New amination strategies based on nitrogen-centered radical chemistry

N-Iodosuccinimide-Promoted Hofmann–Löffler Reactions of Sulfonimides under Visible Light

(2016) Calvin Q. O’Broin et al.   ORGANIC LETTERS

Diastereoselective Oxidative CN/CO and CN/CN Bond Formation Tandems Initiated by Visible Light: Synthesis of FusedN-Arylindolines

(2015) Scott A. Morris et al.   ADVANCED SYNTHESIS & CATALYSIS

Highly Regioselective Radical Amination of Allenes: Direct Synthesis of Allenamides and Tetrasubstituted Alkenes

(2015) Ge Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Mediated Generation of Nitrogen-Centered Radicals: Metal-Free Hydroimination and Iminohydroxylation Cyclization Reactions

(2015) Jacob Davies et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Promoted Iminyl-Radical Formation from Acyl Oximes: A Unified Approach to Pyridines, Quinolines, and Phenanthridines

(2015) Heng Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Iodine-Catalyzed Hofmann-Löffler Reaction

(2015) Claudio Martínez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Olefin Hydroamidation Enabled by Proton-Coupled Electron Transfer

(2015) David C. Miller et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Alkene Carboaminations Enabled by Oxidative Proton-Coupled Electron Transfer

(2015) Gilbert J. Choi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light-Promoted Remote C(sp3)–H Amidation and Chlorination

(2015) Qixue Qin et al.   ORGANIC LETTERS

Visible-Light-Promoted and One-Pot Synthesis of Phenanthridines and Quinolines from Aldehydes and O-Acyl Hydroxylamine

(2015) Xiao-De An et al.   ORGANIC LETTERS

Chemoselective Intramolecular Functionalization of Methyl Groups in Nonconstrained Molecules Promoted by N-Iodosulfonamides

(2015) Nieves R. Paz et al.   ORGANIC LETTERS

Cobalt catalyzed sp3 C–H amination utilizing aryl azides

(2015) Omar Villanueva et al.   Chemical Science

Photocatalytic Generation of N-Centered Hydrazonyl Radicals:  A Strategy for Hydroamination of β,γ-Unsaturated Hydrazones

(2014) Xiao-Qiang Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective Radical Aminofluorination of Styrenes

(2014) Hongwei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nitrogen-centered radical-mediated C–H imidation of arenes and heteroarenes via visible light induced photocatalysis

(2014) Hyejin Kim et al.   CHEMICAL COMMUNICATIONS

Visible-Light Promoted Catalyst-Free Imidation of Arenes and Heteroarenes

(2014) Lu Song et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Mild, Ferrocene-Catalyzed C–H Imidation of (Hetero)Arenes

(2014) Klement Foo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Acyloxyphthalimides as Nitrogen Radical Precursors in the Visible Light Photocatalyzed Room Temperature C–H Amination of Arenes and Heteroarenes

(2014) Laura J. Allen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Olefin Hydroamination with Aminium Radical Cations: A Photoredox Method for Direct C–N Bond Formation

(2014) Andrew J. Musacchio et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron(II)-Catalyzed Intermolecular Amino-Oxygenation of Olefins through the N–O Bond Cleavage of Functionalized Hydroxylamines

(2014) Deng-Fu Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light-Promoted Redox Neutral C–H Amidation of Heteroarenes with Hydroxylamine Derivatives

(2014) Qixue Qin et al.   ORGANIC LETTERS

N-Aminopyridinium Salts as Precursors for N-Centered Radicals – Direct Amidation of Arenes and Heteroarenes

(2014) Tobias W. Greulich et al.   ORGANIC LETTERS

Copper-Catalyzed Intermolecular Aminoazidation of Alkenes

(2014) Bo Zhang et al.   ORGANIC LETTERS

Direct Stereospecific Synthesis of Unprotected N-H and N-Me Aziridines from Olefins

(2014) Jawahar L. Jat et al.   SCIENCE

Selective radical amination of aldehydic C(sp2)–H bonds with fluoroaryl azides via Co(ii)-based metalloradical catalysis: synthesis of N-fluoroaryl amides from aldehydes under neutral and nonoxidative conditions

(2014) Li-Mei Jin et al.   Chemical Science

Copper catalyzed Heck-like cyclizations of oxime esters

(2014) Adele Faulkner et al.   Chemical Science

Effective Synthesis of ChiralN-Fluoroaryl Aziridines through Enantioselective Aziridination of Alkenes with Fluoroaryl Azides

(2013) Li-Mei Jin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Intermolecular Aminocyanation and Diamination of Alkenes

(2013) Hongwei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Complexes with Nitrogen-Centered Radical Ligands: Classification, Spectroscopic Features, Reactivity, and Catalytic Applications

(2013) Alma I. Olivos Suarez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Oxidative Amination and Allylic Amination of Alkenes

(2013) Timothy W. Liwosz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iron(II)-Catalyzed Intramolecular Aminohydroxylation of Olefins with Functionalized Hydroxylamines

(2013) Guan-Sai Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Direct α-Amination of Aldehydes via a Photoredox Mechanism: A Strategy for Asymmetric Amine Fragment Coupling

(2013) Giuseppe Cecere et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Aryl C–H Imidation with Arene as the Limiting Reagent

(2013) Gregory B. Boursalian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu-Catalyzed C–H Amination of Hydrofullerenes Leading to 1,4-Difunctionalized Fullerenes

(2013) Weili Si et al.   ORGANIC LETTERS

Sultam Synthesis via Cu-Catalyzed Intermolecular Carboamination of Alkenes with N-Fluorobenzenesulfonimide

(2013) Keiichi Kaneko et al.   ORGANIC LETTERS

Complex N-Heterocycle Synthesis via Iron-Catalyzed, Direct C-H Bond Amination

(2013) E. T. Hennessy et al.   SCIENCE

Intramolecular C(sp3)–H amination

(2013) Jenna L. Jeffrey et al.   Chemical Science

A Visible-Light-Mediated Oxidative CN Bond Formation/Aromatization Cascade: Photocatalytic Preparation of N-Arylindoles

(2012) Soumitra Maity et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-metal-free Benzylic C–H Bond Intermolecular Amination Utilizing Chloramine-T and I2

(2012) Youhei Takeda et al.   CHEMISTRY LETTERS

Lewis Acid Trapping of an Elusive Copper–Tosylnitrene Intermediate Using Scandium Triflate

(2012) Subrata Kundu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H Functionalization Reactivity of a Nickel–Imide

(2012) Stefan Wiese et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation

(2011) Seung Hwan Cho et al.   CHEMICAL SOCIETY REVIEWS

Cu(I)-Catalyzed Diamination of Conjugated Dienes. Complementary Regioselectivity from Two Distinct Mechanistic Pathways Involving Cu(II) and Cu(III) Species

(2011) Baoguo Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Cobalt(II) Porphyrin-Catalyzed C–H Amination with Organic Azides: Radical Nature and H-Atom Abstraction Ability of the Key Cobalt(III)–Nitrene Intermediates

(2011) Volodymyr Lyaskovskyy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic C−H Bond Amination from High-Spin Iron Imido Complexes

(2011) Evan R. King et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Intramolecular CH Amination through the Metalloradical Activation of Azides: Synthesis of 1,3-Diamines under Neutral and Nonoxidative Conditions

(2010) Hongjian Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic CH Amination with Unactivated Amines through Copper(II) Amides

(2010) Stefan Wiese et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Intermolecular Aminofluorination of Styrenes

(2010) Shuifa Qiu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent progress in the generation and use of nitrogen-centred radicals

(2008) Samir Z. Zard   CHEMICAL SOCIETY REVIEWS

A Cu(I)-Catalyzed C−H α-Amination of Esters. Direct Synthesis of Hydantoins

(2008) Baoguo Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY