Recent advances in radical-based C–N bond formation via photo-/electrochemistry

Metal- and Reagent-Free Intramolecular Oxidative Amination of Tri- and Tetrasubstituted Alkenes

(2017) Peng Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Directed β C–H Amination of Alcohols via Radical Relay Chaperones

(2017) Ethan A. Wappes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-light-promoted selective C–H amination of heteroarenes with heteroaromatic amines under metal-free conditions

(2017) Supravat Samanta et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Cross-Dehydrogenative C–H Amination of Indoles under Aerobic Photo-oxidative Conditions

(2017) Tomoaki Yamaguchi et al.   ORGANIC LETTERS

Photocatalytic Hydrazonyl Radical-Mediated Radical Cyclization/Allylation Cascade: Synthesis of Dihydropyrazoles and Tetrahydropyridazines

(2017) Quan-Qing Zhao et al.   ORGANIC LETTERS

Catalytic intermolecular hydroaminations of unactivated olefins with secondary alkyl amines

(2017) Andrew J. Musacchio et al.   SCIENCE

Enantioselective catalytic β-amination through proton-coupled electron transfer followed by stereocontrolled radical–radical coupling

(2017) Zijun Zhou et al.   Chemical Science

Photo-induced oxidant-free oxidative C–H/N–H cross-coupling between arenes and azoles

(2017) Linbin Niu et al.   Nature Communications

Photocatalytic Cross-Dehydrogenative Amination Reactions between Phenols and Diarylamines

(2017) Yating Zhao et al.   ACS Catalysis

Selective Piperidine Synthesis Exploiting Iodine-Catalyzed Csp3–H Amination under Visible Light

(2017) Hongwei Zhang et al.   ACS Catalysis

Photochemical Generation of Nitrogen-Centered Amidyl, Hydrazonyl, and Imidyl Radicals: Methodology Developments and Catalytic Applications

(2017) Markus D. Kärkäs   ACS Catalysis

Electro-oxidative C(sp3)–H Amination of Azoles via Intermolecular Oxidative C(sp3)–H/N–H Cross-Coupling

(2017) Jiwei Wu et al.   ACS Catalysis

Selective C(sp2 )−H Functionalization of Arenes for Amination Reactions by Using Photoredox Catalysis

(2017) Ganesh Pandey et al.   Asian Journal of Organic Chemistry

Catalytic Dehydrogenative C–H Imidation of Arenes Enabled by Photo-generated Hole Donation to Sulfonimide

(2017) Eri Ito et al.   Chem

Synthetic Applications of Proton-Coupled Electron Transfer

(2016) Emily C. Gentry et al.   ACCOUNTS OF CHEMICAL RESEARCH

Electrochemical C−H/N−H Functionalization for the Synthesis of Highly Functionalized (Aza)indoles

(2016) Zhong-Wei Hou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrocatalytic Generation of Amidyl Radicals for Olefin Hydroamidation: Use of Solvent Effects to Enable Anilide Oxidation

(2016) Lin Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Triiodide-Mediated δ-Amination of Secondary C−H Bonds

(2016) Ethan A. Wappes et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Amidinyl Radical Formation through Anodic N−H Bond Cleavage and Its Application in Aromatic C−H Bond Functionalization

(2016) Huai-Bo Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photocatalytic Dehydrogenative Cross-Coupling of Alkenes with Alcohols or Azoles without External Oxidant

(2016) Hong Yi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free C–H sulfonamidation of pyrroles by visible light photoredox catalysis

(2016) Andreas Uwe Meyer et al.   CHEMICAL COMMUNICATIONS

A visible-light photocatalytic N-radical cascade of hydrazones for the synthesis of dihydropyrazole-fused benzosultams

(2016) Quan-Qing Zhao et al.   CHEMICAL COMMUNICATIONS

New amination strategies based on nitrogen-centered radical chemistry

(2016) Tao Xiong et al.   CHEMICAL SOCIETY REVIEWS

Visible light photoredox-controlled reactions of N-radicals and radical ions

(2016) Jia-Rong Chen et al.   CHEMICAL SOCIETY REVIEWS

Visible-Light-Induced Direct Oxidative C−H Amidation of Heteroarenes with Sulfonamides

(2016) Kun Tong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organophotocatalytic Generation of N- and O-Centred Radicals Enables Aerobic Oxyamination and Dioxygenation of Alkenes

(2016) Xiao-Qiang Hu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Benzylic C(sp3)–H Functionalization for C–N and C–O Bond Formation via Visible Light Photoredox Catalysis

(2016) Ganesh Pandey et al.   JOURNAL OF ORGANIC CHEMISTRY

Photocatalytic Hydrogen-Evolution Cross-Couplings: Benzene C–H Amination and Hydroxylation

(2016) Yi-Wen Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light-Promoted Direct Amination of Phenols via Oxidative Cross-Dehydrogenative Coupling Reaction

(2016) Yating Zhao et al.   ORGANIC LETTERS

N-Iodosuccinimide-Promoted Hofmann–Löffler Reactions of Sulfonimides under Visible Light

(2016) Calvin Q. O’Broin et al.   ORGANIC LETTERS

Visible light amination/Smiles cascade: access to phthalazine derivatives

(2016) Etienne Brachet et al.   Chemical Science

Catalytic N-radical cascade reaction of hydrazones by oxidative deprotonation electron transfer and TEMPO mediation

(2016) Xiao-Qiang Hu et al.   Nature Communications

Transition-Metal-Mediated Direct C–H Amination of Hydrocarbons with Amine Reactants: The Most Desirable but Challenging C–N Bond-Formation Approach

(2016) Hyunwoo Kim et al.   ACS Catalysis

Transition-Metal-Catalyzed C–N Bond Forming Reactions Using Organic Azides as the Nitrogen Source: A Journey for the Mild and Versatile C–H Amination

(2015) Kwangmin Shin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Diastereoselective Oxidative CN/CO and CN/CN Bond Formation Tandems Initiated by Visible Light: Synthesis of FusedN-Arylindolines

(2015) Scott A. Morris et al.   ADVANCED SYNTHESIS & CATALYSIS

Visible-Light-Catalyzed Direct Benzylic C(sp3)-H Amination Reaction by Cross-Dehydrogenative Coupling

(2015) Ganesh Pandey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Iodine-Catalyzed Hofmann-Löffler Reaction

(2015) Claudio Martínez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-light initiated copper(i)-catalysed oxidative C–N coupling of anilines with terminal alkynes: one-step synthesis of α-ketoamides

(2015) Arunachalam Sagadevan et al.   GREEN CHEMISTRY

Hypervalent Iodine(III) in Direct Oxidative Amination of Arenes with Heteroaromatic Amines

(2015) Srimanta Manna et al.   ORGANIC LETTERS

Site-selective arene C-H amination via photoredox catalysis

(2015) N. A. Romero et al.   SCIENCE

Photocatalytic Generation of N-Centered Hydrazonyl Radicals:  A Strategy for Hydroamination of β,γ-Unsaturated Hydrazones

(2014) Xiao-Qiang Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

anti-Markovnikov Hydroamination of Alkenes Catalyzed by a Two-Component Organic Photoredox System: Direct Access to Phenethylamine Derivatives

(2014) Tien M. Nguyen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Olefin Hydroamination with Aminium Radical Cations: A Photoredox Method for Direct C–N Bond Formation

(2014) Andrew J. Musacchio et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative C–H amination reactions

(2013) Marie-Laure Louillat et al.   CHEMICAL SOCIETY REVIEWS

Anti-Markovnikov Hydroamination of Alkenes Catalyzed by an Organic Photoredox System

(2013) Tien M. Nguyen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Visible-Light-Mediated Oxidative CN Bond Formation/Aromatization Cascade: Photocatalytic Preparation of N-Arylindoles

(2012) Soumitra Maity et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION