinones Bearing Tetrasubstituted Carbon Stereocenters

(2012) Guoqiang Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Heterocyclic Acceptors

(2012) Jeffrey C. Holder et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Asymmetric Quaternary Stereocenter Formation

(2012) Aditya L. Gottumukkala et al.   CHEMISTRY-A EUROPEAN JOURNAL

Conjugate Addition vs Heck Reaction: A Theoretical Study on Competitive Coupling Catalyzed by Isoelectronic Metal (Pd(II) and Rh(I))

(2012) Qian Peng et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium(II)-Catalyzed Enantioselective Arylation of α-Imino Esters

(2012) Jiayan Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Dynamic Kinetic Asymmetric Transformations of Racemic Tertiary Allylic Trichloroacetimidates with Anilines

(2012) Jeffrey S. Arnold et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Benzylic Phosphates as Electrophiles in the Palladium-Catalyzed Asymmetric Benzylation of Azlactones

(2012) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of (Triaryl)methylamines by Rhodium-Catalyzed Addition of Arylboroxines to Cyclic N-Sulfonyl Ketimines

(2012) Takahiro Nishimura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergent Direct Catalytic Asymmetric Mannich-Type Reactions of α-Isothiocyanato Ester with Ketimines

(2011) Gang Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Intramolecular Benzylic CH Bond Amination: Efficient Synthesis of Optically Active Benzosultams

(2011) Masami Ichinose et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Rhodium(I)-Catalyzed [3+2] Annulations of Aromatic Ketimines Induced by Directed CH Activations

(2011) Duc N. Tran et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Diastereo- and Enantioselective Mannich Reactions of Synthetically Flexible Ketimines with Secondary Amine Organocatalysts

(2011) Taichi Kano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Advances in the Catalytic Asymmetric Arylation of Imines using Organoboron Reagents: An Approach to Chiral Arylamines

(2011) Carolina S. Marques et al.   ChemCatChem

Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners

(2011) Ranjan Jana et al.   CHEMICAL REVIEWS

Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications

(2011) Richard I. McDonald et al.   CHEMICAL REVIEWS

Catalytic Enantioselective Formation of C−C Bonds by Addition to Imines and Hydrazones: A Ten-Year Update

(2011) Shu̅ Kobayashi et al.   CHEMICAL REVIEWS

Mechanism of the Palladium-Catalyzed Addition of Arylboronic Acids to Enones: A Computational Study

(2011) Yu Lan et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Enantioselective Arylation ofN-Tosylalkylaldimines Catalyzed by Rhodium-Diene Complexes

(2011) Zhe Cui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Five-, Six-, and Seven-Membered β-Substituted Cyclic Enones: Enantioselective Construction of All-Carbon Quaternary Stereocenters

(2011) Kotaro Kikushima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Brønsted Acid-Catalyzed Asymmetric Trisubstituted Aziridine Synthesis Using α-Diazoacyl Oxazolidinones

(2011) Takuya Hashimoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Divergent C–H Functionalizations Directed by Sulfonamide Pharmacophores: Late-Stage Diversification as a Tool for Drug Discovery

(2011) Hui-Xiong Dai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Homoallylic Amines through Reactions of (Pinacolato)allylborons with Aryl-, Heteroaryl-, Alkyl-, or Alkene-Substituted Aldimines Catalyzed by ChiralC1-Symmetric NHC−Cu Complexes

(2011) Erika M. Vieira et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Functional Group Compatible Rh-Catalyzed Addition of Arylboroxines to ActivatedN-tert-Butanesulfinyl Ketimines

(2011) Hyung Hoon Jung et al.   ORGANIC LETTERS

Rhodium-Catalyzed Asymmetric Addition of Potassium Organotrifluoroborates toN-Sulfonyl Ketimines

(2011) Ryo Shintani et al.   ORGANIC LETTERS

Catalytic Enantioselective Addition of Phenylboronic Acid and Phenylboroxine toN-Tosylimines: PdIIand RhICatalysis

(2010) Carolina S. Marques et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Asymmetric 1,4-Addition of Arylboronic Acids to 2,3-Dihydro-4-pyridones Catalyzed by Axially Chiral NHC−Pd(II) Complexes

(2010) Qin Xu et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Construction of Highly Substituted Pyrrolidines by Palladium-Catalyzed Asymmetric [3+2] Cycloaddition of Trimethylenemethane with Ketimines

(2010) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Bisguanidine-Catalyzed Inverse-Electron-Demand Hetero-Diels−Alder Reaction of Chalcones with Azlactones

(2010) Shunxi Dong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Bicycle Imidazole Nucleophilic Catalysts: Rational Design, Facile Synthesis, and Successful Application in Asymmetric Steglich Rearrangement

(2010) Zhenfeng Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Design of Structurally Rigidtrans-Diamine-Based Tf-Amide Organocatalysts with a Dihydroanthracene Framework for Asymmetric Conjugate Additions of Heterosubstituted Aldehydes to Vinyl Sulfones

(2010) Shin A. Moteki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Asymmetric Arylation ofN-Tosyl Ketimines

(2010) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Synthesis of 3-Aminooxindoles: Enantiofacial Selectivity Switch in Bimetallic vs Monometallic Schiff Base Catalysis

(2010) Shinsuke Mouri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Preliminary Biochemical Evaluation of Novel Derivatives of PCP

(2010) Joannes Linders et al.   Letters in Drug Design & Discovery

Cationic Pd(II)/Bipyridine-Catalyzed Conjugate Addition of Arylboronic Acids to β,β-Disubstituted Enones: Construction of Quaternary Carbon Centers

(2010) Shaohui Lin et al.   ORGANIC LETTERS

Catalytic asymmetric addition of arylboronic acids to N-Boc imines generated in situ using C2-symmetric cationic N-heterocyclic carbenes (NHCs) Pd2+ diaquo complexes

(2010) Zhen Liu et al.   TETRAHEDRON

Enantioselective Fujiwara-Moritani Indole and Pyrrole Annulations Catalyzed by Chiral Palladium(II)-NicOx Complexes

(2009) Julia A. Schiffner et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Highly Enantioselective Synthesis of Sultams via Pd-Catalyzed Hydrogenation

(2009) Chang-Bin Yu et al.   JOURNAL OF ORGANIC CHEMISTRY

Construction of Contiguous Tetrasubstituted Chiral Carbon Stereocenters via Direct Catalytic Asymmetric Aldol Reaction of α-Isothiocyanato Esters with Ketones

(2009) Tatsuhiko Yoshino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Arylation ofN-Tosylarylimines with Arylboronic Acids UsingC2-Symmetric CationicN-Heterocyclic Carbene Pd2+Diaquo Complexes

(2009) Guang-Ning Ma et al.   ORGANIC LETTERS

Stereoselective synthesis of N-heterocycles: application of the asymmetric Cu-catalyzed addition of Et2Zn to functionalized alkyl and aryl imines

(2009) Isabelle Bonnaventure et al.   TETRAHEDRON

Palladium(II)/2,2′-bipyridine-catalyzed addition of arylboronic acids to N-tosyl-arylaldimines

(2009) Huixiong Dai et al.   TETRAHEDRON LETTERS

Palladium(II)-Catalyzed One-Pot Enantioselective Synthesis of Arylglycine Derivatives from Ethyl Glyoxylate,p-Toluenesulfonyl Isocyanate and Arylboronic Acids

(2008) Huixiong Dai et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective Synthesis of α-Aryl Alkylamines by Rh-Catalyzed Addition Reactions of Arylboronic Acids to Aliphatic Imines

(2008) Mónica Trincado et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of Tertiary Alcohols and α-Tertiary Amines via Cu-Catalyzed C−C Bond Formation to Ketones and Ketimines

(2008) Masakatsu Shibasaki et al.   CHEMICAL REVIEWS

Copper-Catalyzed Asymmetric Alkylation of Imines with Dialkylzinc and Related Reactions

(2008) Ken-ichi Yamada et al.   CHEMICAL REVIEWS

Highly Enantioselective Strecker Reaction of Ketoimines Catalyzed by an Organocatalyst from (S)-BINOL andL-Prolinamide

(2008) Zongrui Hou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chiral Bidentate Bis(N-Heterocyclic Carbene)-Based Palladium Complexes Bearing Carboxylate Ligands: Highly Effective Catalysts for the Enantioselective Conjugate Addition of Arylboronic Acids to Cyclic Enones

(2008) Tao Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Asymmetric Conjugate Addition of Aryl-Metal Species

(2008) Andrey Gutnov   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Catalytic Enantioselective Addition of Organometallic Reagents toN-Formylimines Using Monodentate Phosphoramidite Ligands

(2008) Maria Gabriella Pizzuti et al.   JOURNAL OF ORGANIC CHEMISTRY

Cyclic Ketimines as Superior Electrophiles for NHC-Catalyzed Homoenolate Additions with Broad Scope and Low Catalyst Loadings

(2008) Michael Rommel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Reductive Mannich Reaction to Ketimines Catalyzed by a Cu(I) Complex

(2008) Yao Du et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Catalytic Asymmetric Addition of Allylic Cyanides to Ketoimines

(2008) Ryo Yazaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Alkylations of Ketoimines. Enantioselective Synthesis ofN-Substituted Quaternary Carbon Stereogenic Centers by Zr-Catalyzed Additions of Dialkylzinc Reagents to Aryl-, Alkyl-, and Trifluoroalkyl-Substituted Ketoimines

(2008) Peng Fu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ag-Catalyzed Diastereo- and Enantioselective Vinylogous Mannich Reactions of α-Ketoimine Esters. Development of a Method and Investigation of its Mechanism

(2008) Laura C. Wieland et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Aza-Henry Reaction of Ketoimines Catalyzed by ChiralN,N′-Dioxide−Copper(I) Complexes

(2008) Cheng Tan et al.   ORGANIC LETTERS

1,4-Additions of arylboron, -silicon, and -bismuth compounds to α,β-unsaturated carbonyl compounds catalyzed by dicationic palladium(II) complexes

(2008) Yasunori Yamamoto et al.   PURE AND APPLIED CHEMISTRY

Copper-catalyzed asymmetric addition of diethylzinc to Boc-protected imines

(2008) Quentin Perron et al.   TETRAHEDRON-ASYMMETRY

Enantioselective, NHC-Catalyzed Bicyclo-β-Lactam Formation via Direct Annulations of Enals and UnsaturatedN-Sulfonyl Ketimines

(2007) Ming He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY